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Volumn 130, Issue 22, 2008, Pages 7085-7091

X-ray diffraction analysis of photochromic reaction of fulgides: Crystalline state reaction induced by two-photon excitation

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; SOLID STATE REACTIONS; TWO PHOTON PROCESSES; X RAY DIFFRACTION ANALYSIS;

EID: 44449164021     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja800353u     Document Type: Article
Times cited : (64)

References (53)
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    • (2000) Chem. Rev , vol.100 , pp. 1683-1890
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    • (a) For reviews, see: Whittal, J. in reference 1b, chapter 9.
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    • (b) Fan, M.-G.; Yu, L.; Zhao, W. in reference 1c, vol. 1 chapter 4.
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  • 11
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    • In the E-form, one of the carbonyl groups of the acid anhydride moiety and the furan ring are in the E configuration
    • In the E-form, one of the carbonyl groups of the acid anhydride moiety and the furan ring are in the E configuration.
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    • In order to obtain good quality data, all of the X-ray diffraction measurements were carried out at 90 K after the photoreactions at room temperature.
    • In order to obtain good quality data, all of the X-ray diffraction measurements were carried out at 90 K after the photoreactions at room temperature.
  • 38
    • 44449090981 scopus 로고    scopus 로고
    • The crystal structure of 1 at 90 K is essentially identical to that at other temperatures reported in the literature, (a) Yoshioka, Y.; Tanaka, T.; Sawada, M.; Irie, M. Chem. Lett. 1989, 19-22.
    • The crystal structure of 1 at 90 K is essentially identical to that at other temperatures reported in the literature, (a) Yoshioka, Y.; Tanaka, T.; Sawada, M.; Irie, M. Chem. Lett. 1989, 19-22.
  • 41
    • 44449153497 scopus 로고    scopus 로고
    • Crystals of 2 are more photoreactive than those of 1. The yellow crystals of 2 easily turn orange under indoor lighting.
    • Crystals of 2 are more photoreactive than those of 1. The yellow crystals of 2 easily turn orange under indoor lighting.
  • 42
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    • The crystal structure of 2 at 90 K is essentially identical to that at room temperature reported in the literature. Reference 15c.
    • The crystal structure of 2 at 90 K is essentially identical to that at room temperature reported in the literature. Reference 15c.
  • 45
    • 44449177052 scopus 로고    scopus 로고
    • Some of the recent applications of the long wavelength irradiation to single crystal photoreactions. Zouev, I, Lavy, T, Kaftory, M, Chem. 2006, 416, 4-4169
    • (a) Some of the recent applications of the long wavelength irradiation to single crystal photoreactions. Zouev, I.; Lavy, T.; Kaftory, M. Eur. J. Org. Chem. 2006, 416, 4-4169.
  • 49
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    • The photoconversion of 1 into its C-form is nearly quantitative even in highly concentrated solutions. This is because the colored form does not act as an internal filter for the activating radiation. Heller, H. G. In CRC Handbook of Organic Photochemistry and Photobiology; Horspool, W. M., Soon, P.-S., Eds.; CRC Press: Boca Raton, FL, 1995; pp 173-183..
    • The photoconversion of 1 into its C-form is nearly quantitative even in highly concentrated solutions. This is because the colored form does not act as an internal filter for the activating radiation. Heller, H. G. In CRC Handbook of Organic Photochemistry and Photobiology; Horspool, W. M., Soon, P.-S., Eds.; CRC Press: Boca Raton, FL, 1995; pp 173-183..
  • 50
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    • This piece of crystal was sliced off from the single crystal used for the X-ray diffraction analysis shown in Table 1 as 1 irradiated with 405 nm
    • This piece of crystal was sliced off from the single crystal used for the X-ray diffraction analysis shown in Table 1 as "1 irradiated with 405 nm".
  • 51
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    • Two-photon absorption mentioned here is simultaneous absorption of two photons by individual molecules and does not mean two sequential one-photon absorption events
    • Two-photon absorption mentioned here is simultaneous absorption of two photons by individual molecules and does not mean two sequential one-photon absorption events.
  • 52
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    • The IR spectra of the reacted crystals confirmed that the product obtained by the laser light irradiation was identical to that obtained by steady UV light irradiation
    • The IR spectra of the reacted crystals confirmed that the product obtained by the laser light irradiation was identical to that obtained by steady UV light irradiation.
  • 53
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    • Photochromic reaction by means of two-photon excitation was reported to take place in polymer matrix of 1. Parthenopoulos, D. A, Rentzepis, P. M. J. Appl. Phys. 1990, 68, 5814-5818
    • Photochromic reaction by means of two-photon excitation was reported to take place in polymer matrix of 1. Parthenopoulos, D. A.; Rentzepis, P. M. J. Appl. Phys. 1990, 68, 5814-5818.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.