A unique coordination of SiH4: Isolation, characterization, and theoretical study of (PR3)2>H2Ru(SiH4)RuH2(PR3)2 [15]

Journal of the American Chemical Society

Volumn 122, Issue 23, 2000, Pages 5664-5665

  Atheaux, Isabelle ^a   Donnadieu, Bruno ^a   Rodriguez, V ^a,c   Sabo Etienne, Sylviane ^a   Chaudret, Bruno ^a   Hussein, Khansaa ^b,d   Barthelat, Jean Claude ^b  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b European Theoretical Spectroscopy Facility   (France)

^c Grupo de Ingenieria Bioquimica   (Spain)

^d University of Al Baath   (Syrian Arab Republic)

Author keywords

[No Author keywords available]

Indexed keywords

RUTHENIUM COMPLEX; SILANE DERIVATIVE;

CATALYSIS; CHEMICAL BINDING; CHEMICAL REACTION; CRYSTALLIZATION; EXTRACTION; HYDROGEN BOND; LETTER; MOLECULAR MODEL; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 0034647243     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000223p     Document Type: Letter

References (31)

1. Hoyano, J. K.; Elder, M.; Graham, W. A. G. J. Am. Chem. Soc. 1969, 91, 4569.
2. Corey, J. Y.; Braddock-Wilking, J. Chem. Rev. 1999, 99, 175.
3. (a) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789.
4. (b) Schubert, U. Adv. Organomet. Chem. 1990, 30, 151.
5. (a) Speier, J. L. Adv. Organomet. Chem. 1979, 17, 407.
6. (b) Brown, S. S.; Kendrick, T. C.; McVie, J.; Thomas, D. R. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon press: New York, 1994; Vol. 2, Chapter 4.
7. (c) West, R. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1989; Chapter 19.
8. (d) Ojima, I. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1989; Chapter 25.
9. (e) Lapointe, A. M.; Rix, F. C.; Brookhart, M. J. Am. Chem. Soc. 1997, 119, 906.
10. (f) Woo, H. G.; Waltzer, J. F.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 7047.
11. (g) Procopio, L. J.; Carroll, P. J.; Berry, D. H. J. Am. Chem. Soc. 1994, 116, 177.
12. Luo, X.-L.; Kubas, G. J.; Burns, C. J.; Bryan, J. C.; Unkefer, C. J. J. Am. Chem. Soc. 1995, 117, 1159.
13. (a) Xin, S.; Aitken, C.; Harrod, J. F.; Mu, Y.; Samuel, E. Can. J. Chem. 1990, 68, 471.
14. (b) Hao, L.; Lebuis, A.-M.; Harrod, J. F.; Samuel, E. Chem. Commun. 1997, 2193.
15. (c) Hao, L.; Lebuis, A.-M.; Harrod, J. F. Chem. Commun. 1998, 1089.
16. Woo, H. G.; Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 5698.
17. (a) Delpech, F.; Sabo-Etienne, S.; Chaudret, B.; Daran, J. C J. Am. Chem. Soc. 1997, 119, 3167.
18. (b) Delpech, F.; Sabo-Etienne, S.; Chaudret, B.; Daran, J. C.; Hussein, K.; Marsden, C. J.; Barthelat, J.-C. J. Am. Chem. Soc. 1999, 121, 6668.
19. Hussein, K.; Marsden, C. J.; Barthelat, J.-C.; Rodriguez, V.; Conejero, S.; Sabo-Etienne, S.; Donnadieu, B.; Chaudret, B. Chem. Commun. 1999, 1315.
20. Sabo-Elienne, S.; Chaudret, B. Coord. Chem. Rev. 1998, 178-180, 381.
21. See Supporting Information for details on the synthesis and characterization of 2a and 2b.
22. Crystal data for 2b: pale yellow crystal, T = 160 K, monoclinic, C2/c, a = 19.588(2) Å, b = 12.1805(15) Å, c = 19.823(3) Å, β = 98.066 (15)°, Z = 8, R1 = 0.0281, GOF = 1.034.
23. (a) Grumbine, S. K.; Tilley, T. D.; Arnold, F. P.; Rheingold, A. L. J. Am. Chem. Soc. 1994, 116, 5495.
24. (b) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D.; Rheingold, A. L. Organometallics 1998, 17, 5607.
25. 17 were used to represent the 10-electron core of the Si and P atoms. For these atoms and for the hydrogen atoms directly attached to Si and Ru, double-ς plus polarization basis sets were used. All calculations were carried out with the Gaussian 98 program (see Supporting Information).
26. Rodriguez, V.; Sabo-Etienne, S.; Chaudret, B.; Thoburn, J.; Ulrich, S.; Limbach, H.-H.; Eckert, J.; Barthelat, J.-C.; Hussein, K.; Marsden, C. J. Inorg. Chem. 1998, 37, 3475.
27. Bouteiller, Y.; Mijoule, C.; Nizam, M.; Barthelat, J.-C.; Daudey, J.-P.; Pélissier, M.; Silvi, B. Mol. Phys. 1988, 65, 2664.
28. Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899.
29. 21
30. Curtis, M. D.; Epstein, P. S. Adv. Organomet. Chem. 1981, 19, 213.
31. Takao, T.; Yoshida, S.; Suzuki, H.; Tanaka, M. Organometallics 1995, 14, 3855.