Direct synthesis of polyfunctionalized unsaturated δ-lactones and δ-lactams from α-alkenoyl α-carboxyl/carbamoyl ketene S,S-acetals under Vilsmeier conditions

Journal of Organic Chemistry

Volumn 74, Issue 14, 2009, Pages 5090-5092

  Liu, Jun ^a   Wang, Mang ^a,b   Han, Feng ^a   Liu, Yingjie ^a   Liu, Qun ^a  

^a NORTHEAST NORMAL UNIVERSITY   (China)

^b DALIAN UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL EQUATIONS; DIRECT SYNTHESIS; EFFICIENT METHOD; VILSMEIER; VILSMEIER REAGENT;

CHEMICAL REACTIONS;

AMIDES;

ACETAL DERIVATIVE; DELTA LACTAM; DELTA LACTONE; KETENE DERIVATIVE; LACTAM DERIVATIVE; LACTONE DERIVATIVE; REAGENT; UNCLASSIFIED DRUG; VILSMEIER REAGENT;

ANNULATION REACTION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; HALOFORMYLATION; HALOVINYLATION; MICHAEL ADDITION; REACTION OPTIMIZATION; SYNTHESIS;

ACETALS; CYCLIZATION; ETHYLENES; KETONES; LACTAMS; LACTONES; MOLECULAR STRUCTURE; SULFUR;

EID: 67650376993     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo900663z     Document Type: Article

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52. In our research, the corresponding 4-chloro-unsaturated δ-lactams were not obtained under the reaction conditions used.