Investigation of the morphological changes promoted by heating of Si-C-O ceramics derived from a phenyl-rich hybrid polymer. Effect of Ni in the polymeric precursor

Journal of the European Ceramic Society

Volumn 29, Issue 15, 2009, Pages 3279-3287

  Segatelli, Mariana Gava ^a   Radovanovic, Eduardo ^b   Gonçalves, Maria do Carmo ^a   Yoshida, Inez Valéria Pagotto ^a  

^a UNIVERSITY OF CAMPINAS   (Brazil)

^b STATE UNIVERSITY OF MARINGÁ   (Brazil)

Author keywords

Electron microscopy; Glass ceramics; Nanowires; SiC; SiO2

Indexed keywords

AMORPHOUS NANOWIRES; C-SYSTEMS; CERAMIC BODIES; DIFFERENT SIZES; EXTERNAL LAYERS; GROWTH MECHANISMS; HYBRID POLYMERIC PRECURSORS; HYBRID POLYMERS; METHYLSILOXANE; MORPHOLOGICAL CHANGES; NANO DOMAIN; NICKEL ACETATE; POLYMERIC PRECURSORS; SIC; SILICON OXYCARBIDE CERAMICS; SIO2;

AMORPHOUS CARBON; AMORPHOUS SILICON; ELECTRIC WIRE; GRAPHITE; HEATING; MORPHOLOGY; NANOWIRES; NICKEL; NICKEL ALLOYS; ORGANOMETALLICS; OXYGEN; POLYMERS; SILICON CARBIDE; SILICON OXIDES; STRUCTURAL CERAMICS;

GLASS CERAMICS;

EID: 68949158454     PISSN: 09552219     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jeurceramsoc.2009.06.018     Document Type: Article

References (36)

