SO2 oxidation products other than H2SO4 as a trigger of new particle formation. Part 2: Comparison of ambient and laboratory measurements, and atmospheric implications

Atmospheric Chemistry and Physics

Volumn 8, Issue 23, 2008, Pages 7255-7264

  Laaksonen, A ^a,g   Kulmala, M ^b   Berndt, T ^c   Stratmann, F ^c   Mikkonen, S ^a   Ruuskanen, A ^a   Lehtinen, K E J ^a,g   Dal Maso, M ^b   Aalto, P ^b   Petaja T ^b   Riipinen, I ^b   Sihto, S L ^b   Janson, R ^d   Arnold, F ^e   Hanke, M ^e   Ucker J ^e   Umann, B ^e   Sellegri, K ^e,h   O'Dowd, C D ^f   Viisanen, Y ^g  

^a UNIVERSITY OF EASTERN FINLAND   (Finland)

^b UNIVERSITY OF HELSINKI   (Finland)

^c LEIBNIZ INSTITUTE FOR TROPOSPHERIC RESEARCH   (Germany)

^d STOCKHOLM UNIVERSITY   (Sweden)

^e MAX PLANCK INSTITUT FÜR KERNPHYSIK   (Germany)

^f NATIONAL UNIVERSITY OF IRELAND   (Ireland)

^g FINNISH METEOROLOGICAL INSTITUTE   (Finland)

^h UNIVERSITÉ BLAISE PASCAL   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 69949101301     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-8-7255-2008     Document Type: Article

References (35)

