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Volumn 12, Issue 8, 2009, Pages 711-715

Rare monomeric structure of CpRh(III) dithiolene complex: Combined ESR and electronic absorption studies on electrochemically generated Rh(II) species

Author keywords

Dithiolene; Electrochemistry; ESR; Monomeric structure; Rhodium

Indexed keywords


EID: 67651233508     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.05.021     Document Type: Article
Times cited : (3)

References (64)
  • 1
  • 28
    • 67651231194 scopus 로고    scopus 로고
    • CrystEngCommun , in press, doi:10.1039/b823200h
    • M. Fourmigué, T. Cauchy, M. Nomura, CrystEngCommun (2004), in press, doi:10.1039/b823200h.
    • (2004)
    • Fourmigué, M.1    Cauchy, T.2    Nomura, M.3
  • 54
    • 67651219733 scopus 로고    scopus 로고
    • note
    • The single crystal of 1 was obtained by recrystallization from the dichloromethane/n-hexane. Data were collected on a Rigaku imaging plate diffractometer with graphite-monochromated Mo Kα radiation (λ = 0.71073 Å). The structure was solved by direct methods (SIR92) and expanded Fourier techniques. The non-hydrogen atoms were refined anisotropically. Hydrogen atoms were introduced at calculated positions (riding model), included in structure factor calculations, and these were not refined. Absorption corrections were applied. Idealized positions of complex were used for the Crystal Structure crystallographic software package of Molecular Structure Corp.
  • 55
    • 67651225926 scopus 로고    scopus 로고
    • note
    • int = 0.016), R(I > 2σ(I)) = 0.0354 and Rw(I > 2σ(I)) = 0.0899, GOF = 1.011.
  • 58
    • 67651225925 scopus 로고    scopus 로고
    • note
    • -3 dichloromethane solution (or acetonitrile) of complex 1.
  • 59
    • 67651217626 scopus 로고    scopus 로고
    • note
    • -3 tetra-n-butylammonium perchlorate at 25 °C in an optically transparent thin-layer electrode (OTTLE, thin-layer thickness 0.4 mm) cell by using a Photal MCPD-7000 rapid scan spectrometer. The working electrode was stationary platinum mesh in thin-layer form.
  • 60
    • 67651227930 scopus 로고    scopus 로고
    • note
    • -3 tetra-n-butylammonium perchlorate of complex 1 was used for ESR measurements.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.