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Volumn 11, Issue 21, 2009, Pages 4132-4135

Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C4H 9CCAg)nAg]+. Size does matter!

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EID: 65949104100     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/b904687a     Document Type: Article
Times cited : (15)

References (43)
  • 2
    • 84906476329 scopus 로고    scopus 로고
    • D. M. P. Mingos and R. H. Crabtree, Elsevier, Amsterdam, p. 197. For key structures see
    • V. W. W. Yam and E. C. C. Cheng, in Compr. Organomet. Chem. III, ed., D. M. P. Mingos, and, R. H. Crabtree, Elsevier, Amsterdam, 2007, vol. 2 (K. Mayer Ed.), p. 197. For key structures see
    • (2007) Compr. Organomet. Chem. III, Ed.
    • Yam, V.W.W.1    Cheng In, E.C.C.2
  • 15
    • 53549103314 scopus 로고    scopus 로고
    • There are dramatic examples in lithium acetylide chemistry where there can be orders of magnitude difference in reactivity between dimers and tetramers:
    • K. Murakami K. Hirano H. Yorimitsu K. Oshima Angew. Chem. Int. Ed. 2008 47 5833
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 5833
    • Murakami, K.1    Hirano, K.2    Yorimitsu, H.3    Oshima, K.4
  • 20
    • 33645460222 scopus 로고    scopus 로고
    • For a recent example of organozincates see:
    • R. A. J. O'Hair Chem. Comm. 2006 1469
    • (2006) Chem. Comm. , pp. 1469
    • O'Hair, R.A.J.1
  • 25
    • 65949119450 scopus 로고    scopus 로고
    • 3 (0.0005%)
    • Silver hexynyl was synthesized by the method of Létinois-Halbes et al.
  • 26
    • 65949101155 scopus 로고    scopus 로고
    • Note
    • 2O (50 to 50 ratio, 10 mL). The resulting mixture was diluted to a maximum concentration of ca. 1 mM of silver hexynyl. The sample was injected with a flow of approximately 5 μL/min. Typical electrospray source conditions involved needle potentials of 4.5-5.0 kV and heated capillary temperatures of 180-200 °C


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.