Chemically blockable transformation and ultraselective low-pressure gas adsorption in a non-porous metal organic framework

Nature Chemistry

Volumn 1, Issue 4, 2009, Pages 289-294

  Xiao, Bo ^a   Byrne, Peter J ^a   Wheatley, Paul S ^a   Wragg, David S ^a   Zhao, Xuebo ^b,c   Fletcher, Ashleigh J ^b,c   Thomas, K Mark ^b,c   Peters, Lars ^d   Evans, John S O ^d   Warren, John E ^e   Zhou, Wuzong ^a   Morris, Russell E ^a  

^a UNIVERSITY OF ST ANDREWS   (United Kingdom)

^b Northern Carbon Research Laboratories   (United Kingdom)

^c NEWCASTLE UNIVERSITY   (United Kingdom)

^d DURHAM UNIVERSITY   (United Kingdom)

^e DARESBURY LABORATORY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; ISOPHTHALATE; METAL; ORGANIC COMPOUND; ORGANOMETALLIC COMPOUND; PHTHALIC ACID DERIVATIVE; SULFUR DERIVATIVE; WATER;

ADSORPTION; ARTICLE; CHEMISTRY; GAS; POROSITY; PRESSURE; SYNTHESIS; X RAY DIFFRACTION;

ADSORPTION; COPPER; GASES; METALS; ORGANIC CHEMICALS; ORGANOMETALLIC COMPOUNDS; PHTHALIC ACIDS; POROSITY; PRESSURE; SULFUR COMPOUNDS; WATER; X-RAY DIFFRACTION;

EID: 67849085131     PISSN: 17554330     EISSN: 17554349     Source Type: Journal    
DOI: 10.1038/nchem.254     Document Type: Article

References (34)

