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18C6, 1,4,7,10,13,16-hexaoxacyclooctadecane
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18C6 = 1,4,7,10,13,16-hexaoxacyclooctadecane.
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Drawings illustrating the near eclipse of C(4) and C(1) in 1-3, as well as angles between planes that quantify the orientation of the Cp rings relative to the M(CO)3 fragments, are provided in the Supporting Information.
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Drawings illustrating the near eclipse of C(4) and C(1) in 1-3, as well as angles between planes that quantify the orientation of the Cp rings relative to the M(CO)3 fragments, are provided in the Supporting Information.
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IR v(CO) spectral data for [M(CO)3(η5- Cppph]-/CuCl reaction products in THF: M, Cr, 1910 (s, 1813 (s, 1779 (s) cm-1, M, Mo, 1917 (s, 1816 (s, 1786 (s) cm-1; M, W, 1912 (s, 1810 (s, 1779 cm-1. These complexes exhibit nearly indistinguishable IR v(CO) spectra in CH3CN. Ambient-temperature THF and CH3CN solutions of these complexes are stable indefinitely under a purified Ar atmosphere, b) For example: 31P (1H) NMR (121 MHz) spectral data for the [Mo(CO) 3(η5Cppph, /CuCl reaction product in C4D8O: δ-3.5 (d, 2J PP, 130 Hz, 13.8 (d, 2JPP, 130 Hz, c) A postulated structure of these products is provided in the Supporting Information, d) These bright yellow solids invariably exhibited a glassy appearance; microcrystalline samples co
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PP = 130 Hz). (c) A postulated structure of these products is provided in the Supporting Information, (d) These bright yellow solids invariably exhibited a glassy appearance; microcrystalline samples could not be obtained.
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34th ed, Academic Press: San Diego, CA
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Holleman, A. F.; Wiberg, E. Inorganic Chemistry, 34th ed.; Academic Press: San Diego, CA, 2001; p 1253.
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Clusters with more than one Cr-Cu bond have been structurally characterized. For example, see
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Clusters with more than one Cr-Cu bond have been structurally characterized. For example, see: Klüfers, P.; Wilhelm, U. J. Organomet. Chem. 1991, 421, 39.
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Klüfers, P.1
Wilhelm, U.J.2
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