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Volumn , Issue 26, 2009, Pages 4400-4403

Regioselective metal-catalyzed hydrophosphinylation of alkynes: Synthesis of enantiopure α- or β-substituted vinylphosphane oxides

Author keywords

Alkynes; Homogeneous catalysis; Phosphorus heterocycles; Regioselectivity

Indexed keywords


EID: 69449105279     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200900658     Document Type: Article
Times cited : (27)

References (40)
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    • For the synthesis of phosphinates by metal-catalyzed hydrophosphinylation, see: a) S. Kumar Nune, M. Tanaka, Chem. Commun. 2007, 2858-2860;
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    • For the synthesis of H-phosphinates by metal-catalyzed hydrphosphinylation, see
    • For the synthesis of H-phosphinates by metal-catalyzed hydrphosphinylation, see: a) S. Deprèle, J.-L. Montchamp, J. Am. Chem. Soc. 2002,124, 9386-9387;
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 9386-9387
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    • For the synthesis of phosphane oxides by metal-catalyzed hy drophosphinylation, see
    • For the synthesis of phosphane oxides by metal-catalyzed hy drophosphinylation, see: a) L. B. Han, N. Choi, M. Tanaka, Organometallics 1996, 15, 3259-3261;
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    • The isolated yields of pure product are low despite the high yields determined by NMR spectroscopy. This result is due to the degradation of product on silica gel
    • The isolated yields of pure product are low despite the high yields determined by NMR spectroscopy. This result is due to the degradation of product on silica gel.
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    • In solution, secondary phosphane oxides exist in equilibrium between pentavalent (phosphane oxide form) and trivalent (phosphane form) tautomeric structures. At room temperature, the phosphane oxide form is the more stable, whereas the phosphane form coordinates transition metals
    • In solution, secondary phosphane oxides exist in equilibrium between pentavalent (phosphane oxide form) and trivalent (phosphane form) tautomeric structures. At room temperature, the phosphane oxide form is the more stable, whereas the phosphane form coordinates transition metals: a) N. V. Dubrovina, A. Börner, Angew. Chem. 2004,116, 6007-6010;
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.