Photochromism of an organorhodium dithionite complex in the crystalline-state: Molecular motion of pentamethylcyclopentadienyl ligands coupled to atom rearrangement in a dithionite ligand

Journal of the American Chemical Society

Volumn 130, Issue 52, 2008, Pages 17836-17845

  Nakai, Hidetaka ^a   Nonaka, Takashi ^a   Miyano, Yousuke ^a   Mizuno, Motohiro ^a   Ozawa, Yoshiki ^b   Toriumi, Koshiro ^b   Koga, Nobuaki ^c   Nishioka, Takanori ^d   Irie, Masahiro ^e   Isobe, Kiyoshi ^a  

^a KANAZAWA UNIVERSITY   (Japan)

^b UNIVERSITY OF HYOGO   (Japan)

^c NAGOYA UNIVERSITY   (Japan)

^d Osaka Prefecture University   (Japan)

^e RIKKYO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ATOM TRANSFER; CHARGE TRANSFER BANDS; CRYSTAL STRUCTURE ANALYSIS; CRYSTALLINE STATE; DFT CALCULATION; DINUCLEAR COMPLEX; DITHIONITE; FORMATION RATES; H NMR SPECTROSCOPY; INTERCONVERSION; MAS NMR; MOLECULAR MOTIONS; MOLECULAR STRESS; ORBITALS; PENTAMETHYLCYCLOPENTADIENYL; PHOTO-IRRADIATION; PHOTOREACTION; PHOTORESPONSIVE; ROOM TEMPERATURE; ROTATIONAL MOTION; STABLE ISOMERS; STEREOSPECIFIC; STERIC HINDRANCES; VARIABLE TEMPERATURE;

ACTIVATION ENERGY; ATOMS; CHARGE TRANSFER; CRYSTAL STRUCTURE; CRYSTALLINE MATERIALS; ION EXCHANGE; ISOMERS; LIGANDS; MOLECULAR OXYGEN; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OPTICAL COMMUNICATION; PHOTOCHROMISM; PHOTOREACTIVITY; RHODIUM; RHODIUM COMPOUNDS; ROTATIONAL FLOW; SANITARY SEWERS; STEREOCHEMISTRY;

PROCESS CONTROL;

CYCLOPENTADIENE DERIVATIVE; DITHIONITE; ORGANORHODIUM DITHIONITE; PENTAMETHYLCYCLOPENTADIENYL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTALLIZATION; ISOMERIZATION;

EID: 67749142095     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja807150a     Document Type: Article

References (59)

