The PPh 3-substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph 2-3,4-Tol 2(η 5-C 4COH)] Ru(CO)(PPh 3)H is a more efficient catalyst for hydrogenation of aldehydes

Organometallics

Volumn 25, Issue 5, 2006, Pages 1230-1235

  Casey, Charles P ^a   Strotman, Neil A ^a   Beetner, Sharon E ^a   Johnson, Jeffrey B ^a   Priebe, David C ^a   Vos, Thomas E ^a   Khodavandi, Babak ^a   Guzei, Ilia A ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE REDUCTION; ALDEHYDIC HYDROGEN; HYDROXYCYCLOPENTADIENYL RUTHENIUM HYDRIDE;

ALDEHYDES; HYDRIDES; HYDROGEN INORGANIC COMPOUNDS; HYDROGENATION; THERMAL EFFECTS;

RUTHENIUM COMPOUNDS;

EID: 33644930551     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0509387     Document Type: Article

References (21)

1. (a) Shvo, Y.; Czarkie, D.; Rahamim, Y.; Chodosh, D. F. J. Am. Chem. Soc. 1986, 108, 7400.
2. (b) Menashe, N.; Shvo, Y. Organometallics 1991, 10, 3885.
3. (c) Menashe, N.; Salant, E.; Shvo, Y. J. Organomet. Chem. 1996, 514, 97.
4. (a) Haack, K.-J.; Hashiguchi, S.; Fujii, A.; Ikariya, T.; Noyori, R. Angew. Chem., Int. Ed. 1997, 36, 285.
5. (b) Noyori, R.; Hashiguchi, S. Acc. Chem. Res. 1997, 50, 97.
6. (c) Marsumura, K.; Hashiguchi, S.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1997, 119, 8738.
7. Noyori, R.; Ohkuma, T. Angew. Chem., Int. Ed. 2001, 40, 40 and references therein.
8. (a) Abdur-Rashid, K.; Faatz, M.; Lough, A. J.; Morris, R. H. J. Am. Chem. Soc. 2001, 123, 7473.
9. (b) Abdur-Rashid, K.; Lough, A. J.; Morris, R. H. Organometallics 2001, 20, 1047.
10. (c) Abdur-Rashid, K.; Clapham, S. E.; Hadzovic, A.; Harvey, J. N.; Lough, A. J.; Morris, R. H. J. Am. Chem. Soc. 2002, 124, 15104.
11. For a recent review of hydrogenation of polar bonds catalyzed by ruthenium hydride complexes, see: Clapham, S. E.; Hadzovic, A.; Morris, R. H. Coord. Chem. Rev. 2004, 248, 2201.
12. Fehring, V.; Selke, R. Angew. Chem., Int. Ed. 1998, 37, 1827.
13. Yamakawa, M.; Ito, H.; Noyori, R. J. Am. Chem. Soc. 2000, 122, 1466.
14. Casey, C. P.; Singer, S. W.; Powell, D. R.; Hayashi, R. K.; Kavana, M. J. Am. Chem. Soc. 2001, 123, 1090.
15. Casey, C. P.; Johnson, J. B. J. Org. Chem. 2003, 68, 1998.
16. Casey, C. P.; Johnson, J.-B. Unpublished results.
17. Casey, C. P.; Vos, T. E.; Singer, S. W.; Guzei, I. A. Organometallics 2002, 21, 5038.
18. (a) Jordan, R. F.; Norton, J. R. J. Am. Chem. Soc. 1982, 104, 1255.
19. (b) Moore, E. J.; Sullican, J. M.; Norton, J. R. J. Am. Chem. Soc. 1986, 108, 2257.
20. The mechanism of this exchange reaction is not well understood and is currently under investigation: Casey, C. P.; Johnson, J. B.; Singer, S. W.; Cui, Q. J. Am. Chem. Soc. 2005, 127, 3100.
21. Casey, C. P.; Singer, S. W.; Powell, D. R. Can. J. Chem. 2001, 79, 1002.