SO2 oxidation products other than H2SO4 as a trigger of new particle formation. Part 1: Laboratory investigations

Atmospheric Chemistry and Physics

Volumn 8, Issue 21, 2008, Pages 6365-6374

  Berndt, T ^a   Stratmann, F ^a   Brasel S ^a   Heintzenberg, J ^a   Laaksonen, A ^b   Kulmala, M ^c  

^a LEIBNIZ INSTITUTE FOR TROPOSPHERIC RESEARCH   (Germany)

^b UNIVERSITY OF EASTERN FINLAND   (Finland)

^c UNIVERSITY OF HELSINKI   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 69949085629     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-8-6365-2008     Document Type: Article

References (37)

1. x species, Atmos. Chem. Phys., 4, 1461-1738, 2004, http://www.atmos-chem-phys.net/4/1461/2004/. (Pubitemid 39342128)
2. 3 vapors, J. Geophys. Res., 104, 23 709-23 718, doi:10.1029/1999JD900411, 1999.
3. 2+OH reaction, Geophys. Res. Lett., 35, L11801, doi:10.1029/2008GL033387, 2008.
4. 2, Atmos. Environ., 38, 2145-2153, 2004. (Pubitemid 38519780)
5. Berndt, T., Boge, O., Stratmann, F., Heintzenberg, J., and Kulmala, M.: Rapid Formation of Sulfuric Acid Particles at Near-Atmospheric Conditions, Science, 307, 698-700, 2005. (Pubitemid 40194634)
6. 2O particles in the absence of organics: A laboratory study, Geophys. Res. Lett., 33, L15817, doi:10.1029/2006GL026660, 2006. (Pubitemid 44962211)
7. 3 and OH initiated oxidation of α-pinene and β-pinene between 278 and 320 K, J. Geophys. Res., 112, D10216, 2007.
8. 2 radical studied by laser magnetic resonance spectroscopy, Proc. R. Soc. Lond. A, 368, 463-481, 1979.
9. Finlayson-Pitts, B. J. and Pitts Jr., J. N., and references therein: Chemistry of the Upper and Lower Atmosphere, Academic Press, San Diego, CA, USA, 2000.
10. Friend, J. P., Barnes, R. A. and Vasta, R. M.: Nucleation by freeradicals from the photo-oxidation of sulfur-dioxide in air, J. Phys. Chem., 84, 2423-2436, 1980.
11. 3, J. Phys. Chem., 91, 719-724, 1987.
12. 4, J. Phys. Chem. A, 104, 1715-1719, 2000.
13. 3 reaction: Implications for new particle formation processes, J. Geophys. Res., 103, 25 569-25 578, 1998. (Pubitemid 128700104)
14. Howard, C., Communication at the 17th Symposium on Free Radicals, Granby, 1985;
15. 2, edited by: Martin, D., Jourdain, J. L., and LeBras, G., J. Phys. Chem., 90, 4143-4147, 1986.
16. 4 surfaces, J. Phys. Chem., 101, 10 000-10 011, 1997. (Pubitemid 127617251)
17. Kolditz, L.: Anorganische Chemie, Deutscher Verlag der Wissenschaften, Berlin, 461-482, 1983.
18. Kulmala, M., Laaksonen, A., and Pirjola, L.: Parameterization for sulphuric acid/water nucleation rates, J. Geophys. Res., 103, 8301-8307, 1998. (Pubitemid 28388669)
19. Kulmala, M., Pirjola, L., and Makela, J. M.: Stable sulphate cluster as a source of new atmospheric particles, Nature, 404, 66-69, 2000. (Pubitemid 30143131)
20. Kulmala, M.: How particles nucleate and grow, Science, 302, 1000-1001, 2003. (Pubitemid 37386184)
