Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex

Angewandte Chemie - International Edition

Volumn 45, Issue 39, 2006, Pages 6473-6476

  Nakai, Hidetaka ^a   Mizuno, Motohiro ^a   Nishioka, Takanori ^b   Koga, Nobuaki ^d   Shiomi, Kimie ^b   Miyano, Yousuke ^a   Irie, Masahiro ^e   Breedlove, Brian K ^b   Kinoshita, Isamu ^b   Hayashi, Yoshihito ^a   Ozawa, Yoshiki ^c   Yonezawa, Takae ^c   Toriumi, Koshiro ^c   Isobe, Kiyoshi ^a  

^a KANAZAWA UNIVERSITY   (Japan)

^b Osaka Prefecture University   (Japan)

^c UNIVERSITY OF HYOGO   (Japan)

^d NAGOYA UNIVERSITY   (Japan)

^e KYUSHU UNIVERSITY   (Japan)

Author keywords

Photochemistry; Photochromism; Rhodium; S ligands; Solid state reactions

Indexed keywords

DINUCLEAR RHODIUM COMPLEXES; S LIGANDS; SOLID-STATE REACTIONS; STEREOSPECIFIC TRANSFORMATION;

COMPLEXATION; PHOTOCHEMICAL REACTIONS; PHOTOCHROMISM; SINGLE CRYSTALS; STEREOCHEMISTRY; X RAY DIFFRACTION;

RHODIUM COMPOUNDS;

EID: 33749869016     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200601702     Document Type: Article

References (20)

1. Special edition: Photochromism: Memories and Switches (Ed.: M. Irie), Chem. Rev. 2000, 100.
2. Molecular Switches (Ed.: B. L. Feringa), Wiley-VCH, Weinheim, 2001.
3. J. J. D. de Jong, L. N. Lucas, R. M. Kellogg, J. H. van Esch, B. L. Feringa, Science 2004, 304, 278.
4. M. Irie, S. Kobatake, M. Horichi, Science 2001, 291, 1769.
5. S. Yamamoto, K. Matsuda, M. Irie, Angew. Chem. 2003, 115, 1589;
6. Angew. Chem. Int. Ed. 2003, 42, 1636.
7. E. V. Boldyreva, Mol. Cryst. Liq. Cryst. 1994, 242, 17.
8. J. Harada, H. Uekusa, Y. Ohashi, J. Am. Chem. Soc. 1999, 121, 5809.
9. T. Yamada, S. Kobatake, K. Muto, M. Irie, J. Am. Chem. Soc. 2000, 122, 1589.
10. T. Yamada, S. Kobatake, M. Irie, Bull. Chem. Soc. Jpn. 2000, 73, 2179.
11. M. Morimoto, M. Irie, Chem. Commun. 2005, 3895.
12. T. Nishioka, H. Kitayama, B. K. Breedlove, K. Shiomi, I. Kinoshita, K. Isobe, Inorg. Chem. 2004, 43, 5688.
13. F. A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry, 5th ed., Wiley-Interscience, New York, 1988, p. 522.
14. S. Lacombe, M. Loudet, A. Dargelos, E. Robert-Banchereau, J. Org. Chem. 1998, 63, 2281.
15. H. Dürr, H. Bouas-Laurent, Photochromism: Molecules and Systems, Elsevier, Amsterdam, 2003, p. 1032.
16. Results on the photoreactivity of 1 in solution will be published elsewhere.
17. The absorption spectra in Figure S1 in the Supporting Information were measured on the same sample before and after irradiation.
18. Y. Ohashi, Acta Crystallogr. Sect. A 1998, 54, 842.
19. P. Coppens, I. Novozhilova, A. Kovalevsky, Chem. Rev. 2002, 102, 861.
20. A. Y. Kovalevsky, K. A. Bagley, J. M. Cole, P. Coppens, Inorg. Chem. 2003, 42, 140.