Effect of ammonia on new particle formation: A kinetic H2SO4-H2O-NH3 nucleation model constrained by laboratory measurements

Journal of Geophysical Research Atmospheres

Volumn 111, Issue 1, 2006, Pages

  Yu, Fangqun ^a  

^a STATE UNIVERSITY OF NEW YORK   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; ATMOSPHERIC AEROSOLS; ATMOSPHERIC CHEMISTRY; COMPOSITION EFFECTS; MATHEMATICAL MODELS; METEOROLOGY; NUCLEATION; PARTICLES (PARTICULATE MATTER); REACTION KINETICS;

AEROSOL; AMMONIA; NUCLEATION;

EID: 62549117436     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2005JD005968     Document Type: Article

References (32)

1. 3 vapors, J. Geophys. Res., 104, 23,709.
2. 3 in humid air, Chem. Eng. Sci., 49, 4605.
3. Clarke, A. D., et al. (1998), Particle nucleation in the tropical boundary layer and its coupling to marine sulfur sources, Science, 282, 89.
4. Coffman, D. J., and D. A. Hegg (1995), A preliminary study of the effect of ammonia on particle nucleation in the marine boundary layer, J. Geophys. Res., 100, 7147.
5. D'Auria, R., R. P. Turco, and K. N. Jouk (2004), Effects of hydration on the properties of protonated-water-nitric acid clusters, J. Phys. Chem. A, 108, 3756.
6. Diamond, G. L., J. V. Iribarne, and D. J. Corr (1985), Ion-induced nucleation from sulfur dioxide, J. Aerosol Sci., 16, 43.
7. Gaydos, T. M., C. O. Stanier, and S. N. Pandis (2005), Modeling of in situ ultrafine atmospheric particle formation in the eastern United States, J. Geophys. Res., 110, D07S12, doi:10.1029/2004JD004683.
8. 2O system, J. Geophys. Res., 107(D12), 4158, doi:10.1029/ 2001JD001100.
9. 4 and its implications for the formation of new atmospheric particles, J. Phys. Chem. A, 103, 2801.
10. 2O/air mixtures by ionizing irradiation, Aerosol Sci. Technol., 29, 112.
11. 2O in the atmosphere, J. Geophys. Res., 104, 26,349.
12. 2O, J. Geophys. Res., 107(D19), 8111, doi:10.1029/2001JD000900.
13. 4 vapor pressure of sulfuric acid and ammonium sulfate solutions, J. Geophys. Res., 102, 3725.
14. Nadykto, A., and F. Yu (2003), Uptake of neutral polar vapour molecules by charged particles: Enhancement due to dipole-charge interaction, J. Geophys. Res., 108(D23), 4717, doi:10.1029/2003JD003664.
15. Napari, I., M. Noppel, H. Vehkamäki, and M. Kulmala (2002a), An improved model for ternary nucleation of sulfuric acid-ammonia-water, J. Chem. Phys., 116, 4221.
16. 2O vapors, J. Geophys. Res., 107(D19), 4381, doi:10.1029/2002JD002132.
17. Nolan, P. M. (1987), Condensation nuclei formation by photooxidation of sulfur dioxide with OH radical in the presence of water vapor and ammonia, thesis, Drexel Univ., Philadelphia, Pa.
18. O'Dowd, C. D., et al. (2002a), A dedicated study of New Particle Formation and Fate in the Coastal Environment (PARFORCE): Overview of objectives and achievements, J. Geophys. Res., 107(D19), 8108, doi:10.1029/2001JD000555.
19. O'Dowd, C. D., et al. (2002b), Marine aerosol formation from biogenic iodine emissions, Nature, 417, 632.
20. Seinfeld, J. H., and S. N. Pandis (1998), Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, 1326 pp., John Wiley, Hoboken, N. J.
21. Stanier, C., A. Khlystov, and S. N. Pandis (2004), Nucleation events during the Pittsburgh Air Quality Study: Description and relation to key meteorological, gas phase, and aerosol parameters, Aerosol Sci. Technol., suppl. 1, 38, 253.
22. Vehkamäki, H., et al. (2002), An improved parameterization for sulfuric acid-water nucleation rates for tropospheric and stratospheric conditions, J. Geophys. Res., 107(D22), 4622, doi:10.1029/2002JD002184.
23. Vehkamäki, H., I. Napari, M. Kulmala, and M. Noppel (2004), Stable ammonium bisulfate clusters in the atmosphere, Phys. Rev. Lett., 93, 148501.
24. Weber, R. J., J. J. Marti, P. H. McMurray, F. L. Eisele, D. J. Tanner, and A. Jefferson (1996), Measured atmospheric new particle formation rates: Implications for nucleation mechanisms, Chem. Eng. Comm., 151, 53-64.
25. 2O, J. Chem. Phys., 122, 074501.
26. Yu, F. (2005b), Modified Kelvin-Thomson equation considering ion-dipole interaction: Comparison with observed ion-clustering enthalpies and entropies, J. Chem. Phys., 122, 084503.
27. Yu, F. (2006), Binary H2SO4-H2O homogeneous nucleation rates based on a kinetic quasi-unary model: Look-up tables, J. Geophys. Res., doi:10.1029/ 2005JD006358, in press.
28. Yu, F., and R. P. Turco (2000), Ultrafine aerosol formation via ion-mediated nucleation, Geophys. Res. Lett., 27, 883.
29. Yu, F., and R. P. Turco (2001), From molecular clusters to nanoparticles: The role of ambient ionization in tropospheric aerosol formation, J. Geophys. Res., 106, 4797.
30. Yu, F., C. Cai, and K. L. Demerjian (2004), Regional scale modeling of particle nucleation in the, lower atmosphere over the Eastern United States, Eos Trans. AGU, 85(47), Fall Meet. Suppl., Abstract A44B-01.
31. Zhang, Q., C. Stanier, M. Canagaratna, J. Jayne, D. Worsnop, S. Pandis, and J. Jimenez (2004a), Insights into nucleation burst and particle growth in Pittsburgh based on aerosol mass spectrometry, Environ. Sci. Technol., 38(18), 4797.
32. Zhang, R., et al. (2004b), Atmospheric new particle formation enhanced by organic acids, Science, 304, 1487-1490.