-
1
-
-
66149162989
-
-
For recent examples of the patent literature related to agrochemicals, see: (a, WO 032462 A1, 2006 Syngenta
-
For recent examples of the patent literature related to agrochemicals, see: (a) Jeanguenat, A.; O'Sullivan, A. C. WO 032462 A1, 2006 (Syngenta).
-
-
-
Jeanguenat, A.1
O'Sullivan, A.C.2
-
4
-
-
66149169998
-
-
WO 2007149134 A1, 2007 Dow Agrosciences
-
Huang, J. X.; Rogers, R. B.; Orr, N.; Sparks, T. C.; Gifford, J. M.; Loso, M. R.; Zhu, Y.; Meade, T. WO 2007149134 A1, 2007 (Dow Agrosciences).
-
-
-
Huang, J.X.1
Rogers, R.B.2
Orr, N.3
Sparks, T.C.4
Gifford, J.M.5
Loso, M.R.6
Zhu, Y.7
Meade, T.8
-
6
-
-
66149176833
-
-
WO 2008027539 A1 Dow Agrosciences
-
Loso, M. R.; Nugent, B. M.; Zhu, Y.; Siddall, T. L.; Tisdell, F. E.; Huang, J. X.; Benko, Z. L. WO 2008027539 A1 (Dow Agrosciences).
-
-
-
Loso, M.R.1
Nugent, B.M.2
Zhu, Y.3
Siddall, T.L.4
Tisdell, F.E.5
Huang, J.X.6
Benko, Z.L.7
-
7
-
-
66149182915
-
-
WO 2008057129 A1 Dow Agrosciences
-
Zhu, Y.; Loso, M. R.; Nugent, B. M.; Huang, J. X.; Rogers, R. B. WO 2008057129 A1 (Dow Agrosciences).
-
-
-
Zhu, Y.1
Loso, M.R.2
Nugent, B.M.3
Huang, J.X.4
Rogers, R.B.5
-
8
-
-
0344844429
-
-
Reviews: a
-
Reviews: (a) Harmata, M. Chemtracts 2003, 16, 660.
-
(2003)
Chemtracts
, vol.16
, pp. 660
-
-
Harmata, M.1
-
10
-
-
84890977660
-
-
Enders, D, Jaeger, K, E, Eds, Wiley-VCH: Weinheim
-
Bolm, C. In Asymmetric Synthesis with Chemical and Biological Methods; Enders, D., Jaeger, K.- E., Eds.; Wiley-VCH: Weinheim, 2007; p 149.
-
(2007)
Asymmetric Synthesis with Chemical and Biological Methods
, pp. 149
-
-
Bolm, C.1
-
11
-
-
84889271806
-
-
Worch, C.; Mayer, A. C.; Bolm, C. In Organosulfur Chemistry in Asymmetric Synthesis; Toru, T., Bolm, C., Eds.; Wiley-VCH: Weinheim, 2008; p 209. For recent examples, see:
-
Worch, C.; Mayer, A. C.; Bolm, C. In Organosulfur Chemistry in Asymmetric Synthesis; Toru, T., Bolm, C., Eds.; Wiley-VCH: Weinheim, 2008; p 209. For recent examples, see:
-
-
-
-
13
-
-
53849086542
-
-
Lu, S.-M.; Bolm, C. Chem.sEur. J. 2008, 14, 7513.
-
Lu, S.-M.; Bolm, C. Chem.sEur. J. 2008, 14, 7513.
-
-
-
-
14
-
-
57349098769
-
-
Lu, S.-M.; Bolm, C. Angew. Chem., Int. Ed. 2008, 47, 8920.
-
(2008)
Angew. Chem., Int. Ed
, vol.47
, pp. 8920
-
-
Lu, S.-M.1
Bolm, C.2
-
15
-
-
60749122587
-
-
Frings, M.; Atodiresei, I.; Runsink, J.; Raabe, G.; Bolm, C. Chem.sEur. J. 2009, 15, 1566.
