메뉴 건너뛰기




Volumn 16, Issue 14, 1997, Pages 3135-3147

Synergy of theory and experiment in the remote functionalization of aliphatic nitriles by "bare" Fe(I) and Co(I) cations in the gas phase

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001743018     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970229w     Document Type: Article
Times cited : (19)

References (109)
  • 3
    • 0001454068 scopus 로고
    • Selected reviews: (a) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121. (b) Eller, K. Coord. Chem. Rev. 1993, 126, 93. (c) Freiser, B. S. Acc. Chem. Res. 1994, 27, 353.
    • (1991) Chem. Rev. , vol.91 , pp. 1121
    • Eller, K.1    Schwarz, H.2
  • 4
    • 13344276647 scopus 로고
    • Selected reviews: (a) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121. (b) Eller, K. Coord. Chem. Rev. 1993, 126, 93. (c) Freiser, B. S. Acc. Chem. Res. 1994, 27, 353.
    • (1993) Coord. Chem. Rev. , vol.126 , pp. 93
    • Eller, K.1
  • 5
    • 0001248001 scopus 로고
    • Selected reviews: (a) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121. (b) Eller, K. Coord. Chem. Rev. 1993, 126, 93. (c) Freiser, B. S. Acc. Chem. Res. 1994, 27, 353.
    • (1994) Acc. Chem. Res. , vol.27 , pp. 353
    • Freiser, B.S.1
  • 7
    • 33845184460 scopus 로고
    • Reviews: (a) Schwarz, H. Acc. Chem. Res. 1989, 22, 282. (b) Czekay, G.; Drewello, T.; Eller, K.; Lebrilla, C. B.; Prüsse, T.; Schulze, C.; Steinrück, N.; Sülzle, D.; Weiske, T.; Schwarz, H. In Organometallics in Organic Synthesis; Werner, H., Erker, G., Eds., Springer: Heidelberg, 1989; Vol. 2, p 203.
    • (1989) Acc. Chem. Res. , vol.22 , pp. 282
    • Schwarz, H.1
  • 19
    • 84984311142 scopus 로고
    • (d) For a complete transition-metal ion screening, see: Eller, K.; Schwarz, H. Chem. Ber. 1990, 123, 201.
    • (1990) Chem. Ber. , vol.123 , pp. 201
    • Eller, K.1    Schwarz, H.2
  • 33
    • 33745181247 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) J. Chem. Phys. , vol.102 , pp. 4931
    • Holthausen, M.C.1    Heinemann, C.2    Cornehl, H.H.3    Koch, W.4    Schwarz, H.5
  • 34
    • 0000840558 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) Chem. Phys. Lett. , vol.240 , pp. 245
    • Holthausen, M.C.1    Mohr, M.2    Koch, W.3
  • 35
    • 0001082068 scopus 로고    scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1996) J. Chem. Phys. , vol.104 , pp. 4642
    • Heinemann, C.1    Schwarz, H.2    Koch, W.3    Dyall, K.G.4
  • 36
    • 0001444755 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) Chem. Phys. Lett. , vol.245 , pp. 150
    • Ricca, A.1    Bauschlicher Jr., C.W.2
  • 37
    • 21944454332 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) Theor. Chim. Acta , vol.92 , pp. 123
    • Ricca, A.1    Bauschlicher Jr., C.W.2
  • 38
    • 0000993764 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) J. Phys. Chem. , vol.99 , pp. 5922
    • Ricca, A.1    Bauschlicher Jr., C.W.2
  • 39
    • 0000837297 scopus 로고    scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1996) J. Chem. Phys. , vol.104 , pp. 9546
    • Blomberg, M.R.A.1    Siegbahn, P.E.R.2    Svensson, M.3
  • 40
    • 0001555202 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) Chem. Phys. Lett. , vol.233 , pp. 129
    • Barone, V.1
  • 41
    • 0000178914 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) J. Phys. Chem. , vol.99 , pp. 11659
    • Barone, V.1
  • 42
    • 4244198419 scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1995) Chem. Phys. Lett. , vol.246 , pp. 463
    • Adamo, C.1    Lelj, F.2
  • 43
    • 33751129536 scopus 로고    scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1996) J. Phys. Chem. , vol.100 , pp. 2094
    • Barone, V.1    Adamo, C.2
  • 44
    • 0031077496 scopus 로고    scopus 로고
    • See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
    • (1997) J. Phys. Chem. , vol.101 , pp. 1567
    • Pavlov, M.1    Blomberg, M.R.A.2    Siegbahn, P.E.M.3    Wesendrup, R.4    Heinemann, C.5    Schwarz, H.6
  • 45
    • 3843074731 scopus 로고    scopus 로고
    • Ph.D. Thesis, Technische Universität Berlin D83
    • (a) Holthausen, M. C. Ph.D. Thesis, Technische Universität Berlin D83, 1996.
    • (1996)
    • Holthausen, M.C.1
  • 47
    • 0030123831 scopus 로고    scopus 로고
    • (b) Holthausen, M. C.; Fiedler, A.; Schwarz, H.; Koch, W. Angew. Chem., Int. Ed. Engl. 1995, 34, 2282; J. Phys. Chem. 1996, 100, 6236.
    • (1996) J. Phys. Chem. , vol.100 , pp. 6236
  • 54
    • 3843139939 scopus 로고
    • Cray Research, Inc.
    • DGauss 2.3, Cray Research, Inc. 1994.
    • (1994) DGauss 2.3
  • 58
    • 0039499668 scopus 로고    scopus 로고
    • Wavefunction, Inc., 18401 Von Karman Ave., Suite 370, Irvine, CA 92715
    • Spartan 3.0, Wavefunction, Inc., 18401 Von Karman Ave., Suite 370, Irvine, CA 92715.
    • Spartan 3.0
  • 63
    • 3042988525 scopus 로고
    • (e) MM3 is a further development of the program MM2: Allinger, N. L. J. Am. Chem. Soc. 1977, 99, 8127.
    • (1977) J. Am. Chem. Soc. , vol.99 , pp. 8127
    • Allinger, N.L.1
  • 64
    • 3843143319 scopus 로고    scopus 로고
    • Reference 13a
    • (a) Reference 13a.
  • 70
    • 3843118212 scopus 로고    scopus 로고
    • note
    • This estimate is based on the maximum deviation from the average of two independent sets of measurements of the nonanitrile isotopologs.
  • 94
    • 85087581360 scopus 로고    scopus 로고
    • note
    • +) = 98.0 (65.0). Considering the experimental uncertainty and the limitations of the applied model, the agreement is quite satisfactory and demonstrates the validity of the approach.
  • 103
    • 85087579969 scopus 로고    scopus 로고
    • note
    • +/nonanitrile complex has been mass selected by means of B1 and E1, and the metastable ion decomposition spectra have been recorded with the subsequent magnetic sector B2. No olefin loss is observed, thus ruling out a consecutive reaction mechanism.
  • 104
    • 3843146720 scopus 로고    scopus 로고
    • note
    • Note that this formalism is hardly affected by the absolute heights of the barriers and only depends upon the difference for the various positions.
  • 105
    • 3843133503 scopus 로고    scopus 로고
    • note
    • + occurs as a continuously endothermic process without any significant barrier such that the internal energy that can be stored in these ions is much smaller, given that a similar time scale for unimolecular dissociation is sampled in both experiments.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.