Paramagnetic Cp/Dithiolene Complexes as Molecular Hinges: Interplay of Metal/Ligand Electronic Delocalization and Solid-State Magnetic Behavior

Accounts of Chemical Research

Volumn 37, Issue 3, 2004, Pages 179-186

  Fourmigué, Marc ^a  

^a UNIVERSITÉ D'ANGERS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; CYCLOPENTADIENE DERIVATIVE; DITHIOL DERIVATIVE; LIGAND; METAL; NIOBIUM; URANIUM DERIVATIVE; VANADIUM DERIVATIVE;

ARTICLE; COMPLEX FORMATION; MAGNETISM; MOLECULAR DYNAMICS; OXIDATION; SOLID STATE;

EID: 1642315211     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar030214w     Document Type: Article

References (55)

1. Williams, R.; Billig, E.; Waters, J. H.; Gray, H. B. The Toluenedithiolate and Maleonitriledithiolate Square-Matrix Systems. J. Am. Chem. Soc. 1966, 88, 43-50.
2. Schrauzer, G. N.; Mayweg, V. Reaction of Diphenylacetylene with Nickel Sulfides. J. Am. Chem. Soc. 1962, 84, 3221-3221.
3. Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H. E.s.r. Studies of Four-Coordinate Complexes of Nickel, Palladium and Platinum Related by Electron-Transfer Reactions. J. Am. Chem. Soc. 1963, 85, 2029-2030.
4. Mueller-Westerhoff, U. T.; Vance, B. Dithiolenes and Related Species. In Comprehensive Coordination Chemistry, Wilkinson, G., Ed., Pergamon Press: Oxford, U.K., 1987; Chapter 16.5, pp 595-631.
5. Ward, M. D.; McCleverty, J. A. Noninnocent behaviour in mononuclear and polynuclear complexes: consequences for redox and electronic spectroscopic properties. J. Chem Soc., Dalton Trans. 2002, 275-288.
6. Clemenson, P. I. The Chemistry and Solid State Properties of Nickel, Palladium and Platinum bis(Maleonitriledithiolate) Compounds. Coord. Chem. Rev. 1990, 106, 171-203.
7. Cassoux, P.; Valade, L.; Kobayashi, H.; Kobayashi, A.; Clark, R. A.; Underhill, A. E. Molecular Metals and Superconductors Derived from Metal Complexes of 1,3-Dithiol-2-thione-4,5-ditholate (dmit). Coord. Chem. Rev. 1991, 110, 115-160.
8. Robertson, N.; Cronin, L. Metal bis-1,2-Dithiolene Complexes in Conducting or Magnetic Cystalline Assemblies. Coord. Chem. Rev. 2002, 227, 93-127.
9. Pullen, A. E.; Olk, R.-M. The Coordination Chemistry of 1,3-Dithiole-2-thione-4,5-dithiolate (dmit) and Isologs. Coord. Chem. Rev. 1999, 188, 211-262.
10. Watanabe, E.; Fujiwara, M.; Yamaura, J.; Kato, R. Synthesis and properties of novel donor-type metal-dithiolene complexes based on 5,6-dihydro-1,4-dioxine-2,3-dithiol (edo). J. Mater. Chem. 2001, 11, 2131-2141.
11. Tanaka, H.; Okano, Y.; Kobayashi, H.; Suzuki, W.; Kobayashi, A. A Three-Dimensional Synthetic Metallic Crystal Composed of Single-Component Molecules. Science 2001, 291, 285-287.
12. 2. Phys. Rev. B 2002, 6508-6511.
13. 3]. Inorg. Chem. 1993, 32, 5990-5996.
14. .. Bull. Soc. Chim. Fr. 1993, 130, 761-771.
15. Fourmigué, M. Mixed Cyclopentadienyl/Dithiolene Complexes. Coord. Chem. Rev. 1998, 178-180, 823-864.
16. 5)]. J. Chem. Soc., Dalton Trans. 1996, 2261-2267.
17. King, R. B. Organosulfur Derivatives of the Metal Carbonyls. V. The Reactions between Certain Organic Sulfur Compounds and Various Cyclopentadienyl Metal Carbonyl Complexes. J. Am. Chem. Soc. 1963, 85, 1587-1590.
18. Sellmann, D.; Unger, E. Synthese und Eigenschaften von Eisenund Molybdän-Komplexen mit Schwefelliganden. Z. Naturforsch. B 1978, 33, 1438-1442.
19. 2. Organometallics 1985, 4, 1315-1318.
20. Casey, A. T.; Raynor, J. B. Electron Spin Resonance studies of some Bis(cyclopentadienyl) Complexes of Vanadium(IV) and Niobium(IV). J. Chem. Soc., Dalton Trans. 1983, 2057-2062.
21. Zeltner, S.; Dietzsch, W.; Olk, R.-M.; Kirmse, R.; Richter, R.; Schröder, U.; Olk, B.; Hoyer, E. Synthese und Charakterisierung von Metallocen-Chelaten Heterocyclischer 1,2-Dithiolate. Z. Anorg. Allg. Chem. 1994, 620, 1768-1776.
22. Viard, B.; Amaudrut, J.; Sala-Pala, J.; Fakhr, A.; Mugnier, Y.; Moise, C. Synthèse et Etude Electrochimique de Complexes Dithiolènes du Dicyclopentadienyl Niobium. J. Organomet. Chem. 1985, 292, 403-409.
23. 5-Cyclopentadienyl Rings. J. Organomet. Chem. 1994, 465, 187-191.
24. 0 Niobium Complexes. J. Chem. Soc., Dalton Trans. 1996, 4093-4098.
