The role of metallacycles in the chromium-catalyzed trimerization of ethylene

Organometallics

Volumn 16, Issue 8, 1997, Pages 1511-1513

  Emrich, Rainer ^a   Heinemann, Oliver ^a   Jolly, Peter W ^a   Krüger, Carl ^a   Verhovnik, Glenn P J ^a  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 5244338028     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om961044c     Document Type: Article

References (17)

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8. Satisfactory analytical and mass spectral data have been obtained for all compounds.
9. c) minimized. For the final refinement, the program GFMLX was used. Atomic coordinates, bond lengths and angles, and thermal parameters have been deposited at the Cambridge Crystallographic Data Centre. See Information for Authors, Issue No. 1.
10. For example, thermolysis of 5 at 200 °C leads to the liberation (MS identification) of 1-hexene (23.4%) as well as hydrogen (34.2%) and small (<10%) amounts of propane, propene, methane, ethane, bexane, and 1,3-butadiene, The main organic products of the thermolysis of the chromacyclopentane derivatives are 1-butene and ethylene.
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