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Syntheses for 1 and 2: A mixture of H2TDA (0.3 mmol, 51.7 mg), 0.2 mmol of Ln(NO3)3 6H2O (Ln ) Gd (1), 90.6 mg; Dy (2), 91.3 mg), and 10 mL of water was heated in a 20 mL Teflon cup at 160 ?C for 3 days and then cooled to room temperature at a rate of 1.5 ?C h-1. The crystals of 1 and 2 were collected in 52% and 47% yields, respectively, based on Ln after being washed by water and diethyl ether. Elem anal. Calcd for 1: C, 24.10; H, 1.57; S, 10.72. Found: C, 24.33; H, 1.64; S, 11.01. Calcd for 2: C, 23.82; H, 1.56; S, 10.60. Found: C, 23.80; H, 1.58; S, 10.69.
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