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Selected reviews: (a) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121. (b) Eller, K. Coord. Chem. Rev. 1993, 126, 93. (c) Freiser, B. S. Acc. Chem. Res. 1994, 27, 353.
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Selected reviews: (a) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121. (b) Eller, K. Coord. Chem. Rev. 1993, 126, 93. (c) Freiser, B. S. Acc. Chem. Res. 1994, 27, 353.
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Schröder, D.; Heinemann, C.; Koch, W.; Schwarz, H. Pure Appl. Chem. 1997, 69, 273.
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Reviews: (a) Schwarz, H. Acc. Chem. Res. 1989, 22, 282. (b) Czekay, G.; Drewello, T.; Eller, K.; Lebrilla, C. B.; Prüsse, T.; Schulze, C.; Steinrück, N.; Sülzle, D.; Weiske, T.; Schwarz, H. In Organometallics in Organic Synthesis; Werner, H., Erker, G., Eds., Springer: Heidelberg, 1989; Vol. 2, p 203.
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Acc. Chem. Res.
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Schwarz, H.1
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Reviews: (a) Schwarz, H. Acc. Chem. Res. 1989, 22, 282. (b) Czekay, G.; Drewello, T.; Eller, K.; Lebrilla, C. B.; Prüsse, T.; Schulze, C.; Steinrück, N.; Sülzle, D.; Weiske, T.; Schwarz, H. In Organometallics in Organic Synthesis; Werner, H., Erker, G., Eds., Springer: Heidelberg, 1989; Vol. 2, p 203.
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Steinrück, N.7
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(c) Prüsse, T.; Drewello, T.; Lebrilla, C. B.; Schwarz, H. J. Am. Chem. Soc. 1989, 111, 2857.
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(d) Hankinson, D. J.; Miller, C. B.; Allison, J. J. Phys. Chem. 1989, 93, 3624.
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(a) Eller, K.; Zummack, W.; Schwarz, H. Int. J. Mass Spectrom. Ion Processes 1990, 100, 803.
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Int. J. Mass Spectrom. Ion Processes
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(b) Eller, K.; Karrass, S.; Schwarz, H. Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1201.
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Ber. Bunsen-Ges. Phys. Chem.
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(c) Eller, K.; Karrass, S.; Schwarz, H. Organometallics 1992, 11, 1637.
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Organometallics
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(d) For a complete transition-metal ion screening, see: Eller, K.; Schwarz, H. Chem. Ber. 1990, 123, 201.
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(a) Schröder, D.; Eller, K.; Schwarz, H. Helv. Chim. Acta 1990, 73, 380.
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Helv. Chim. Acta
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(b) Schröder, D.; Eller, K.; Prüsse, T.; Schwarz, H. Organometallics 1991, 10, 2052.
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Organometallics
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(c) Stöckigt, D.; Sen, S.; Schwarz, H. Chem. Ber. 1993, 126, 2553.
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(d) Stöckigt, D.; Sen, S.; Schwarz, H. Organometallics 1994, 13, 1465.
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Organometallics
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(e) Raabe, N.; Karass, S.; Schwarz, H. Chem. Ber. 1994, 127, 261.
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Chem. Ber.
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(a) Hornung, G.; Schröder, D.; Schwarz, H. J. Am. Chem. Soc. 1995, 117, 8192.
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(b) Hornung, G.; Schröder, D.; Schwarz, H. J. Am. Chem. Soc. 1997, 119, 2273.
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(b) Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.; Frisch, M. J. J. Phys. Chem. 1994, 98, 11623.
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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Chem. Phys. Lett.
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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Heinemann, C.1
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36
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0001444755
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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Chem. Phys. Lett.
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Ricca, A.1
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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Theor. Chim. Acta
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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See, for example: (a) Holthausen, M. C.; Heinemann, C.; Cornehl, H. H.; Koch, W.; Schwarz, H. J. Chem. Phys. 1995, 102, 4931. (b) Holthausen, M. C.; Mohr, M.; Koch, W. Chem. Phys. Lett. 1995, 240, 245. (c) Heinemann, C.; Schwarz, H.; Koch, W.; Dyall, K. G. J. Chem. Phys. 1996, 104, 4642. (d) Ricca, A.; Bauschlicher, C. W., Jr. Chem. Phys. Lett. 1995, 245, 150. (e) Ricca, A.; Bauschlicher, C. W., Jr. Theor. Chim. Acta 1995, 92, 123. (f) Ricca, A.; Bauschlicher, C. W., Jr. J. Phys. Chem. 1995, 99, 5922. (g) Blomberg, M. R. A.; Siegbahn, P. E. R.; Svensson, M. J. Chem. Phys. 1996, 104, 9546. (h) Barone, V. Chem. Phys. Lett. 1995, 233, 129. (i) Barone, V. J. Phys. Chem. 1995, 99, 11659. (j) Adamo, C.; Lelj, F. Chem. Phys. Lett. 1995, 246, 463. (k) Barone, V.; Adamo, C. J. Phys. Chem. 1996, 100, 2094. (l) Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem., 1997, 101, 1567.
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3843118212
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This estimate is based on the maximum deviation from the average of two independent sets of measurements of the nonanitrile isotopologs.
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-
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85087581360
-
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note
-
+) = 98.0 (65.0). Considering the experimental uncertainty and the limitations of the applied model, the agreement is quite satisfactory and demonstrates the validity of the approach.
-
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95
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(a) Czekay, G.; Drewello, T.; Eller, K.; Zummack, W.; Schwarz, H. Organometallics 1989, 8, 2439.
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103
-
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85087579969
-
-
note
-
+/nonanitrile complex has been mass selected by means of B1 and E1, and the metastable ion decomposition spectra have been recorded with the subsequent magnetic sector B2. No olefin loss is observed, thus ruling out a consecutive reaction mechanism.
-
-
-
-
104
-
-
3843146720
-
-
note
-
Note that this formalism is hardly affected by the absolute heights of the barriers and only depends upon the difference for the various positions.
-
-
-
-
105
-
-
3843133503
-
-
note
-
+ occurs as a continuously endothermic process without any significant barrier such that the internal energy that can be stored in these ions is much smaller, given that a similar time scale for unimolecular dissociation is sampled in both experiments.
-
-
-
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