1. 2 (M = Ar), J. Chem. Phys., 65, 306-310, 1976.
2. 3 vapors. J. Geophys. Res., 104, 23709-23718, 1999.
3. Berndt, T., Böge, O., Stratmann, F., Heintzenberg, J., and Kulmala, M.:, Rapid formation of sulfuric acid particles at nearatmospheric conditions, Science, 307, 698-700, 2005. (Pubitemid 40194634)
4. 2O particles in the absence of organics: A laboratory study, Geophys. Res. Lett., 33, L15817, doi:10.1029/2006GL026660, 2006. (Pubitemid 44962211)
5. 4 as a trigger of new particle formation. Part 1: Laboratory investigations, Atmos. Chem. Phys., 8, 6365-6374, 2008, http://www.atmos-chem-phys.net/8/6365/2008/.
6. 3, and the influence of water vapour: particle size distribution studies, Atmos. Chem. Phys., 2, 183-196, 2002, http://www.atmos-chem-phys.net/2/183/2002/.
7. Bonn, B., Schuster, G., and Moortgat, G. K.: Influence of water vapour on the process of new particle formation during monoterpene ozonolysis, J. Phys. Chem. A, 106, 2869-2881, 2002. (Pubitemid 35264149)
8. Dal Maso, M., Kulmala, M., Riipinen, I., Wagner, R., Hussein, T., Aalto, P. P., and Lehtinen, K. E. J.: Formation and Growth of fresh atmospheric aerosols: eight years of aerosol size distribution data from SMEAR II, Hyytiälä, Finland, Boreal Env. Res., 10, 323-336, 2005. (Pubitemid 41587373)
9. Finlayson-Pitts, B. J. And J. N. Pitts Jr.: Chemistry of the Upper and Lower Atmosphere: Theory, Experiments, and Applications, Academic Press, San Diego, CA, USA, 298-299, 2000.
10. Friend, J. P., Barnes, R. A., and Vasta, R. M.: Nucleation by free radicals from the photooxidation of sulfur dioxide in air.: J. Phys. Chem. 84, 2423-2436, 1980.
11. 3, J. Phys. Chem., 91, 719-724, 1987.
12. Komppula, M., Lihavainen, H., Kerminen, V.-M., Kulmala M., and Viisanen, Y.: Measurements of cloud droplet activation of aerosol particles at a clean subarctic background site, J. Geophys. Res. 110, D06204, doi:10.1029/ 2004JD005200, 2005. (Pubitemid 40771625)
13. Kuang C., McMurry, P. H., McCormick, A. V., and Eisele, F. L.: Dependence of nucleation rates on sulfuric acid vapor concentration in diverse atmospheric locations, J. Geophys. Res., 113, D10209, doi:10.1029/2007JD009253, 2008.
14. Kulmala, M., Pirjola, L., and Mäkelä, J. M.: Stable sulfate clusters as a source of new atmospheric particles, Nature, 404, 66-69, 2000. (Pubitemid 30143131)
15. Kulmala, M.: How particles nucleate and grow, Science, 302, 1000-1001, 2003. (Pubitemid 37386184)
16. Kulmala, M., Lehtinen K. E. J., and Laaksonen A.: Cluster activation theory as an explanation of the linear dependence between formation rate of 3 nm particles and sulphuric acid concentration, Atmos. Chem. Phys., 6, 787-793, 2006, http://www.atmos-chem-phys.net/6/787/2006/.
17. Kulmala, M., Mordas, G., Petäjä, T., Grönholm, T., Aalto, P. P., Vehkamäki, H., Hienola, A. I., Herrmann, E., Sipilä, M., Riipinen, I., Manninen, H. E., Hämeri, K., Stratmann, F., Bilde, M., Winkler, P. M., Birmili, W., and Wagner, P. E.: The condensation particle counter battery (CPCB): A new tool to investigate the activation properties of nanoparticles, J. Aerosol Sci. 38, 289-304, 2007. (Pubitemid 46365708)
18. Laaksonen, A., Hamed, A., Joutsensaari, J., Hiltunen, L., Cavalli, F., Junkermann, W., Asmi, A., Fuzzi, S., and Facchini, M. C.: Cloud condensation nucleus production from nucleation events at a highly polluted region, Geophys. Res. Lett., 32, L06812, doi:10.1029/2004GL022092, 2005 (Pubitemid 40771692)
19. McGraw, R.: Condensation nuclei production from sulfur dioxide photooxidation in air, J. Phys. Chem., 86, 2750-2752, 1982.
20. Merikanto, J., Napari, I., Vehkamäki, H., Anttila, T., and Kulmala, M.: New parameterization of sulfuric acid-ammonia-water ternary nucleation rates at tropospheric conditions, J. Geophys. Res. D15207, doi:10.1029/2006JD007977, 2007 (Pubitemid 47534414)
21. Napari, I., Noppel, M., Vehhkamäki, H., and Kulmala, M.: Parametrization of ternary nucleation rates for H2SO4-NH3-H2O vapors, J. Geophys. Res. 107, 4381-4386, 2002.
22. Riipinen, I., Sihto, S.-L., Kulmala, M., Arnold, F., Dal Maso, M., Birmili, W., Saarnio, K., Teinilä, K., Kerminen, V.-M., Laaksonen, A., and Lehtinen, K. E. J.: Connections between atmospheric sulphuric acid and new particle formation during QUEST III-IV campaigns in Heidelberg and Hyytiälä, Atmos. Chem. Phys., 7, 1899-1914, 2007. (Pubitemid 46615537)
23. Schmidt, V., Zhu, G. Y., Becker H., and Fink, E. H.: Study of OH reactions at high pressures by excimer laser photolysis - dye laser fluorescence, Ber. Bunsenges., Phys. Chem., 89, 321-322, 1985. (Pubitemid 15579186)
24. Sellegri, K., Hanke, M., Umann B., Arnold F., and Kulmala, M., Measurement of organic gases during aerosol formation events in the boreal forest atmosphere during QUEST, Atmos. Chem. Phys., 5, 373-384, 2005, http://www.atmos-chem-phys.net/5/373/2005/. (Pubitemid 40405289)
25. Sihto, S.-L., Kulmala, M., Kerminen, V.-M., Dal Maso, M., Petäjä, T., Riipinen, I., Korhonen, H., Arnold, F., Janson, R., Boy, M., Laaksonen, A., and Lehtinen, K. E. J.: Atmospheric sulphuric acid and aerosol formation: implications from atmospheric measurements for nucleation and early growth mechanisms, Atmos. Chem. Phys., 6, 4079-4091, 2006, http://www.atmos-chem-phys.net/6/4079/2006/. (Pubitemid 44373019)
26. 4 and ion-induced nucleation kinetics, Atmos. Environ., 41, 3740-3747, 2007. (Pubitemid 46602057)
27. 2 reaction, Atmos. Environ., 17, 2231-2235, 1983 (Pubitemid 14179967)
28. Vehkamäki, H., Kulmala, M., Napari, I., Lehtinen, K. E. J., Timmreck, C., Noppel M., and Laaksonen, A.: An improved parameterization for sulfuric acid-water nucleation rates for tropospheric and stratospheric conditions, J. Geophys. Res., 107, 4622, doi:10.1029/2002JD002184, 2002 (Pubitemid 43211904)
29. Vehkamäki, H., Määttänen, A., Lauri, A., Kulmala, M., Winkler, P., Vrtala, A., and Wagner, P. E.: Heterogeneous multicomponent nucleation theorems for the analysis of nanoclusters, J. Chem. Phys., 126, 174707, doi:10.1063/1.2723073, 2007 (Pubitemid 46717802)
30. Wayne, R. P.: Chemistry of Atmospheres, Clarendon Press, Oxford, p. 244, 1991.
31. Weber, R. J., Marti, J. J., McMurry, P. H., Eisele, F. L., Tanner, D. J., and Jefferson, A.: Measured atmospheric new particle formation rates: Implications for nucleation mechanisms, Chem. Eng. Commun., 151, 53-64, 1996.
32. Weber, R. J., McMurry, P. H., Mauldin III, R. L., Tanner, D. J., Eisele, F. L., Clarke, A. D., and Kapustin, V. N.: New particle formation in the remote troposphere: A comparison of observations at various sites, Geophys. Res. Lett., 26, 307-310, 1999. (Pubitemid 29321807)
33. 2+OH reaction: evaluation of the experimental setup and preliminary results, Atmos. Chem. Phys., 8, 4997-5016, 2008
34. Yu F.: Effect of ammonia on new particle formation: A kinetic H2SO4-H2O-NH3 nucleation model constrained by laboratory measurements, J. Geophys Res., 111, D0124, doi:10.1029/2005JD005968, 2006. (Pubitemid 43263783)
35. Zhang, R., Suh, I., Zhao, J., Zhang, D., Fortner, E. C., Tie, X., Molina, L. T., and Molina, M. J.: Atmospheric new particle formation enhanced by organic acids, Science, 304, 1487-1490, 2004. (Pubitemid 38720925)