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A high degree of steric hindrance for two of the branches of the quaternary carbon atom would reduce the availability of the other two polymerizable moieties to be involved in the propagation of differing chains, resulting in cross-linking
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A high degree of steric hindrance for two of the branches of the quaternary carbon atom would reduce the availability of the other two polymerizable moieties to be involved in the propagation of differing chains, resulting in cross-linking.
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Lower yields for the cyclopolymerization were obtained using BPO instead of AIBN as the free-radical initiator (see Supporting Information).
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2O, corresponding to the ketal cleavage and then loss of H2O) correspond to a neat loss of one molecule of acetone.
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2O, corresponding to the ketal cleavage and then loss of H2O) correspond to a neat loss of one molecule of acetone.
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51
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27944497380
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The compound is a potent lacrymator; extreme caution is strongly suggested when using it
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Following conditions smilar to: Kamahori, K.; Ito, K.; Itsuno, S. J. Org. Chem. 1996, 61, 8321-8324.
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