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Volumn 22, Issue 13, 2003, Pages 2564-2570

Mechanism of ethene trimerization at an ansa-(arene)(cyclopentadienyl) titanium fragment

Author keywords

[No Author keywords available]

Indexed keywords

ARENE CYCLOPENTADIENYL; COSSEE-ARLMAN COORDINATION MIGRATORY INSERTION MECHANISMS; ETHENE; METALLACYCLE MECHANISM; TRIMERIZATION;

EID: 0037861823     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030049o     Document Type: Article
Times cited : (131)

References (50)
  • 7
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    • (Phillips Petroleum Co.) US 2,825,721
    • (a) Hogan, J. P.; Banks, R. L. (Phillips Petroleum Co.) US 2,825,721, 1958.
    • (1958)
    • Hogan, J.P.1    Banks, R.L.2
  • 10
    • 0038272904 scopus 로고
    • (Union Carbide) US-A 4,668,838
    • (d) Briggs, J. R. (Union Carbide) US-A 4,668,838, 1987.
    • (1987)
    • Briggs, J.R.1
  • 11
    • 0037597685 scopus 로고
    • (Phillips Petroleum) EP 416 304
    • (e) Reagan, W. K.; Conroy, B. K. (Phillips Petroleum) EP 416 304, 1990.
    • (1990)
    • Reagan, W.K.1    Conroy, B.K.2
  • 34
    • 0038272905 scopus 로고    scopus 로고
    • note
    • GAMESS-UK is a package of ab initio programs written by Guest, M. F.; Van Lenthe, J. H.; Kendrick, J.; Schoffel, K.; Sherwood, P. with contributions from Amos, R. D.; Buenker, R. J.; Van Dam, H. J. J.; Dupuis, M.; Handy, N. C.; Hillier, I. H.; Knowles, P. J.; Bonacic-Koutecky, V.; Von Niessen, W.; Harrison, R. J.; Rendell, A. P.; Saunders, V. R.; Stone, A. J.; Tozer, D. J.; De Vries, A. H. The package is derived from the original GAMESS code due to Dupuis, M.; Spangler, D.; Wendoloski, J. NRCC Software Catalog, Vol. 1, Program No. QG01 (GAMESS), 1980.
  • 36
    • 0037597686 scopus 로고    scopus 로고
    • note
    • Under reaction conditions, dissolved ethene is in equilibrium with gaseous ethene at 5 bar, so we can use the free energy for the gas-phase substrate without solvent corrections.
  • 49
    • 0038611842 scopus 로고    scopus 로고
    • note
    • 12m and higher olefins are produced, but again it is not clear whether these are formed at the same catalytic center as the trimer.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.