Ferromagnetic and Antiferromagnetic Intermolecular Interactions in a New Family of Mn4 Complexes with an Energy Barrier to Magnetization Reversal

Journal of the American Chemical Society

Volumn 125, Issue 46, 2003, Pages 14046-14058

  Boskovic, Colette ^a   Bircher, Roland ^a   Tregenna Piggott, Philip L W ^a   Güdel, Hans U ^a   Paulsen, Carley ^b   Wernsdorfer, Wolfgang ^b   Barra, Anne Laure ^c   Khatsko, Eugene ^d   Neels, Antonia ^e   Stoeckli Evans, Helen ^e  

^a UNIVERSITY OF BERN   (Switzerland)

^b LABORATOIRE DE CRISTALLOGRAPHIE   (France)

^c GRENOBLE HIGH MAGNETIC FIELD LABORATORY   (France)

^d B VERKIN INSTITUTE FOR LOW TEMPERATURE PHYSICS AND ENGINEERING   (Ukraine)

^e UNIVERSITY OF NEUCHÂTEL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERROMAGNETISM; COMPLEXATION; FERROMAGNETISM; MAGNETIC ANISOTROPY; MAGNETIC RELAXATION; MAGNETIZATION; PARAMAGNETIC RESONANCE; PHASE TRANSITIONS; SYNTHESIS (CHEMICAL); TEMPERATURE;

MAGNETOCHEMICAL STUDIES;

ORGANOMETALLICS;

FERROMAGNETIC MATERIAL; MANGANESE DERIVATIVE;

ANISOTROPY; ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; ENERGY; HYSTERESIS; LOW TEMPERATURE; MAGNETISM; MEASUREMENT; MOLECULAR INTERACTION; PHASE TRANSITION; SOLVATION; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0242582484     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0367086     Document Type: Article

References (60)