-
Frings, M.; Atodiresei, I.; Runsink, J.; Raabe, G.; Bolm, C. Chem.sEur. J. 2009, 15, 1566.
-
-
-
-
16
-
-
0031575567
-
-
(a) Bolm, C.; Kahmann, J. D.; Moll, G. Tetrahedron Lett. 1997, 38, 1169.
-
(1997)
Tetrahedron Lett
, vol.38
, pp. 1169
-
-
Bolm, C.1
Kahmann, J.D.2
Moll, G.3
-
17
-
-
0035793836
-
-
Bolm, C.; Moll, G.; Kahmann, J. D. Chem.sEur. J. 2001, 7, 1118.
-
Bolm, C.; Moll, G.; Kahmann, J. D. Chem.sEur. J. 2001, 7, 1118.
-
-
-
-
19
-
-
0037149654
-
-
Bolm, C.; Müller, D.; Hackenberger, C. P. R. Org. Lett. 2002, 4, 893.
-
(2002)
Org. Lett
, vol.4
, pp. 893
-
-
Bolm, C.1
Müller, D.2
Hackenberger, C.P.R.3
-
20
-
-
0042332036
-
-
Bolm, C.; Müller, D.; Dalhoff, C.; Hackenberger, C. P. R.; Weinhold, E. Bioorg. Med. Chem. Lett. 2003, 13, 3207.
-
(2003)
Bioorg. Med. Chem. Lett
, vol.13
, pp. 3207
-
-
Bolm, C.1
Müller, D.2
Dalhoff, C.3
Hackenberger, C.P.R.4
Weinhold, E.5
-
21
-
-
66149172063
-
-
For classical methods, see the following. NaN3/H2SO4: (a) Fusco, R.; Tenconi, F. Chim. Ind. (Milan) 1965, 47, 61.
-
For classical methods, see the following. NaN3/H2SO4: (a) Fusco, R.; Tenconi, F. Chim. Ind. (Milan) 1965, 47, 61.
-
-
-
-
23
-
-
0030987106
-
-
Brandt, J.; Gais, H.-J. Tetrahedron: Asymmetry 1997, 6, 909. O-Mesitylenesulfonyl hydroxylamine (MSH):
-
Brandt, J.; Gais, H.-J. Tetrahedron: Asymmetry 1997, 6, 909. O-Mesitylenesulfonyl hydroxylamine (MSH):
-
-
-
-
24
-
-
0015933580
-
-
Tamura, Y.; Minamikawa, J.; Sumoto, K.; Fujii, S.; Ikeda, M. J. Org. Chem. 1973, 38, 1239.
-
(1973)
J. Org. Chem
, vol.38
, pp. 1239
-
-
Tamura, Y.1
Minamikawa, J.2
Sumoto, K.3
Fujii, S.4
Ikeda, M.5
-
25
-
-
0000012935
-
-
Johnson, C. R.; Kirchhoff, R. A.; Corkins, H. G. J. Org. Chem. 1974, 39, 2458.
-
(1974)
J. Org. Chem
, vol.39
, pp. 2458
-
-
Johnson, C.R.1
Kirchhoff, R.A.2
Corkins, H.G.3
-
26
-
-
0007230737
-
-
Tamura, Y.; Matushima, H.; Minamikawa, J.; Ikeda, M.; Sumoto, K. Tetrahedron 1975, 31, 3035.
-
(1975)
Tetrahedron
, vol.31
, pp. 3035
-
-
Tamura, Y.1
Matushima, H.2
Minamikawa, J.3
Ikeda, M.4
Sumoto, K.5
-
27
-
-
66149171388
-
-
Fieser, M.; Fieser, L. F. Reagents for Organic Synthesis; John Wiley & Sons: New York, 1975; 5, p 430. See also:
-
Fieser, M.; Fieser, L. F. Reagents for Organic Synthesis; John Wiley & Sons: New York, 1975; Vol. 5, p 430. See also:
-
-
-
-
28
-
-
0030040171
-
-
Allenmark, S.; Claeson, S.; Lowendahl, C. Tetrahedron: Asymmetry 1996, 7, 361.
