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For reviews, see (a) in: S. Patai, Z. Rappoport (Eds.), chap. 24
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For reviews, see (a) T.D. Tilley, in: S. Patai, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds, Wiley, 1989, chap. 24. (b) P.D. Lickiss, Chem. Soc. Rev. (1992) 271. (c) K. H. Pannell, H, K, Sharma, Chem. Rev. (1995) 1351. (d) C. Zybill, Top. Curr. Chem. 160 (1991) 1.
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For reviews, see (a) T.D. Tilley, in: S. Patai, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds, Wiley, 1989, chap. 24. (b) P.D. Lickiss, Chem. Soc. Rev. (1992) 271. (c) K. H. Pannell, H, K, Sharma, Chem. Rev. (1995) 1351. (d) C. Zybill, Top. Curr. Chem. 160 (1991) 1.
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For reviews, see (a) T.D. Tilley, in: S. Patai, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds, Wiley, 1989, chap. 24. (b) P.D. Lickiss, Chem. Soc. Rev. (1992) 271. (c) K. H. Pannell, H, K, Sharma, Chem. Rev. (1995) 1351. (d) C. Zybill, Top. Curr. Chem. 160 (1991) 1.
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Fischer carbenes exhibit electrophilic behavior in contrast to Schrock carbenes, which are normally nucleophilic. See (a)
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Fischer carbenes exhibit electrophilic behavior in contrast to Schrock carbenes, which are normally nucleophilic. See (a) E.O. Fischer, A. Massböl, Angew. Chem. Int. Ed. Engl. 3 (1964) 580. (b) K.H. Dotz, E.O. Fischer, P. Hoffmann, F.R. Kreissel, U. Schubert, K. Weiss, Transition Metal Carbene Complexes, Verlag Chemie, 1983.
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Fischer carbenes exhibit electrophilic behavior in contrast to Schrock carbenes, which are normally nucleophilic. See (a) E.O. Fischer, A. Massböl, Angew. Chem. Int. Ed. Engl. 3 (1964) 580. (b) K.H. Dotz, E.O. Fischer, P. Hoffmann, F.R. Kreissel, U. Schubert, K. Weiss, Transition Metal Carbene Complexes, Verlag Chemie, 1983.
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See for example (a)
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See for example (a) D.A. Straus, S.D. Grumbine, T.D. Tilley, J. Am. Chem. Soc. 116 (1994) 7801. (b) S.K. Grumbine, T.D. Tilley, J. Am. Chem. Soc. 116 (1994) 5495.
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11644310835
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(b)
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See for example (a) D.A. Straus, S.D. Grumbine, T.D. Tilley, J. Am. Chem. Soc. 116 (1994) 7801. (b) S.K. Grumbine, T.D. Tilley, J. Am. Chem. Soc. 116 (1994) 5495.
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(b) L. Ackermann, A. Fürstner, T. Weskamp, F.J. Kohl, W.A. Herrmann, Tetrahedron Lett. 40 (1999) 4787.
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Herrmann, W.A.5
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(c) M.G. Gardiner, W.A. Herrmann, C.-P. Reisinger, J. Schwartz, M. Spiegler, J. Organomet. Chem. 572 (1999) 239.
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(f) T. Weskamp, W.C. Schattenmann, M. Speigler, W.A. Herrmann, Angew. Chem. Int. Ed. Engl. 37 (1998) 2490.
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Petri S.H.A., Eikenberg D., Neumann B., Stammler H.-G., Jutzi P. Organometallics. 18:1999;2615.
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25
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0000122520
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N-heterocyclic silylenes cannot be viewed as true "cones" due to their planar configuration, and may be better described as "fences". See (a)
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N-heterocyclic silylenes cannot be viewed as true "cones" due to their planar configuration, and may be better described as "fences". See (a) J. Huang, H. Schanz, E.D. Stevens, S.P. Nolan, Organometallics 18 (1999) 2370. (b) T.E. Muller, D.M.P. Mingos, Transition Metal Chem. 20 (1995) 533.
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Huang, J.1
Schanz, H.2
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Nolan, S.P.4
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26
-
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0000242318
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(b)
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N-heterocyclic silylenes cannot be viewed as true "cones" due to their planar configuration, and may be better described as "fences". See (a) J. Huang, H. Schanz, E.D. Stevens, S.P. Nolan, Organometallics 18 (1999) 2370. (b) T.E. Muller, D.M.P. Mingos, Transition Metal Chem. 20 (1995) 533.
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Muller, T.E.1
Mingos, D.M.P.2
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27
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0011712227
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Detailed IR studies of analogous carbene complexes can be found in (a)
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Detailed IR studies of analogous carbene complexes can be found in (a) K. Öfele, M. Herberhold, Z. Naturforsch. 28 (1973) 306. (b) P.B. Hitchcock, M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 2160. (c) M.F. Lappert, P.L. Pye, G.M. McLaughlin, J. Chem. Soc. Dalton Trans. (1984) 1307. (d) M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 1283.
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Z. Naturforsch.
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Öfele, K.1
Herberhold, M.2
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28
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51149210110
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-
(b)
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Detailed IR studies of analogous carbene complexes can be found in (a) K. Öfele, M. Herberhold, Z. Naturforsch. 28 (1973) 306. (b) P.B. Hitchcock, M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 2160. (c) M.F. Lappert, P.L. Pye, G.M. McLaughlin, J. Chem. Soc. Dalton Trans. (1984) 1307. (d) M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 1283.
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Hitchcock, P.B.1
Lappert, M.F.2
Pye, P.L.3
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29
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0345904519
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(c)
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Detailed IR studies of analogous carbene complexes can be found in (a) K. Öfele, M. Herberhold, Z. Naturforsch. 28 (1973) 306. (b) P.B. Hitchcock, M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 2160. (c) M.F. Lappert, P.L. Pye, G.M. McLaughlin, J. Chem. Soc. Dalton Trans. (1984) 1307. (d) M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 1283.
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Pye, P.L.2
McLaughlin, G.M.3
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30
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37049105203
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(d)
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Detailed IR studies of analogous carbene complexes can be found in (a) K. Öfele, M. Herberhold, Z. Naturforsch. 28 (1973) 306. (b) P.B. Hitchcock, M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 2160. (c) M.F. Lappert, P.L. Pye, G.M. McLaughlin, J. Chem. Soc. Dalton Trans. (1984) 1307. (d) M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 1283.
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Lappert, M.F.1
Pye, P.L.2
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