1. (a) Sessoli, R.; Tsai, H.-L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804.
2. (b) Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141.
3. (c) Christou, G.; Gatteschi, D.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25, 56.
4. (a) Novak, M. A.; Sessoli, R. In Quantum Tunneling of the Magnetization; Gunther, L., Barbara, B., Eds.; NATO ASI Series E: Kluwer: Dordrecht, 1995; Vol. 301.
5. (b) Friedman, J. R.; Sarachik, M. P. Phys. Rev. Lett. 1996, 76, 3830.
6. (c) Thomas, L.; Lionti, F.; Ballou, R.; Gatteschi, D.; Sessoli, R.; Barbara, B. Nature 1996, 383, 145.
7. (d) Gatteschi, D.; Sessoli, R. Angew. Chem., Int. Ed. 2003, 42, 268.
8. (a) Eppley, H. J.; Christou, G.; Law, N. A.; Pecoraro, V. L. Inorg. Synth. 2002, 33, 61.
9. (b) Eppley, H. J.; Tsai, H.-L.; de Vries, N.; Folting, K.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1995, 117, 301.
10. (c) Soler, M.; Wernsdorfer, W.; Abboud, K. A.; Huffman, J. C.; Davidson, E. R.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2003, 125, 3576.
11. (d) Artus, P.; Boskovic, C.; Yoo, J.; Streib, W. E.; Brunel, L.-C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 2001, 40, 4199.
12. (e) Boskovic, C.; Pink, M.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2001, 123, 9914.
13. (a) Aubin, S. M. J.; Wemple, M. W.; Adams, D. M.; Tsai, H.-L.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1996, 118, 7746.
14. (b) Yoo, J.; Brechin, E. K.; Yamaguchi, A.; Nakano, M.; Huffman, J. C.; Maniero, A. L.; Brunel, L.-C.; Awaga, K.; Ishimoto, H.; Christou, G.; Hendrickson, D. N. Inorg. Chem. 2000, 39, 3615.
15. (c) Yoo, J.; Yamaguchi, A.; Nakano, M.; Krzystek, J.; Streib, W. E.; Brunel, L.-C.; Ishimoto, H.; Christou, G.; Hendrickson, D. N. Inorg. Chem. 2001, 40, 4604.
16. (d) Boskovic, C.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 2002, 41, 5107.
17. (e) Boskovic, C.; Brechin, E. K.; Streib, W. E.; Folting, K.; Bollinger, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2002, 124, 3725.
18. (f) Brechin, E. K.; Boskovic, C.; Wernsdorfer, W.; Yoo, J.; Yamaguchi, A.; Sañudo, E. C.; Concolino, T. R.; Rheingold, A. L.; Ishimoto, H.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2002, 124, 9710.
19. (g) Brechin, E. K.; Soler, M.; Davidson, J.; Hendrickson, D. N.; Parsons, S.; Christou, G. Chem. Commun. 2002, 2252.
20. (h) Barra, A.-L.; Caneschi, A.; Gatteschi, D.; Goldberg, D. P.; Sessoli, R. J. Solid State Chem. 1999, 145, 484.
21. (a) Sangregorio, C.; Ohm, T.; Paulsen, C.; Sessoli, R.; Gatteschi, D. Phys. Rev. Lett. 1997, 78, 4645.
22. (b) Barra, A.-L.; Caneschi, A.; Cornia, A.; deBiani, F. F.; Gatteschi, D.; Sangregorio, C.; Sessoli, R.; Sorace, L. J. Am. Chem. Soc. 1999, 121, 5302.
23. (c) Oshio, H.; Hoshino, N.; Ito, T. J. Am. Chem. Soc. 2000, 120, 2997.
24. (d) Goodwin, J. C.; Sessoli, R.; Gatteschi, D.; Wernsdorfer, W.; Powell, A. K.; Heath, S. L. J. Chem. Soc., Dalton Trans. 2000, 1835.
25. (a) Andres, H.; Basler, R.; Blake, A. J.; Cadiou, C.; Chaboussant, G.; Grant, C. M.; Güdel, H. U.; Murrie, M.; Parsons, S.; Paulsen, C.; Semadini, F.; Villar, V.; Wernsdorfer, W.; Winpenny, R. E. P. Chem.-Eur. J. 2002, 8, 4867.
26. (b) Ochsenbein, S. T.; Murrie, M.; Rusanov, E.; Stoeckli-Evans, H.; Sekine, C.; Güdel, H.-U. Inorg. Chem. 2002, 41, 5133.
27. Wernsdorfer, W.; Aliaga-Alcalde, N.; Hendrickson, D. N.; Christou, G. Nature 2002, 416, 406.
