Spin dynamics in the negatively charged terbium (III) bis-phthalocyaninato complex

Journal of the American Chemical Society

Volumn 131, Issue 12, 2009, Pages 4387-4396

  Branzoli, Francesca ^a   Carretta, Pietro ^a   Filibian, Marta ^a   Zoppellaro, Giorgio ^c,e   Graf, Michael J ^b   Galan Mascaros, Jose R ^d   Fuhr, Olaf ^c   Brink, Susan ^c   Ruben, Mario ^c  

^a UNIVERSITY OF PAVIA   (Italy)

^b BOSTON COLLEGE   (United States)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^d UNIVERSITY OF VALENCIA   (Spain)

^e UNIVERSITY OF OSLO   (Norway)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; CRYOGENIC TEMPERATURES; CRYSTAL-FIELD LEVELS; DATA STORAGE; DIAMAGNETIC MATRIX; ELECTRON SPIN DYNAMICS; H NMR SPECTROSCOPY; HIGH TEMPERATURE; LOW ENERGIES; MATRIX ARRANGEMENT; METAL CENTERS; PHONON ASSISTED TRANSITION; SINGLE-ION; SINGLE-MOLECULE; TETRABUTYLAMONIUM BROMIDES; THEORETICAL STUDY; TUNNELING PROCESS; TUNNELING RATES;

CRYSTAL SYMMETRY; DYNAMICS; MAGNETIC PROPERTIES; MOLECULES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; TERBIUM; TERBIUM ALLOYS; TUNNELING (EXCAVATION); WIND TUNNELS;

SPIN DYNAMICS;

BIS PHTHALOCYANINATO TERBIUM; BROMINE DERIVATIVE; TERBIUM; TETRABUTYLAMONIUM BROMIDE; UNCLASSIFIED DRUG; ION; METAL; QUATERNARY AMMONIUM DERIVATIVE; TETRABUTYLAMMONIUM;

ARTICLE; ELECTRON SPIN RESONANCE; HIGH TEMPERATURE; MAGNETIC FIELD; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SYNTHESIS; X RAY CRYSTALLOGRAPHY; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; CRYSTALLIZATION; MAGNETISM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROCEDURES; SPECTROPHOTOMETRY; STATISTICAL MODEL; TEMPERATURE;

CRYSTALLIZATION; IONS; MAGNETIC RESONANCE SPECTROSCOPY; MAGNETICS; METALS; MODELS, STATISTICAL; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; QUATERNARY AMMONIUM COMPOUNDS; SPECTROPHOTOMETRY; TEMPERATURE; TERBIUM;

EID: 67749097786     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja808649g     Document Type: Article

References (72)

