Role of solvent-host interactions that lead to very large swelling of hybrid frameworks

Science

Volumn 315, Issue 5820, 2007, Pages 1828-1831

  Serre, C ^a   Mellot Draznieks, C ^a,b   Surble S ^a   Audebrand, N ^c   Filinchuk, Y ^d   Ferey G ^a  

^a UNIVERSITÉ DE VERSAILLES SAINT QUENTIN EN YVELINES   (France)

^b DAVY FARADAY RESEARCH LABORATORY   (United Kingdom)

^c UNIVERSITÉ DE RENNES 1   (France)

^d EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BIPHENYL DERIVATIVE; BIPHENYLDICARBOXYLATE; CHROMIUM; DICARBOXYLIC ACID DERIVATIVE; FUMARIC ACID DERIVATIVE; IRON; SOLVENT; TEREPHTHALIC ACID; UNCLASSIFIED DRUG;

ADSORPTION; CHEMICAL BONDING; ORGANIC COMPOUND; SOLVENT; SWELLING;

ADSORPTION; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMISTRY; PRIORITY JOURNAL;

EID: 34147217224     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1137975     Document Type: Article

References (13)

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12. Supplementary data and figures are available on Science Online.
13. We are indebted to the ESRF in Grenoble for providing beamtime and for the help of the staff during and after the experiments. F. Millange and G. Marsolier are also acknowledged for their help in collecting XRD patterns. CNRS is acknowledged for financial support. Coordinates of MIL-88A to D deduced from computer simulation (dry, open forms) as well as the experimental structures of the open forms of MIL-88A to D (with solvents) have been deposited with ICSD data bank, deposition numbers CSD 417746, 417747, 417748, 417749, 417750, 417751, 417752, 417753, 417756, 417757, 417758, and 417759.