21. Martin, L. R. and Damschen, D. E.: Aqueous Oxsidation of Sulfur Dioxide by Hydrogen Peroxide at Low pH, Atmos. Environ., 15, 1615-1621, 1981.
22. Laaksonen, A., Kulmala, M., Berndt, T., Stratmann, F., Mikkonen, S., Ruuskanen, A., Lehtinen, K. E. J., Dal Maso, M., Aalto, P., Petäjä, T., Riipinen, I., Sihto, S.-L., Janson, R., Arnold, F., Hanke, M., Ücker, J., Umann, B., Sellegri, K., O'Dowd, C. D., and Viisanen, Y., Atmos. Chem. Phys. Discuss., 8, 9673-9695, 2008, http://www.atmos-chem-phys-discuss.net/8/9673/ 2008/.
23. Lee, S.-H., Reeves, J. M., Wilson, J. C., Hunton, D. E., Viggiano, A. A., Miller, T. M., Ballenthin, J. O., and Lait, L. R.: Science, 301, 1886-1889, 2003.
24. 3 with water, J. Phys. Chem., 100, 19 911-19 916, 1996. (Pubitemid 126786911)
25. Lovejoy, E. R., Curtius, J., and Froyd, K. D.: Atmospheric ioninduced nucleation of sulphuric acid and water, J. Geophys. Res., 109, D08204, doi:10.1029/2003JD004460, 2004. (Pubitemid 38904635)
26. 2, J. Phys. Chem., 90, 4143-4147, 1986.
27. McMurry, P. H., Fink, M., Sakurai, H., Stolzenburg, M. R., Mauldin III, R. L., Smith, J., Eisele, F., Moore, K., Sjostedt, S., Tanner, D., Huey, L. G., Nowak, J. B., Edgerton, E., and Voisin, D.: A criterion for new particle formation in the sulfur-rich Atlanta atmosphere, J. Geophys. Res., 110, D22S02, doi:10.1029/2005JD005901, 2005. (Pubitemid 43051317)
28. 2 and NO, J. Am. Chem. Soc., 95, 7614-7619, 1973.
29. 3, Ber. Bunsen Phys. Chem., 87, 648-654, 1983. (Pubitemid 14466732)
30. Reid, R. C., Prausnitz, J. M., and Poling, B. E.: The Properties of Gases and Liquids, McGraw-Hill, New York, 11, 1-20, 1987.
31. Riipinen, I., Sihto, S.-L., Kulmala, M., Arnold, F., Dal Maso, M., Birmili, W., Teinilä, K., Kerminen, V.-M., Laaksonen, A., and Lehtinen, K. F. J.: Connections between atmospheric sulphuric acid and new particle formation during QUEST III-IV campaigns in Heidelberg and Hyytiälä, Atmos. Chem. Phys., 7, 1899-1914, 2007, http://www.atmos-chem-phys.net/7/1899/2007/. (Pubitemid 46615537)
32. 2 reaction, Atmos. Environ., 17, 2231-2235, 1983. (Pubitemid 14179967)
33. Wayne, R.: Chemistry of Atmospheres, Clarendon Press, Oxford, 242-245, 1991.
34. Weber, R. J., Marti, J. J., McMurry, P. H., Eisele, F. L., Tanner, D. J., and Jefferson, A.: Measured atmospheric new particle formation rates: Implications for nucleation mechanisms, Chem. Eng. Comm., 151, 53-64, 1996.
35. 2+OH reaction: evaluation of the experimental setup and preliminary results, Atmos. Chem. Phys., 8, 4997-5016, 2008, http://www.atmos-chem-phys.net/ 8/4997/2008/.
36. Yu, F., Turco, R. P., and Kärcher, B.: The possible role of organics in the formation and evolution of ultrafine aircraft particles, J. Geophys. Res., 104, 4079-4087, 1999. (Pubitemid 29280433)
37. Zhang, R., Suh, I., Zhao, J., Zhang, D., Fortner, E. C., Tie, X., Molina, L. T., and Molina, M. J.: Atmospheric New Particle Formation Enhanced by Organic Acids, Science, 304, 1487-1489, 2004.