-
(1996)
Tetrahedron: Asymmetry
, vol.7
, pp. 361
-
-
Allenmark, S.1
Claeson, S.2
Lowendahl, C.3
-
29
-
-
0001017993
-
-
For reviews on synthetic approaches to sulfoximines, see: a
-
For reviews on synthetic approaches to sulfoximines, see: (a) Johnson, C. R. Acc. Chem. Res. 1973, 6, 341.
-
(1973)
Acc. Chem. Res
, vol.6
, pp. 341
-
-
Johnson, C.R.1
-
30
-
-
66149184331
-
-
Methoden Org. Chem. (Houben-Weyl); Klamann, D., Ed.; VCH Thieme: Stuttgart, 1985; E11, Parts 1 and 2.
-
Methoden Org. Chem. (Houben-Weyl); Klamann, D., Ed.; VCH Thieme: Stuttgart, 1985; Vol. E11, Parts 1 and 2.
-
-
-
-
34
-
-
0033985468
-
-
Reggelin, M.; Zur, C. Synthesis 2000, 1.
-
Reggelin, M.; Zur, C. Synthesis 2000, 1.
-
-
-
-
36
-
-
0042881024
-
-
For an excellent review on metal-catalyzed nitrogen transfer reactions, see
-
For an excellent review on metal-catalyzed nitrogen transfer reactions, see: Müller, P.; Fruit, C. Chem. Rev. 2003, 103, 2905.
-
(2003)
Chem. Rev
, vol.103
, pp. 2905
-
-
Müller, P.1
Fruit, C.2
-
39
-
-
0032868574
-
-
Bolm, C.; Muñiz, K.; Aguilar, N.; Kesselgruber, M.; Raabe, R. Synthesis 1999, 1251.
-
(1999)
Synthesis
, pp. 1251
-
-
Bolm, C.1
Muñiz, K.2
Aguilar, N.3
Kesselgruber, M.4
Raabe, R.5
-
40
-
-
0033519191
-
-
Takada, H.; Ohe, K.; Uemura, S. Angew. Chem., Int. Ed. 1999, 38, 1288.
-
(1999)
Angew. Chem., Int. Ed
, vol.38
, pp. 1288
-
-
Takada, H.1
Ohe, K.2
Uemura, S.3
-
41
-
-
0034928855
-
-
Nakayama, J.; Otani, T.; Sugihara, Y.; Sano, Y.; Ishii, A.; Sakamoto, A. Heteroatom Chem. 2001, 12, 333.
-
(2001)
Heteroatom Chem
, vol.12
, pp. 333
-
-
Nakayama, J.1
Otani, T.2
Sugihara, Y.3
Sano, Y.4
Ishii, A.5
Sakamoto, A.6
-
42
-
-
0037041363
-
-
Cren, S.; Kinahan, T. C.; Skinner, C. L.; Tye, H. Tetrahedron Lett. 2002, 43, 2749.
-
(2002)
Tetrahedron Lett
, vol.43
, pp. 2749
-
-
Cren, S.1
Kinahan, T.C.2
Skinner, C.L.3
Tye, H.4
-
43
-
-
0036139906
-
-
Lacôte, E.; Amatore, M.; Fensterbank, L.; Malacria, M. Synlett 2002, 116.
-
(2002)
Synlett
, pp. 116
-
-
Lacôte, E.1
Amatore, M.2
Fensterbank, L.3
Malacria, M.4
-
46
-
-
26844488178
-
-
For alternative metal-free sulfur iminations, see: a
-
For alternative metal-free sulfur iminations, see: (a) Cho, G. Y.; Bolm, C. Tetrahedron Lett. 2005, 46, 8007.
