Properties of organometallic sulfur-rich dithiolate complexes [M(L)(C 8H4S8)] (M = RhIII and Ir III; L = η5-C5H5 and η5-C5Me5) and their oxidation

European Journal of Inorganic Chemistry

Volumn , Issue 10, 2004, Pages 2137-2143

  Kawabata, Kazuhiro ^a   Nakano, Motohiro ^a   Tamura, Hatsue ^a   Matsubayashi, Gen Etsu ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Electrical conductivity; EPR spectroscopy; Iridium; Oxidation; Rhodium; S ligands; X ray diffraction

Indexed keywords

DECOMPOSITION; ELECTRIC CONDUCTIVITY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STATES; IRIDIUM; LIGANDS; METAL COMPLEXES; ORGANOMETALLICS; OXIDATION; RHODIUM COMPOUNDS;

AG +; DITHIOLATES; ELECTRICAL CONDUCTIVITY; EPR SPECTROSCOPY; ESR SPECTRUM; FERROCENIUM CATIONS; OXIDATION POTENTIALS; PROPERTY; S LIGANDS; X- RAY DIFFRACTIONS;

X RAY DIFFRACTION;

BROMINE; FERROCENE DERIVATIVE; IODINE; IRIDIUM; RHODIUM;

ARTICLE; CHEMICAL REACTION; CRYSTAL STRUCTURE; ELECTRIC CONDUCTIVITY; ELECTRONICS; GEOMETRY; OXIDATION; ROOM TEMPERATURE; X RAY DIFFRACTION;

EID: 4544345670     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300790     Document Type: Article

References (35)

1. P. Cassoux, L. Valade, K. Kobayashi, A. Kobayashi, R. A. Clark, A. E. Underhill, Coord. Chem. Rev. 1991, 110, 115-160.
2. R.-M. Olk, B. Olk, W. Dietzsch, R. Kirmse, E. Hoyer, Coord. Chem. Rev. 1992, 117, 99-131.
3. A. E. Pullen, R.-M. Olk, Coord. Chem. Rev. 1999, 188, 211-262.
4. G. Matsubayashi, M. Nakano, H. Tamura, Coord. Chem. Rev. 2002, 226, 143-151.
5. H. Mori, M. Nakano, H. Tamura, G. Matsubayashi, W. Mori, Chem. Lett. 1998, 729-730.
6. K. Kawabata, M. Nakano, H. Tamura, G. Matsubayashi, J. Organomet. Chem., 2004, 689, 405-410.
7. H. Mori, M. Nakano, H. Tamura, G. Matsubayashi, J. Organomet. Chem. 1999, 574, 77-85.
8. K. Saito, M. Nakano, H. Tamura, G. Matsubayashi, Inorg. Chem. 2000, 39, 4815-4820.
9. K. Saito, M. Nakano, H. Tamura, G. Matsubayashi, J. Organomet. Chem. 2001, 625, 7-17.
10. M. Nakano, A. Kuroda, H. Tamura, R. Arakawa, G. Matsubayashi, Inorg. Chim. Acta 1998, 279, 165-171.
11. G. Matsubayashi, M. Nakano, K. Saito, T. Yonamine, R. Arakawa, J. Organomet. Chem. 2000, 611, 364-369.
12. T. Nakazono, M. Nakano, T. Tamura, G. Matsubayashi, J. Mater. Chem. 1999, 9, 2413-2417.
13. K. Kawabata, M. Nakano, H. Tamura, G. Matsubayashi, manuscript to be published.
14. M. Cowie, A. Gleizes, G. W. Grynkewich, D. W. Kalina, M. S. McClure, R. P. Scaringe, R. C. Teitelbaum, S. L. Ruby, J. A. Ibers, C. R. Kannewurf, T. J. Marks, J. Am. Chem. Soc. 1979, 101, 2921-2936.
15. B. N. Diel, T. Inabe, J. W. Lyding, K. F. Schoch Jr., C. R. Kannewurf, T. J. Marks, J. Am. Chem. Soc. 1983, 105, 1551-1567.
16. K. Kubo, M. Nakano, H. Tamura, G. Matsubayashi, M. Nakamoto, J. Organomet. Chem. 2003, 669, 141-148.
17. R. Ziessel, M.-T. Youinou, F. Balegroune, D. Grandjean, J. Organomet. Chem. 1992, 441, 143-154.
18. M.-J. Don, K. Yang, S. G. Bott, M. G. Richmond, J. Organomet. Chem. 1997, 544, 15-21.
19. C.-H. Cheng, B. C. Spivack, R. Eisenberg, J. Am. Chem. Soc. 1977, 99, 3003-3011.
20. K. Kubo, M. Nakano, H. Tamura, G. Matsubayashi, Inorg. Chim. Acta 2002, 336, 120-124.
21. K. Kubo, M. Nakano, H. Tamura, G. Matsubayashi, Eur. J. Inorg. Chem. 2003, 4093-4098.
22. J. W. Kang, K. Moseley, P. M. Maitlis, J. Am. Chem. Soc. 1969, 91, 5970-5977.
23. "Jikken Kagaku Kouza (in Japanese)", Maruzen Co. Tokyo, Japan, 1991, 18, p. 344.
24. N. Svenstrup, K. M. Rasmussen, T. K. Kansen, J. Becher, Synthesis 1994, 809.
25. L. Binet, J. M. Fabre, C. Montginoul, K. B. Simonsen, J. Becher, J. Chem. Soc., Perkin Trans. 1 1996, 783-788.
26. K. Akiba, G. Matsubayashi, T. Tanaka, Inorg. Chim. Acta 1989, 165, 245-248.
27. K. Natsuaki, M. Nakano, G. Matsubayashi, Inorg. Chim. Acta 2000, 299, 112-117.
28. G. Matsubayashi, T. Ryowa, H. Tamura, M. Nakano, R. Arakawa, J. Organomet. Chem. 2002, 645, 94-100.
29. A. Nakahama, M. Nakano, G. Matsubayashi, Inorg. Chim. Acta 1999, 284, 55-60.
30. T. Higashi, ABSCOR, a computer program for absorption correction, Rigaku Corporation, Tokyo, Japan, 1995.
31. PATTY: P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israel, J. M. M. Smits, DIRDIF94 program system, Technical report of the Crystallography laboratory, University of Nijmegen, The Netherlands, 1994.
32. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israel, J. M. M. Smits, DIRDIF94 program system, Technical report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1994.
33. G. M. Sheldrick, SHELXL 97, a computer program for the refinement of crystal structures, University of Göttingen, Germany, 1997.
34. International Tables for X-ray Crystallography, vol. 4, Kynoch Press, Birmingham, England, 1974.
35. C. K. Johnson, ORTEP-II, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.