25. King, R. B.; Bisnette, M. B. Organosulfur Derivatives of the Metal Carbonyls. IX. Some Transition Metals Derivatives Containing Both π-Cyclopentadienyl and Bis(trifluoromethyl)ethylene Dithiolate Ligands. Inorg. Chem. 1967, 6, 469-479.
26. Collison, D.; Garner, C. D.; Joule, J. A. The Structure and Mode of Action of the Cofactor of the Oxomolybdoenzymes. Chem. Soc. Rev. 1996, 25-32.
27. Pacheco, A.; Basu, P.; Borbat, P.; Raitsimring, A. M.; Enemark, J. H. Multifrequency ESEEM Spectroscopy of Sulfite Oxidase in Phosphate Buffer: Direct Evidence for Coordinated Phosphate. Inorg. Chem. 1996, 35, 7001-7008.
28. Davies, E. S.; Beddoes, R. L.; Collison, D.; Dinsmore, A.; Docrat, A.; Joule, J. A.; Wilson, C. R.; Garner, C. D. Synthesis of oxomolybdenum bis(dithiolene) complexes related to the cofactor of the oxomolybdoenzymes. J. Chem. Soc., Dalton Trans. 1997, 3985-3996.
29. (a) Kaiwar, S. P.; Hsu, J. K.; Vodacek, A.; Yap, G.; Liable-Sands, L. M. ; Rheingold, A. L.; Pilato, R. S. Metallo 2,3-Disulfidothienoquinoxaline, 2,3-Disulfidothienopyridine, and 2-Sulfido-3-oxidothienoquinoxaline Complexes: Synthesis and Characterization. Inorg. Chem. 1997, 36, 2406-2412.
30. (b) Hsu, J. K.; Bonangelino, C. J.; Kaiwar, S. P.; Boggs, C. M.; Fettinger, J. C.; Pilato, R. S. Direct Conversion of α-Substituted Ketones to Metallo-1,2-enedithiolates. Inorg. Chem. 1996, 35, 4743-4751.
31. 5)Br]. Chem. Lett. 1998, 729-730.
32. 5)
33. 2+. Organometallics 2001, 20, 2421-2424.
34. Guyon, F.; Lenoir, C.; Fourmigué, M.; Larsen, J.; Amaudrut, J. Syntheses, Structures, and Electrochemical Characterization of Mixed Cyclopentadienyl/Dithiolene Complexes of Ti(IV). Bull. Soc. Chim. Fr. 1994, 131, 217-226.
35. 2], a Unique Example of a Uranium(V) Compound with Metal-Sulfur Bonds. Organometallics 2000, 19, 109-111.
36. Green, M. L. H.; Heuer, W. B.; Saunders, G. C. Synthesis and Electrochemistry of Crown Ether Dithiolene Complexes. J. Chem. Soc., Dalton Trans. 1990, 3789-3792.
37. 2Mo(dddt)]-[TCNQ]. Inorg. Chem. 1995, 34, 4979-4985.
38. Fourmigué, M.; Domercq, B.; Jourdain, I. V.; Molinié, P.; Guyon, F.; Amaudrut, J. Interplay of Structural Flexibility and Crystal Packing in a Series of Paramagnetic Cyclopentadienyl/Dithiolene Mo and W Complexes: Evidence for Molecular Spin Ladders. Chem.-Eur. J. 1998, 4, 1714-1723.
39. Batail, P.; Boubekeur, K.; Fourmigué, M.; Gabriel, J.-C. P. Electrocrystallization, an Invaluable Tool for the Construction of Ordered, Electroactive Molecular Solids. Chem. Mater. 1998, 10, 3005-3015.
40. -). J. Solid State Chem. 2001, 159, 413-419.
41. -). Eur. Phys. J. B 1999, 9, 431-443.
42. -). Eur. Phys. J. B 1999, 9, 445-459.
43. - Complex. Eur. J. Inorg. Chem. 2001, 1625-1629.
44. n Complexes. J. Am. Chem. Soc. 1976, 98, 1729-1742.
45. Domercq, B.; Coulon, C.; Fourmigué, M. A Density Functional Study of the Highly Adaptable Molecular Structure of Mo(V) and W(V) Dithiolene Complexes: From Three-Dimensional Antiferromagnet to Spin Ladder. Inorg. Chem. 2001, 40, 371-378.
46. 4] (M = Mo, W): Unprecedented Stoichiometry and Solid-State Arrangement in Charge-Transfer Salts of ansa-Metallocene Dithiolene Complexes. Organometallics, 1999, 18, 1834-1839.
47. 2 tungsten Complexes. Structures and Magnetic Properties of Charge-Transfer Salts. J. Chem. Soc., Dalton Trans. 1998, 483-488.
48. i+1
49. Rovira, C. Molecular Spin Ladders. Chem.-Eur. J. 2000, 6, 1723-1729.
50. Dagotto, E.; Rice, T. M. Surprises on the Way from One- to Two-Dimensional Quantum Magnets: The Ladder Materials. Science 1996, 271, 618-623.
51. .. Adv. Mater. 1994, 6, 948-952.
52. 1) with Optical Limiting Properties in Solution and an Antiferromagnetic Ground State in the Solid State. Adv. Funct. Mater. 2002, 12, 359-366.
53. Néel, by a larger spin-flop field value in the latter (8 vs 5.2 kG in the Mo complex).
54. Dautel, O. J.; Fourmigué, M.; Canadell, E.; Auban-Senzier, P. Fluorine Segregation Controls the Solid State Organization and Electronic Properties of Ni and Au Dithiolene Complexes: Stabilization of a Conducting Single-Component Gold Dithiolene Complex. Adv. Funct. Mater. 2002, 12, 693-698.
55. 3 has been very recently reported by R. Llusar (Castellon, Spain) at the 7th FIGIPS Meeting in 187Inorganic Chemistry, Lisbon, Portugal, June 11-14, 2003.