-
(2005)
Tetrahedron Lett
, vol.46
, pp. 8007
-
-
Cho, G.Y.1
Bolm, C.2
-
47
-
-
13244289971
-
-
Siu, T.; Picard, C. J.; Yudin, A. K. J. Org. Chem. 2005, 70, 932.
-
(2005)
J. Org. Chem
, vol.70
, pp. 932
-
-
Siu, T.1
Picard, C.J.2
Yudin, A.K.3
-
48
-
-
21344468586
-
-
Karabuga, S.; Kazaz, C.; Kilic, H.; Ulukanli, S.; Celik, A. Tetrahedron Lett. 2005, 46, 5225.
-
(2005)
Tetrahedron Lett
, vol.46
, pp. 5225
-
-
Karabuga, S.1
Kazaz, C.2
Kilic, H.3
Ulukanli, S.4
Celik, A.5
-
49
-
-
66149161688
-
-
Krasnova, L. B.; Hili, R. M.; Chernoloz, O. V.; Yudin, A. K. Arkivoc 2005, iV, 268.
-
Krasnova, L. B.; Hili, R. M.; Chernoloz, O. V.; Yudin, A. K. Arkivoc 2005, iV, 268.
-
-
-
-
50
-
-
34848854176
-
-
GarcI'a Mancheño, O.; Bistri, O.; Bolm, C. Org. Lett. 2007, 9, 3809.
-
GarcI'a Mancheño, O.; Bistri, O.; Bolm, C. Org. Lett. 2007, 9, 3809.
-
-
-
-
51
-
-
11144323895
-
-
For reviews on iron catalysis, see: a
-
For reviews on iron catalysis, see: (a) Bolm, C.; Legros, J.; Le Paih, J.; Zani, L. Chem. Rev. 2004, 104, 6217.
-
(2004)
Chem. Rev
, vol.104
, pp. 6217
-
-
Bolm, C.1
Legros, J.2
Le Paih, J.3
Zani, L.4
-
53
-
-
33645995461
-
-
Diaz, D. D.; Miranda, P. O.; Padro'n, J. I.; Martin, V. S. Curr. Org. Chem. 2006, 10, 457.
-
(2006)
Curr. Org. Chem
, vol.10
, pp. 457
-
-
Diaz, D.D.1
Miranda, P.O.2
Padro'n, J.I.3
Martin, V.S.4
-
54
-
-
50049109778
-
-
Enthaler, S.; Junge, K.; Beller, M. Angew. Chem., Int. Ed. 2008, 47, 3317.
-
(2008)
Angew. Chem., Int. Ed
, vol.47
, pp. 3317
-
-
Enthaler, S.1
Junge, K.2
Beller, M.3
-
56
-
-
50049109778
-
-
Enthaler, S.; Junge, K.; Beller, M. Angew. Chem., Int. Ed. 2008, 47, 3317.
-
(2008)
Angew. Chem., Int. Ed
, vol.47
, pp. 3317
-
-
Enthaler, S.1
Junge, K.2
Beller, M.3
-
59
-
-
44349129755
-
-
Correa, A.; GarcI'a Mancheño, O.; Bolm, C. Chem. Soc. Rev. 2008, 37, 1108.
-
Correa, A.; GarcI'a Mancheño, O.; Bolm, C. Chem. Soc. Rev. 2008, 37, 1108.
-
-
-
-
63
-
-
33745697784
-
-
GarcI'a Mancheño, O.; Bolm, C. Org. Lett. 2006, 8, 2349.
-
GarcI'a Mancheño, O.; Bolm, C. Org. Lett. 2006, 8, 2349.
-
-
-
-
64
-
-
34547755047
-
-
GarcI'a Mancheño, O.; Bolm, C. Chem.sEur. J. 2007, 13, 6674.