1. (a) Irie, M.; Kobatake, S.; Horichi, M. Science 2001, 291, 1769-1772. (b) Kobatake, S.; Takami, S.; Muto, H.; Ishikawa, T.; Irie, M. Nature 2007, 446, 778-781.
2. (c) Garcia-Garibay, M. A. Angew. Chem., Int. Ed. 2007, 46, 8945-8947.
3. (a) Harada, J.; Uekusa, H.; Ohashi, Y. J. Am. Chem. Soc. 1999, 121, 5809-5810.
4. (b) Yamada, T.; Kobatake, S.; Muto, K.; Irie, M. J. Am. Chem. Soc. 2000, 122, 1589-1592.
5. (c) Yamada, T.; Kobatake, S.; Irie, M. Bull. Chem. Soc. Jpn. 2000, 73, 2179-2184.
6. (d) Morimoto, M.; Irie, M. Chem. Commun. 2005, 3895-3905.
7. (e) Harada, J.; Nakajima, R.; Ogawa, K. J. Am. Chem. Soc. 2008, 130, 7085-7091.
8. (a) Boldyreva, E. V. Mol. Cryst. Liq. Cryst. 1994, 242, 17-52.
9. (b) Rack, J. J.; Winkler, J. R.; Gray, H. B. J. Am. Chem. Soc. 2001, 123, 2432-2433.
10. (c) Nishimura, H.; Matsushita, N. Chem. Lett. 2002, 930-931.
11. (d) Coppens, P.; Novozhilova, I.; Kovalevsky, A. Chem. Rev. 2002, 102, 861-883.
12. (e) Kovalevsky, A. Y.; Bagley, K. A.; Cole, J. M.; Coppens, P. Inorg. Chem. 2003, 42, 140-147.
13. (f) Niibayashi, S.; Matsubara, K.; Haga, M.; Nagashima, H. Organometallics 2004, 23, 635-646.
14. Nakai, H.; Mizuno, M.; Nishioka, T.; Koga, N.; Shiomi, K.; Miyano, Y.; Irie, M.; Breedlove, B. K.; Kinoshita, I.; Hayashi, Y.; Ozawa, Y.; Yonezawa, T.; Toriumi, K.; Isobe, K. Angew. Chem., Int. Ed. 2006, 45, 6473-6476.
15. (a) Brown, G. H., Ed. Photochromism; Wiley Interscience: New York, 1971.
16. (b) Irie, M., Ed. Chem. Rev. 2000, 100 (Photochromism: Memories and Switches, Special thematic issue 5).
17. (c) Dürr, H., Bouas-Laurent, H., Eds. Photochromism: Molecules and Systems; Elsevier: Amsterdam, 2003.
18. Bouas-Laurent, H.; Dürr, H. Pure Appl. Chem. 2001, 73, 639-665.
19. (a) Mishra, S. P.; Symons, M. C. R. J. Chem. Soc., Dalton Trans. 1994, 1271-1274.
20. (b) Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6th edition; John Wiley & Sons, Inc.: New York, 1999; pp 527-528.
21. (a) Tennent, N. H.; Su, S. R.; Poffenberger, C. A.; Wojcicki, A. J. Organomet. Chem. 1975, 102, C46-C48.
22. (b) Kubas, G. J.; Wasserman, H. J.; Ryan, R. R. Organometallics 1985, 4, 2012-2021.
23. (c) Matsumoto, K.; Koyama, T.; Koide, Y. J. Am. Chem. Soc. 1999, 121, 10913-10923.
24. (a) Nishioka, T.; Nakamura, S.; Kaneko, Y.; Suzuki, T.; Kinoshita, I.; Kiyooka, S.; Isobe, K. Chem. Lett. 1996, 911-912.
25. (b) Shiomi, K.; Breedlove, B. K.; Kitayama, H.; Nishioka, T.; Kinoshita, I.; Koga, N.; Isobe, K. Chem. Commun. 2002, 1756-1757.
26. (c) Nishioka, T.; Kitayama, H.; Breedlove, B. K.; Shiomi, K.; Kinoshita, I.; Isobe, K. Inorg. Chem. 2004, 43, 5688-5697.
27. Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc. Dalton Trans. 1984, 1215-1221.
28. Lacombe, S.; Loudet, M.; Dargelos, A.; Robert-Banchereau, E. J. Org. Chem. 1998, 63, 2281-2291.
29. Frisch, M. J.; et al. Gaussian 03, revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.
30. (a) Ramamurthy, V.; Venkatesan, K. Chem. Rev. 1987, 87, 433-481.
31. (b) Desiraju, G. R., Ed. Crystal Engineering: The Design of Organic Solids; Elsevier: Amsterdam, 1989.
32. (c) Ohashi, Y. Acta Crystallogr. 1998, A54, 842-849.
33. (d) Braga, D.; Grepioni, F. Angew. Chem., Int. Ed. 2004, 43, 4002-4011.
34. (e) Kawano, M.; Fujita, M. Coord. Chem. Rev. 2007, 251, 2592-2605.
35. (a) Cohen, M. D.; Schmidt, G. M. J. J. Chem. Soc. 1964, 1996-2000.
36. (b) Schmidt, G. M. J. Pure Appl. Chem. 1971, 27, 647-678.
37. (a) Bryan, R. F.; Greene, P. T.; Newlands, M. J.; Field, D. S. J. Chem. Soc. A 1970, 3068-3074.
38. (b) Braga, D. Chem. Rev. 1992, 92, 633-665.
39. (a) Garcia-Garibay, M. A. Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 10771-10776.
40. (b) Khuong, T.-A. V.; Nunez, J. E.; Godinez, C. E.; Garcia-Garibay, M. A. Acc. Chem. Res. 2006, 39, 413-422.
41. (c) Horike, S.; Matsuda, R.; Tanaka, D.; Matsubara, S.; Mizuno, M.; Endo, K.; Kitagawa, S. Angew. Chem., Int. Ed. 2006, 45, 7226-7230.
42. (a) Miyano, Y.; Nakai, H.; Hayashi, Y.; Isobe, K. J. Orgnomet. Chem. 2007, 692, 122-128.
43. (b) Miyano, Y.; Nakai, H.; Mizuno, M.; Isobe, K. Chem. Lett. 2008, 37, 826-827.
44. Kang, J. W.; Maitlis, P. M. J. Organomet. Chem. 1971, 30, 127-133.
45. (a) Stratmann, R. E.; Scuseria, G. E.; Frisch, M. J. J. Chem. Phys. 1998, 109, 8218-8224.
46. (b) Bauernschmitt, R.; Ahlrichs, R. Chem. Phys. Lett. 1996, 256, 454-464.
47. (c) Casida, M. E.; Jamorski, C.; Casida, K. C.; Salahub, D. R. J. Chem. Phys. 1998, 108, 4439-4449.
48. (d) Becke, A. D. J.Chem. Phys. 1993, 98, 5648-5652.
49. (a) Ditchfield, R.; Hehre, W. J.; Pople, J. A. J. Chem. Phys. 1971, 54, 724-728.
50. (b) Hehre, W. J.; Ditchfield, R.; Pople, J. A. J. Chem. Phys. 1972, 56, 2257-2261.
51. (c) Hariharan, P. C.; Pople, J. A. Theo. Chim. Acta 1973, 28, 213-222.
52. (d) Francl, M. M.; Pietro, W. J.; Hehre, W. J.; Binkley, J. S.; Gordon, M. S.; DeFrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654-3665.
53. (e) McLean, A. D.; Chandler, G. S. J. Chem. Phys. 1980, 72, 5639-5648.
54. (f) Krishnan, R.; Binkley, J. S.; Seeger, R.; Pople, J. A. J. Chem. Phys. 1980, 72, 650-654.
55. (g) Frisch, M. J.; Pople, J. A.; Binkley, J. S. J. Chem. Phys. 1984, 80, 3265-3269.
56. (h) Clark, T.; Chandrasekhar, J.; Spitznagel, G. W.; Schleyer, P. V. R. J. Comput. Chem. 1983, 4, 294-301.
57. (i) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299-310.
58. (j) Ehlers, A. W.; Böhme, M.; Dapprich, S.; Gobbi, A.; Höllwarth, A.; Jonas, V.; Köhler, K. F.; Stegmann, R.; Veldkamp, A.; Frenking, G. Chem. Phys. Lett. 1993, 208, 111-114.
59. Steigel, A. Dynamic NMR spectroscopy: NMR basic principles and Progress; Springer: Berlin, 1978; Vol. 15, pp 1-54.