메뉴 건너뛰기




Volumn 26, Issue 26, 2007, Pages 6669-6673

[(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Supporting ligands for reactions at group VI metal-copper bonds

Author keywords

[No Author keywords available]

Indexed keywords

CONCOMITANT HETEROLYTIC CLEAVAGES; PHOSPHINES;

EID: 38049143634     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700861r     Document Type: Article
Times cited : (11)

References (38)
  • 26
    • 0001476445 scopus 로고    scopus 로고
    • pph: Graham, T. W.; Llamazares, A.; McDonald, R.; Cowie, M. Organometallics 1999, 18, 3490.
    • pph: Graham, T. W.; Llamazares, A.; McDonald, R.; Cowie, M. Organometallics 1999, 18, 3490.
  • 30
    • 38049147330 scopus 로고    scopus 로고
    • 18C6, 1,4,7,10,13,16-hexaoxacyclooctadecane
    • 18C6 = 1,4,7,10,13,16-hexaoxacyclooctadecane.
  • 31
    • 38049096970 scopus 로고    scopus 로고
    • Drawings illustrating the near eclipse of C(4) and C(1) in 1-3, as well as angles between planes that quantify the orientation of the Cp rings relative to the M(CO)3 fragments, are provided in the Supporting Information.
    • Drawings illustrating the near eclipse of C(4) and C(1) in 1-3, as well as angles between planes that quantify the orientation of the Cp rings relative to the M(CO)3 fragments, are provided in the Supporting Information.
  • 32
    • 38049139958 scopus 로고    scopus 로고
    • +.
    • +.
  • 33
    • 38049145588 scopus 로고    scopus 로고
    • IR v(CO) spectral data for [M(CO)3(η5- Cppph]-/CuCl reaction products in THF: M, Cr, 1910 (s, 1813 (s, 1779 (s) cm-1, M, Mo, 1917 (s, 1816 (s, 1786 (s) cm-1; M, W, 1912 (s, 1810 (s, 1779 cm-1. These complexes exhibit nearly indistinguishable IR v(CO) spectra in CH3CN. Ambient-temperature THF and CH3CN solutions of these complexes are stable indefinitely under a purified Ar atmosphere, b) For example: 31P (1H) NMR (121 MHz) spectral data for the [Mo(CO) 3(η5Cppph, /CuCl reaction product in C4D8O: δ-3.5 (d, 2J PP, 130 Hz, 13.8 (d, 2JPP, 130 Hz, c) A postulated structure of these products is provided in the Supporting Information, d) These bright yellow solids invariably exhibited a glassy appearance; microcrystalline samples co
    • PP = 130 Hz). (c) A postulated structure of these products is provided in the Supporting Information, (d) These bright yellow solids invariably exhibited a glassy appearance; microcrystalline samples could not be obtained.
  • 34
  • 36
    • 38049109182 scopus 로고    scopus 로고
    • 4.
    • 4.
  • 37
    • 4244049277 scopus 로고
    • Clusters with more than one Cr-Cu bond have been structurally characterized. For example, see
    • Clusters with more than one Cr-Cu bond have been structurally characterized. For example, see: Klüfers, P.; Wilhelm, U. J. Organomet. Chem. 1991, 421, 39.
    • (1991) Organomet. Chem , vol.421 , pp. 39
    • Klüfers, P.1    Wilhelm, U.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.