1. Coronado, E.; Day, P. Chem. Rev. 2004, 104, 5419-5448.
2. Gatteschi, D., Kahn, O., Miller, J. S., Palacio, F., Eds. Magnetic Molecular Materials; NATO ASI Series 198, Kluwer Academic Publishers: Dordrecht, 1991.
3. Kahn, O. Molecular Magnetism; Wiley-VCH Inc.: New York, 1993.
4. (a) Miller, J. S., Drillon, M., Eds. Magnetism: Molecules to Materials; Wiley-VCH Verlag: Weinheim, 2001; Vol. I, Models and Experiments.
5. (b) Miller, J. S., Drillon, M., Eds. Magnetism: Molecules to Materials; Wiley-VCH Verlag: Weinheim, 2001; Vol. II, Molecule-Based Materials.
6. (c) Miller, J. S., Drillon, M., Eds. Magnetism: Molecules to Materials; Wiley-VCH Verlag: Weinheim, 2002; Vol. III, Nanosized Magnetic Materials.
7. (d) Miller, J. S., Drillon, M., Eds. Magnetism: Molecules to Materials; Wiley-VCH Verlag: Weinheim, 2003; Vol. IV.
8. (e) Miller, J. S., Drillon, M., Eds. Magnetism: Molecules to Materials; Wiley-VCH Verlag: Weinheim, 2005; Vol. V.
9. Thomas, L.; Lionti, F.; Ballau, R.; Gatteschi, D.; Sessoli, R.; Barbara. B. Nature 1996, 383, 145-147.
10. Gatteschi, D.; Sessoli, R. Angew. Chem., Int. Ed. 2003, 42, 268-297.
11. Friedman, J. R.; Sarachick, M. P.; Tejada, J.; Ziolo, R. Phys. Rev. Lett. 1996, 76, 3830-3833.
12. Wernsdorfer, W.; Sessoli, R. Science 1999, 284, 133-135.
13. Christou, G.; Gatteschi, D.; Hendrichson, D. N.; Sessoli, R. MRS Bull. 2000, 25, 66-71.
14. Aromi, G.; Aubin, S. M. J.; Bolcar, M. A.; Christou, G.; Eppley, H. J.; Folfting, K.; Hendrickson, D. N.; Huffman, J. C.; Squire, R. C.; Tsai, H.-L.; Wang, S.; Wemple, M. W. Polyhedron 1998, 17, 3005-3020.
15. Lis, T. Acta Crystallogr. 1980, B36, 2042-2046.
16. Sessoli, R.; Tsai, H.-L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804-1816.
17. Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141-143.
18. Eppley, H. J.; Tsai, H.-L.; de Vries, N.; Folting, K.; Christou, G.; Hendrickson, D. N J. Am. Chem. Soc. 1995, 117, 301-317.
19. Aubin, S. M. J.; Sun, Z.; Pardi, L.; Krzystek, J.; Folting, K.; Brunel, L.-C.; Rheingold, A. L.; Christou, G.; Hendrickson, D. N. Inorg. Chem. 1999, 38, 5329-5340.
20. Boskovic, C.; Pink, M.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2001, 123, 9914-9915.
21. Soler, M.; Chandra, S. K.; Ruiz, D.; Davidson, E. R.; Hendrickson, D. N.; Christou, G. Chem. Commun. 2000, 24, 2417-2418.
22. Brechin, E. K.; Boskovic, C.; Wernsdorfer, W.; Yoo, J.; Yamaguchi, A.; Sanudo, E. C.; Concolino, T. R.; Rheingold, A. L.; Ishimoto, H.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2002, 124, 9710-9711.
23. Soler, M.; Wernsdorfer, W.; Folting, K.; Pink, M.; Christou, G. J. Am. Chem. Soc. 2004, 126, 2156-2165.
24. Sangregorio, C.; Ohm, T.; Paulsen, C.; Sessoli, R.; Gatteschi, D. Phys. Rev. Lett. 1997, 78, 4645-4648.
25. Aubin, S. M. J.; Wemple, M. W.; Adams, D. M.; Tsai, H.-L.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1996, 11, 7746-7754.
26. (a) Aubin, S. M. J.; Dilley, N. R.; Pardi, L.; Krzystek, J.; Wemple, M. W.; Brunel, L. C.; Maple, M. B.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1998, 120, 4991-5004.
27. (b) Aubin, S. M. J.; Dilley, N. R.; Wemple, M. W.; Maple, M. B.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1998, 120, 839-840.
28. Andres, H.; Basler, R.; Gudel, H.-U.; Aromi, G.; Christou, G.; Buttner, H.; Ruffle, B. J. Am. Chem. Soc. 2000, 122, 12469-12477.
29. (24)(a) Schelter, E. J.; Karadas, F.; Avendano, C.; Prosvirin, A. V.; Wernsdorfer, W.; Dunbar, K. R. J. Am. Chem. Soc. 2007, 129, 8139-8149.
30. (b) Muller, A.; Peters, F.; Pope, M. T.; Gatteschi, D. Chem. Rev. 1998, 98, 239-271.
31. Castro, S. L.; Sun, Z.; Grant, C. M.; Bollinger, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1998, 120, 2365-2375.
32. Gatteschi, D.; Sessoli, R.; Villain, J. Molecular Nanomagnets; Oxford University Press; New York, 2006.
33. Goodwin, J. C.; Sessoli, R.; Gatteschi, D.; Wernsdorfer, W.; Powell, A. K.; Heath, S. L. J. Chem. Soc., Dalton Trans. 2000, 12, 1835-1840.