28. (a) Yamaguchi, A.; Kusumi, N.; Ishimoto, H.; Mitamura, H.; Goto, T.; Mori, N.; Nakano, M.; Awaga, K.; Yoo, J.; Hendrickson, D. N.; Christou, G. J. Phys. Soc. Jpn. 2002, 71, 414.
29. (b) Affronte, M.; Lasjaunias, J. C.; Wernsdorfer, W.; Sessoli, R.; Gatteschi, D.; Heath, S. L.; Fort, A.; Rettori, A. Phys. Rev. B 2002, 66, 064408.
30. (a) Asada, H.; Ozeki, M.; Fujiwara, M.; Matsushita, T. Chem. Lett. 1999, 525.
31. (b) Dey, M.; Rao, C. P.; Saarenketo, P. K.; Rissanen, K. Inorg. Chem. Commun. 2002, 5, 924.
32. (a) Boskovic, C.; Rusanov, E.; Stoeckli-Evans, H.; Güdel, H. U. Inorg. Chem. Commun. 2002, 5, 881.
33. (b) Basler, R.; Boskovic, C.; Chaboussant, G.; Güdel, H. U.; Murrie, M.; Ochsenbein, S. T.; Sieber, A. ChemPhysChem 2003, 4, 910.
34. (a) Chumakov, Y. M.; Biyushkin, V. N.; Malinovskii, T. I.; Kulemu, S.; Tsapkov, V. I.; Popov, M. S.; Samus, N. M. Koord Khim. 1990, 16, 945.
35. (b) Nihei, M.; Hoshino, N.; Ito, T.; Oshio, H. Polyhedron 2003, 22, 2359.
36. (c) Butler, K. D.; Murray, K. S.; West, B. O. Aust. J. Chem. 1971, 24, 2249.
37. IPDS Software; Stoe & Cie GmbH: Darmstadt, Germany, 2000.
38. Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467.
39. Sheldrick, G. M. SHELXL-97: Program for Crystal Structure Refinement; Universität Göttingen: Göttingen, Germany, 1999.
40. Spek, A. L. Acta Crystallogr., Sect. A 1990, 46, C34.
41. Wernsdorfer, W. Adv. Chem. Phys. 2001, 118, 99.
42. Borrás-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Tsukerblatt, B. S. Inorg. Chem. 1999, 38, 6081.
43. (a) Muller, F.; Hopkins, A.; Coron, N.; Ggrynberg, M.; Brunel, L.-C.; Martinez, G. Rev. Sci. Instrum. 1989, 60, 3681.
44. (b) Barra, A.-L.; Brunel, L.-C.; Robert, J. B. Chem. Phys. Lett. 1990, 165, 107.
45. Weihe, H. Sim version 2001.6; Department of Chemistry, H.C. Ørsted Institutt, University of Copenhagen: Copenhagen, Denmark, 2001.
46. Boskovic, C.; Neels, A.; Stoeckli-Evans, H.; Güdel, H.-U. Unpublished observations.
47. (a) Abbati, G. L.; Cornia, A.; Fabretti, A. C.; Caneschi, A.; Gatteschi, D. Inorg. Chem. 1998, 37, 1430.
48. (b) Abbati, G. L.; Cornia, A.; Fabretti, A. C.; Caneschi, A.; Gatteschi, D. Inorg. Chem. 1998, 37, 3759.
49. (c) Aromí, G.; Bell, A.; Teat, S. J.; Whittaker, A. G.; Winpenny, R. E. P. Chem Commun. 2002, 1896.
50. (a) Desiraju, G. R.; Steiner, T. The Weak Hydrogen Bond; Oxford University Press: Oxford, 1999 and refs therein.
51. (b) Desiraju, G. R. Acc. Chem. Res. 2002, 35, 565 and refs therein.
52. Chiorescu, I.; Wernsdorfer, W.; Müller, A.; Bogge, H.; Barbara, B. Phys. Rev. Lett. 2000, 84, 3454.
53. Carlin, R. L. Magnetochemistry; Springer-Verlag: Berlin, 1986.
54. Barra, A.-L.; Brunel, L.-C.; Gatteschi, D.; Pardi, L.; Sessoli, R. Acc. Chem. Res. 1998, 31, 460 and refs therein.
55. Edwards, R. S.; Maccagnano, S.; Yang, E.-C.; Hill, S.; Wernsdorfer, W.; Hendrickson, D. N.; Christou, G. J. Appl. Phys. 2003, 93, 7807 and refs therein.
56. Murray, K. S. Adv. Inorg. Chem. 1995, 43, 261.
57. (a) Wang, S.; Tsai, H.-L.; Libby, E.; Folting, K.; Streib, W. E.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1996, 35. 7578.
58. (b) Aromí, G.; Knapp, M. J.; Claude, J.-P.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1999, 121, 5489.
59. Van Langenberg, K.; Batten, S. R.; Berry, K. J.; Hockless, D. C. R.; Moubaraki, B.; Murray, K. S. Inorg. Chem. 1997, 36, 5006 and refs therein.
60. Morello, A.; Mettes, F. L.; Luis, F.; Fernández, J. F.; Krzystek, J.; Aromí, G.; Christou, G.; de Jongh L. J. Phys. Rev. Lett. 2003, 90, 017206/1.