Rhombic dodecahedral Ag 8M 6 (M = Cu, Ag, Au) cluster complexes of ferrocenylethynyl prepared by reaction of (AgC≡CFc) n with [M 2(Ph 2PNHPh 2) 2(MeCN) 2] 2+ (M = Cu, Ag, Au)

Organometallics

Volumn 25, Issue 21, 2006, Pages 4941-4944

  Wei, Qiao Hua ^a   Yin, Gang Qiang ^a   Zhang, Li Yi ^a   Chen, Zhong Ning ^a,b,c  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^c FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CLUSTER COMPLEXES; CYCLIC ADDITION; ELECTRONIC INTERACTIONS; SILVER FERROCENYLACETYLIDE;

COMPLEXATION; OXIDATION; REACTION KINETICS; REDOX REACTIONS;

SILVER COMPOUNDS;

EID: 33750332449     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0607346     Document Type: Article

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24. n (63.3 mg, 0.20 mmol) with stirring for 12 h to give a clear deep red solution. The solvents were removed in vacuo to afford a red residue, which was dissolved in 5 mL of dichloromethane. The solution was then chromatographed on a silica gel column (100-200 mesh). The first band was eluted using dichloromethane-acetone (50/3) to afford a small quantity of unidentified species. Elution of the second band using dichloromethane-acetone (5/1) gave the mauve compound 1. Yield: 18% (based on AgC≡ CFc). The third band was eluted using dichloromethane - acetone (1/1), affording compound 2 as a red product. Yield: 47% (based on AgC≡CFc). Detailed characterization data for compounds 1-4 is provided in the the Supporting Information.
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