1. Riedel R. Materials science and technology. In: Cahn R.W., Haasen P., and Kramer E.J. (Eds). A Comprehensive Treatment (1996), VCH, Weinheim 1-50
2. Riedel R., Paasing G., Schönfelder H., and Brook R.J. Synthesis of dense silicon-based ceramics at low temperatures. Nature 355 (1992) 714-717
3. Greil P. Polymer derived engineering ceramics. Adv. Eng. Mater. 2 (2000) 339-348
4. Schiavon M.A., Radovanovic E., and Yoshida I.V.P. Microstructural characterization of monolithic ceramic matrix composites from polysiloxane and SiC powder. Powder Technol. 123 (2002) 232-241
5. Wei Q., Pippel E., Woltersdorf J., Scheffler M., and Greil P. Interfacial SiC formation in polysiloxane-derived Si-O-C ceramics. Mater. Chem. Phys. 73 (2002) 281-289
6. Belot V., Corriu R.J.P., Leclercq D., Mutin P.H., and Vioux A. Thermal redistribution reactions in crosslinked polysiloxanes. J. Polym. Sci. A 30 (1992) 613-623
7. Hourlier D.B., Latournerie J., and Dempsey P. Reaction pathways during the thermal conversion of polysiloxane precursors into oxycarbide ceramics. J. Eur. Ceram. Soc. 25 (2005) 979-985
8. Kleebe H.-J., Turquat C., and Sorarù G.D. Phase-separation in an SiCO glass studied by transmission electron microscopy and electron energy-loss spectroscopy. J. Am. Ceram. Soc. 84 (2001) 1073-1080
9. Monthioux M., and Delverdier O. Thermal behavior of (organosilicon) polymer-derived ceramics. V: main facts and trends. J. Eur. Ceram. Soc. 16 (1996) 721-737
10. Trassl S., Motz G., Rössler E., and Ziegler G. Characterization of the free-carbon phase in precursor-derived Si-C-N ceramics. I. Spectroscopic methods. J. Am. Ceram. Soc. 85 (2002) 239-244
11. Gregori G., Kleebe H.-J., Brequel H., Enzo S., and Ziegler G. Microstructure evolution of precursors-derived SiCN ceramics upon thermal treatment at temperatures ranging between 1000 and 1400 °C. J. Non-Cryst. Solids 351 (2005) 1393-1402
12. Scheffler M., Greil P., Berger A., Pippel E., and Woltersdorf J. Nickel-catalysed in situ formation of carbon nanotubes and turbostratic carbon in polymer-derived ceramics. Mater. Chem. Phys. 84 (2004) 131-139
13. Leu I.C., Hon M.H., and Lu Y.M. Chemical vapor deposition of silicon carbide whiskers activated by elemental nickel. J. Electrochem. Soc. 146 (1999) 184-188
14. Nahm K.S., Mo Y.H., Shajahan Md., and Lee S.H. Catalytic growth of semiconductor micro- and nano-crystals using transition metal catalysts. Kor. J. Chem. Eng. 19 (2002) 510-518
15. Jou S., and Hsu C.K. Preparation of carbon nanotubes from vacuum pyrolysis of polycarbosilane. Mater. Sci. Eng. B 106 (2004) 275-281
16. Yang W., Miao H., Xie Z., Zhang L., and An L. Synthesis of silicon carbide nanorods by catalyst-assisted pyrolysis of polymeric precursor. Chem. Phys. Lett. 383 (2004) 441-444
17. 4 nanobelts and nanodendrites by catalyst-assisted crystallization of amorphous SiCN. J. Cryst. Growth 276 (2005) 1-6
18. Haberecht J., Krumeich F., Stalder M., and Nesper R. Carbon nanostructures on high-temperature ceramics-a novel composite material and its functionalization. Catal. Today 102-103 (2005) 40-44
19. Deng S.Z., Li Z.B., Wang W.L., Xu N.S., Zhou J., Zheng X.G., et al. Field emission study of SiC nanowires/nanorods directly grown on SiC ceramic substrate. Appl. Phys. Lett. 89 (2006) [023118-1-023118-3]
20. Liang C.H., Meng G.W., Chen W., Wang Y.W., and Zhang L.D. Growth and characterization of TiC nanorods activated by nickel nanoparticles. J. Cryst. Growth 220 (2000) 296-300
21. Lu H.-Y., Chu S.-Y., and Chang C.-C. Synthesis and optical properties of well-aligned ZnS nanowires on Si substrate. J. Cryst. Growth 280 (2005) 173-178
22. Ci L.J., Zhao Z.G., and Bai J.B. Direct growth of carbon nanotubes on the surface of ceramic fibers. Carbon 43 (2005) 883-886
23. Djurisic A.B., Tam K.H., Hsu Y.F., Zhang S.L., Xie M.H., and Chan W.K. GaN nanowires-influence of the starting material on nanowire growth. Thin Solid Films 516 (2007) 238-242
24. Berger A., Pippel E., Woltersdorf J., Scheffler M., Cromme P., and Greil P. Nanoprocesses in polymer-derived Si-O-C ceramics: electronmicroscopic observations and reaction kinetics. Phys. Status Solidi (a) 202 (2005) 2277-2286
25. y derived from a Ni-containing hybrid polymer. J. Eur. Ceram. Soc. 28 (2008) 2247-2257
26. In: Reimer L., Zepke U., Moesch J., Schulze-Hillert St., Ross-Messemer M., Probst W., and Weimer E. (Eds). EELS Spectroscopy: A Reference Handbook of Standard Data for Identification and Interpretation of Electron Energy Loss Spectra and for Generation of Electron Spectrocopic Images (1992), Oberkochen, Carl Zeiss
27. Li K.-Z., Wei J., Li H.-J., Li Z.-J., Hou D.-S., and Zhang Y.-L. Photoluminescence of hexagonal-shaped SiC nanowires prepared by sol-gel process. Mater. Sci. Eng. A 460-461 (2007) 233-237
28. Kleebel H.-J., and Blum Y.D. SiOC ceramic with high excess free carbon. J. Eur. Ceram. Soc. 28 (2008) 1037-1042
29. Li H.J., Li Z.J., Meng A.L., Li K.Z., Zhang X.N., and Xu Y.P. SiC nanowire networks. J. Alloys Compd. 352 (2003) 279-282
30. Yao X., Tan S., Huang Z., Dong S., and Jiang D. Growth mechanism of β-SiC nanowires in SiC reticulated porous ceramics. Ceram. Int. 33 (2007) 901-904
31. Egerton R.F. Electron Energy-Loss Spectroscopy in the Electron Microscopy (1986), Plenum, New York [chapter 2]
32. Kaneko K., and Kakimoto K.-I. HRTEM and ELNES analysis of polycarbosilane-derived Si-C-O bulk ceramics. J. Non-Cryst. Solids 270 (2000) 181-190
33. Gregori G., Kleebe H.-J., Blum Y.D., and Babonneau F. Evolution of C-rich SiOC ceramics. Part II. Characterization by high lateral resolution techniques: electron energy-loss spectroscopy, high-resolution TEM and energy-filtered TEM. Int. J. Mater. Res. 97 (2006) 710-720
34. 2, Ca- and Zn-silicate in Minuartia. J. Microsc. 183 (1996) 45-52
35. x coatings. New J. Phys. 9 (2007) 13-21
36. Pamplin B.R. Crystal Growth. 2nd ed. (1980), Pergamon Press, Oxford p. 58