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Volumn 48, Issue 14, 2009, Pages 6347-6349

Enhanced Electronic Coupling in a Molecular Pair of Dimolybdenum Units Bridged by a Tetrathioterephthalate Dianion

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EID: 67650463390     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic900956k     Document Type: Article
Times cited : (27)

References (32)
  • 26
    • 67650356726 scopus 로고    scopus 로고
    • Preparation of [Mo2(DAniF)3](S2CC 6H4CS2)[Mo2(DAniF)3, 1, A yellow solution Of Mo2(DAniF)3(O2CCH 3, 0.102 g, 0.10 mmol) in 10 mL of THF was mixed with dipiperidinium tetrathioterephthalate (0.020 g, 0.05 mmol) in 10 mL of ethanol. After stirring for 2 h, a green microcrystalline product formed, which was filtered and washed with ethanol (2x5 mL, Yield: 0.0714 g (67, Diffusion of ethanol into a dichloromethane solution of the product affords green needle-shaped crystals. 1H NMR (CDCl3, ppm, 8.50 (s, 2H, NCHN, 8.33 (s, 4H, NCHN, 8.30 (s, 4H, aromatic H, 6.67 (d, 16H, aromatic H, 6.64 (d, 16H, aromatic H, 6.57 (d, 8H, aromatic H, 6.56 (d, 8H, aromatic H, 3.73 (s, 24H, OCH3, 3.67 s, 12H, OCH3, Anal. Calcd for C 98H94Mo4N12O12S 4
    • 4 (1): C, 53.81; H, 4.42; N, 7.84. Found: C, 53.98; H, 4.80; N, 7.52.
  • 27
    • 67650366059 scopus 로고    scopus 로고
    • 2 and converged for 11541 unique reflections and 648 parameters to give R1 = 0.1082 and wR2 = 0.1388 and a GOF of 0.963.
    • 2 and converged for 11541 unique reflections and 648 parameters to give R1 = 0.1082 and wR2 = 0.1388 and a GOF of 0.963.


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