1. Wang, B., Cote, A. P., Furukawa, H., O'Keeffe, M. & Yaghi, O. M. Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs. Nature 453, 207-211 (2008).
2. 2 capture. Science 319, 939-943 (2008).
3. Cheetham, A. K. & Rao, C. N. R. Materials science: there's room in the middle. Science 318, 58-59 (2007).
4. Eddaoudi, M. et al. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science 295, 469-472 (2002).
5. Morris, R.E. & Wheatley, P. S. Gas storage in nanoporous materials. Angew. Chem. Int. Ed. 47, 4966-4981 (2008).
6. Dinca, M., Yu, A. F. & Long, J. R. Microporous metal-organic frameworks incorporating 1,4-benzeneditetrazolate: syntheses, structures, and hydrogen storage properties. J. Am. Chem. Soc. 128, 8904-8913 (2006).
7. Panella, B., Hirscher, M., Putter, H. & Muller, U. Hydrogen adsorption in metal- organic frameworks: Cu-MOFs and Zn-MOFs compared. Adv. Funct. Mater. 16, 520-524 (2006).
8. Xiao, B. et al. High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework. J. Am. Chem. Soc. 129, 1203-1209 (2007).
9. Zhao, X. B. et al. Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks. Science 306, 1012-1015 (2004).
10. Serre, C. et al. Role of solvent-host interactions that lead to very large swelling of hybrid frameworks. Science 315, 1828-1831 (2007).
11. Zhang, J. P., Lin, Y. Y., Zhang, W. X. & Chen, X. M. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer. J. Am. Chem. Soc. 127, 14162-14163 (2005).
12. Jia, J. et al. Triggered ligand release coupled to framework rearrangement: generating crystalline porous coordination materials. Inorg. Chem. 45, 8838-8840 (2006).
13. Hanson, K., Calin, N., Bugaris, D., Scancella, M. & Sevov, S. C. Reversible repositioning of zinc atoms within single crystals of a zinc polycarboxylate with an open-framework structure. J. Am. Chem. Soc. 126, 10502-10503 (2004).
14. Cussen, E. J., Claridge, J. B., Rosseinsky, M. J. & Kepert, C. J. Flexible sorption and transformation behavior in a microporous metal-organic framework. J. Am. Chem. Soc. 124, 9574-9581 (2002)
15. Kitagawa, S., Kitaura, R. & Noro, S. Functional porous coordination polymers. Angew. Chem. Int. Ed. 43, 2334-2375 (2004)
16. Ghosh, S. K., Zhang, J. P. & Kitagawa, S. Reversible topochemical transformation of a soft crystal of a coordination polymer. Angew. Chem. Int. Ed. 46, 7965-7968 (2007).
17. Bradshaw, D., Warren, J. E. & Rosseinsky, M. J. Reversible concerted ligand substitution at alternating metal sites in an extended solid. Science 315, 977-980 (2007).
18. Maji, T. K., Mostafa, G., Matsuda, R. & Kitagawa, S. Guest-induced asymmetry in a metal-organic porous solid with reversible single-crystal-to- single-crystal structural transformation. J. Am. Chem. Soc. 127, 17152-17153 (2005).
19. Kim, D. S., Forster, P. M., Le Toquin, R. & Cheetham, A. K. A thermally stable nanoporous nickel 5-sulfoisophthalate; crystal structure and adsorption properties. Chem. Commun. 2148-2149 (2004).
20. Liu, Q. Y., Yuan, D. Q. & Xu, L. Diversity of coordination architecture of copper(II)-5-sulfoisophthalic acid: synthesis, crystal structures, and characterization. Cryst. Growth Des. 7, 1832-1843 (2007).
21. n. Science 283, 1148-1150 (1999).
22. Chen, B. L., Ockwig, N. W., Millward, A. R., Contreras, D. S. & Yaghi, O. M. High H2 adsorption in a microporous metal-organic framework with open metal sites. Angew. Chem. Int. Ed. 44, 4745-4749 (2005).
23. Ferey, G. et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309, 2040-2042 (2005).
24. Yaghi, O. M. et al. Reticular synthesis and the design of new materials. Nature 423, 705-714 (2003).
25. Lebedev, O. I., Millange, F., Serre, C., Van Tendeloo, G. & Ferey, G. First direct imaging of giant pores of the metal-organic framework MIL-101. Chem. Mater. 17, 6525-6527 (2005).
26. Zhou, W. Microscopic study of crystal defects enriches our knowledge of materials chemistry. J. Mater. Chem. 18, 5321-5325 (2008).
27. Kitaura, R., Seki, K., Akiyama, G. & Kitagawa, S. Porous coordination-polymer crystals with gated channels specific for supercritical gases. Angew Chem. Int. Ed. 42, 428-431 (2003).
28. Uchida, S. & Mizuno, N. Design and synthesis of nano-structured ionic crystals with selective adsorption properties. Coord. Chem. Rev. 251, 2537-2546 (2007).
29. Tanaka, D. et al. Kinetic gate-opening process in a flexible porous coordination polymers. Angew Chem. Int. Ed. 47, 3914-3918 (2008)
30. Keefer, L. K. Biomaterials - thwarting thrombus. Nature Mater. 2, 357-358 (2003).
31. Wheatley, P. S. et al. NO-releasing zeolites and their antithrombotic properties. J. Am. Chem. Soc. 128, 502-509 (2006).
32. Mowbray, M., Tan, X. J., Wheatley, P. S., Morris, R. E. & Weller, R. B. Topically applied nitric oxide induces T-lymphocyte infiltration in human skin, but minimal inflammation. J. Invest. Dermatol. 128, 352-360 (2008).
33. McKinlay, A. C. et al. Exceptional behavior over the whole adsorption-storage- delivery cycle for NO in porous metal organic frameworks. J. Am. Chem. Soc. 130, 10440-10444 (2008).
34. Bradshaw, D., Prior, T. J., Cussen, E., Claridge, J. B. & Rosseinsky, M. J. Permanent microporosity and enantioselective sorption in a chiral open framework. J. Am. Chem. Soc. 126, 6106-6114 (2004).