-
GarcI'a Mancheño, O.; Bolm, C. Chem.sEur. J. 2007, 13, 6674.
-
-
-
-
65
-
-
66149171387
-
-
Iron(II)/(III) perchlorates and iron(III) diketonates such as 1-acetyl- 2-oxo-1-cyclopentanide and 2-methyl acetylacetonate catalyzed sulfoxide iminations, but they were less efficient than Fe(acac)3.
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Iron(II)/(III) perchlorates and iron(III) diketonates such as 1-acetyl- 2-oxo-1-cyclopentanide and 2-methyl acetylacetonate catalyzed sulfoxide iminations, but they were less efficient than Fe(acac)3.
-
-
-
-
66
-
-
0001174332
-
-
(a) Haynes, J. S.; Sams, J. R.; Thomson, R. C. Can. J. Chem. 1981, 59, 669.
-
(1981)
Can. J. Chem
, vol.59
, pp. 669
-
-
Haynes, J.S.1
Sams, J.R.2
Thomson, R.C.3
-
68
-
-
66149190591
-
-
For preliminary results, see: Nakanishi, M., Dissertation, RWTH Aachen University, 2007.
-
For preliminary results, see: Nakanishi, M., Dissertation, RWTH Aachen University, 2007.
-
-
-
-
69
-
-
53849099673
-
-
For the application of Fe(OTf)2-based catalytic systems in nitrene transfer reactions onto enol silyl ethers and olefins, see: (a) Nakanishi, M.; Salit, A.-F.; Bolm, C. Adv. Synth. Catal. 2008, 350, 1835.
-
For the application of Fe(OTf)2-based catalytic systems in nitrene transfer reactions onto enol silyl ethers and olefins, see: (a) Nakanishi, M.; Salit, A.-F.; Bolm, C. Adv. Synth. Catal. 2008, 350, 1835.
-
-
-
-
70
-
-
56749159841
-
-
For the use of related iron triflate catalysts, see
-
Mayer, A.; Salit, A.-F.; Bolm, C. Chem. Commun. 2008, 5975. For the use of related iron triflate catalysts, see:
-
(2008)
Chem. Commun
, pp. 5975
-
-
Mayer, A.1
Salit, A.-F.2
Bolm, C.3
-
71
-
-
34250778386
-
-
Klotz, K. L.; Slominski, L. M.; Hull, A. V.; Gottsacker, V. M.; Mas-Balleste', R.; Que, L; Halfen, J. A. Chem. Commun. 2007, 2063.
-
(2007)
Chem. Commun
, pp. 2063
-
-
Klotz, K.L.1
Slominski, L.M.2
Hull, A.V.3
Gottsacker, V.M.4
Mas-Balleste', R.5
Que, L.6
Halfen, J.A.7
-
72
-
-
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-
-
For example, nosylamides can be easily cleaved using thiolates, SES-amides react upon treatment with fluorides to give amines, tert-butyl sulfonylamides are deprotected under acidic conditions, and deprotection of the pyridinyl and thiophenyl derivatives could be achieved by reaction with Mg. For general methods for the deprotection of sulfonylamides, see: (a) Greene, T. W.; Wuts, P. G. M. Protective Groups in Organic Synthesis, 3rd ed.; John Wiley & Sons: New York, 1999; p 603.
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For example, nosylamides can be easily cleaved using thiolates, SES-amides react upon treatment with fluorides to give amines, tert-butyl sulfonylamides are deprotected under acidic conditions, and deprotection of the pyridinyl and thiophenyl derivatives could be achieved by reaction with Mg. For general methods for the deprotection of sulfonylamides, see: (a) Greene, T. W.; Wuts, P. G. M. Protective Groups in Organic Synthesis, 3rd ed.; John Wiley & Sons: New York, 1999; p 603.
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-
-
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For experimental details, see the Supporting Information
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For experimental details, see the Supporting Information.
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