Why is the Suzuki-Miyaura cross-coupling of sp3 carbons in α-bromo sulfoxide systems fast and stereoselective? A DFT study on the mechanism

Journal of Organic Chemistry

Volumn 74, Issue 11, 2009, Pages 4049-4054

  Gourlaouen, Christophe ^a   Ujaque, Gregori ^b   Lledós, Agustí ^b   Medio Simon, Mercedes ^c   Asensio, Gregorio ^c   Maseras, Feliu ^a,b  

^a INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^c UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BISPHOSPHINE; CHEMICAL EQUATIONS; DFT CALCULATION; DFT STUDY; ENERGY TRANSITION STATE; EXPERIMENTAL DATA; INVERSION OF CONFIGURATION; MODEL SYSTEM; NUCLEOPHILIC SUBSTITUTIONS; OXIDATIVE ADDITIONS; REACTION PATHWAYS; STEREO-SELECTIVE; SUZUKI-MIYAURA CROSS-COUPLING; TRANSITION STATE;

PALLADIUM; STEREOSELECTIVITY; SULFUR COMPOUNDS;

PROBABILITY DENSITY FUNCTION;

ALPHA BROMOSULFOXIDE DERIVATIVE; BROMINE DERIVATIVE; CARBON; PALLADIUM; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; DENSITY FUNCTIONAL THEORY; REACTION ANALYSIS; REACTION TIME; STEREOCHEMISTRY; STEREOSPECIFICITY; SUZUKI MIYAURA CROSS COUPLING REACTION; SUZUKI REACTION;

EID: 66249135289     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo900178c     Document Type: Article

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