34. Boskovic, C.; Bircher, R.; Tregenna-Piggott, P. L. W.; Gudel, H. U.; Paulsen, C.; Wernsdorfer, W.; Barra, A.-L.; Khatsko, E.; Neels, A.; Stoeckli-Evans, H. J. Am. Chem. Soc. 2003, 125, 14046-14058.
35. Wernsdorfer, W.; Aliaga-Alcalde, N.; Hendrickson, D. N.; Christou, G. Nature 2002, 416, 406-409.
36. Tiron, R.; Wernsdorfer, W.; Foguet-Albiol, D.; Aliaga-Alcalde, N.; Christou, G. Phys. Rev. Lett. 2003, 91, 227203.
37. Miyasaka, H.; Yamashita, M. Dalton Trans. 2007, 399-406.
38. Bogani, L.; Wernsdorfer, W. Nat. Mater. 2008, 7, 179-186.
39. DiVincenzo, D. P. Science 1995, 270, 255-261.
40. (a) Leuenberger, M. N.; Loss, D. Nature 2001, 410, 789-793.
41. (b) Affronte, M.; Troiani, F.; Ghirri, A.; Candini, A.; Evangelisti, M.; Corradini, V.; Santini, P.; Amoretti, G.; Tuna, G.; Winpenny, R. E. P. J. Phys. D: Appl. Phys. 2007, 40, 2999-3004.
42. (c) Wernsdorfer, W. Nat. Mater. 2007, 6, 174-176.
43. Bertaina, S.; Gambarelli, S.; Mitra, T.; Tsukerblat, B.; Miiller, A.; Barbara, B. Nature 2008, 453, 203-206.
44. Aromi, G.; Claude, J.-P.; Knapp, M. J.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1998, 120, 2977-2978.
45. Milios, C. J.; Vinslava, A.; Wernsdorfer, W.; Moggach, S.; Parsons, S.; Perlepes, S. P.; Christou, G.; Brechin, E. K. J. Am. Chem. Soc. 2007, 129, 2754-2755.
46. Chakov, N. E.; Lee, S.-C.; Harter, A. G.; Kuhns, P. L.; Reyes, A. P.; Hill, S. O.; Dalal, N. S.; Wernsdorfer, W.; Abboud, K.; Christou, G. J. Am. Chem. Soc. 2006, 128, 6975-6989.
47. Ishikawa, N.; Sugita, M.; Ishikawa, T.; Koshihara, S.; Kaizu, Y. J. Am. Chem. Soc. 2003, 125, 8694-8695.
48. Ishikawa, N.; Sugita, M.; Ishikawa, T.; Koshihara, S.; Kaizu, Y. J. Phys. Chem. B 2004, 108, 11265-11271.
49. Ishikawa, N.; Sugita, M.; Wernsdorfer, W. J. Am. Chem. Soc. 2005, 127, 3650-3651.
50. (a) Giraud, R.; Wernsdorfer, W.; Tkachuk, A.; Mailly, D.; Barbara, B. Phys. Rev. Lett. 2001, 87, 057203.
51. (b) Giraud, R.; Tkachuk, A. M.; Barbara, B. Phys. Rev. Lett. 2003, 91, 257204.
52. Kirinp, I. S.; Moskalev, P. N.; Makashev, Y. A. Russ. J. Inorg. Chem. 1965, 10, 1065-1066.
53. Kirinp, I. S.; Moskalev, P. N.; Makashev, Y. A. Russ. J. Inorg. Chem. 1967, 12, 369-372.
54. Kirin, I. S.; Shelekhi, Y. L.; Moskalev, Y. A. Sov. Phys. Solid State (Engl. Transl.) 1967, 9, 1461.
55. Decian, A.; Moussavi, M.; Fischer, J.; Weiss, R. Inorg. Chem. 1985, 24, 3162-3167.
56. Trojan, K. L.; Hatfield, W. E.; Kepler, K. D.; Kirk, M. L. J. Appl. Phys. 1991, 69, 6007-6009.
57. Trojan, K. L.; Kendall, J. L.; Kepler, K. D.; Hatfield, W. E. Inorg. Chim. Acta 1992, 198, 795-803.
58. Moussavi, M.; De Cian, A.; Fischer, J.; Weiss, R. Inorg. Chem. 1988, 27, 1287-1291.
59. Haghighi, M. S.; Teske, Ch. R. L.; Honborg, H. Z. Anorg. Allg. Chem. 1992, 608, 73-80.
60. Koike, N.; Uekusa, H.; Ohashi, Y.; Harnoode, C.; Kitamura, F.; Ohsaka, T.; Tokuda, K. Inorg. Chem. 1996, 35, 5798-5804.
61. Kasuga, K.; Tsutsui, M.; Petterson, R. C.; Tatsumi, K.; Van Opden- bosch, N.; Pepe, G.; Meyer, E. F. J. Am. Chem. Soc. 1980, 102, 4835-4836.
62. Loosli, C.; Liu, S.-X.; Neels, A.; Labat, G.; Decurtins, S. Z. Kristallogr. 2006, 221, 135-141.
63. Konami, H.; Hatano, M.; Kobayashi, N.; Osa, T. Chem. Phys. Lett. 1990, 165, 397-400.
64. Harnoode, C.; Takamura, K.; Kubota, H.; Sho, K.; Fujisawa, K.; Kitamura, F.; Ohsaka, T.; Tokuda, K. Electrochemistry 1999, 67, 832-838.
65. Ishikawa, N.; Sugita, M.; Wernsdorfer, W. Angew. Chem., Int. Ed. 2005, 44, 2931-2935.
66. Ishikawa, N. Polyhedron 2007, 26, 2147-2153.
67. Ishikawa, N.; Sugita, M.; Okubo, T.; Tanaka, N.; Iino, T.; Kaizu, Y. Inorg. Chem. 2003, 42, 2440-2446.
68. (59)Lascialfari, A.; Jang, Z. H.; Borsa, F.; Carretta, P.; Gatteschi, D. Phys. Rev. Lett. 1998, 81, 3773-3776.
69. Vitali, L.; Fabris, S.; Mosca Conte, A.; Brink, S.; Ruben, M.; Baroni, S.; Kern, K. Nano Lett. 2008, 8, 3364-3368.
70. Osorio, E.; Bjornholm, T.; Lehn, J.-M.; Ruben, M.; van der Zant, H. S. J. J. Phys.: Condens. Matter 2008, 20, 374121-374131.
71. Ruben, M.; Landa, A.; Lortscher, E.; Riel, H.; Mayor, M.; Gorls, H.; Weber, H. B.; Arnold, A.; Evers, V. Small 2008, 12, 2229-2235.
72. Branzoli, F. Unpublished work.