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(a) Bontemps, S.; Gomitzka, H.; Bouhadir, G.; Miqueu, K.; Bourissou, D. Angew. Chem., Int. Ed. 2006, 45, 1611.
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(b) Bontemps, S.; Sircoglou, M.; Bouhadir, G.; Puschmann, H.; Howard, J. A. K.; Dyer, P. W.; Miqueu, K.; Bourissou, D. Chem. Eur. J. 2008, 14, 731.
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36549064306
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15
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0034813795
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+R(THF)], with no direct M-B bond interaction was reported by Peters et al. In this complex, the electron-donating property of the borate moiety enhanced the electron density of phosphorus atoms, which resulted in higher electron density of the Pt center, leading to successful C-H bond activation of arenes. See: (a) Thomas, S. J.; Peters, J. C. J. Am. Chem. Soc. 2001, 123, 5100.
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+R(THF)], with no direct M-B bond interaction was reported by Peters et al. In this complex, the electron-donating property of the borate moiety enhanced the electron density of phosphorus atoms, which resulted in higher electron density of the Pt center, leading to successful C-H bond activation of arenes. See: (a) Thomas, S. J.; Peters, J. C. J. Am. Chem. Soc. 2001, 123, 5100.
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17
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0000181981
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For closely related examples, see
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(a) Choukroun, R.; Iraq, A.; Gervais, D.; Daran, J. -C.; Jeannin, Y. Organometallics 1987, 6, 1197. For closely related examples, see:
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Iraq, A.2
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0000820430
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(b) Ferguson, G. S.; Wolczanski, P. T.; Párkányi, L.; Zonnevylle, M. C. Organometallics 1988, 7, 1967.
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(c) Baxter, S. M.; Ferguson, G. S.; Wolczanski, P. T. J. Am. Chem. Soc. 1988, 110, 4231.
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12844277296
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2. See: (a) Cornelissen, C: Erker, G.; Kehr, G.; Fröhlich, R. Organometallics 2005, 24, 214.
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2. See: (a) Cornelissen, C: Erker, G.; Kehr, G.; Fröhlich, R. Organometallics 2005, 24, 214.
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21
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0000625123
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(b) Bosch, B. E.; Brümmer, L: Kunz, K.; Erker, G.; Fröhlich, R.; Kotila, S. Organometallics 2000, 19, 1255.
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33745118029
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(c) Cornelissen, C.; Erker, G.; Kehr, G.; Fröhlich, R. Dalton Trans. 2005, 24, 4059.
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65349116847
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See ref 5
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(d) See ref 5.
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24
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0002894082
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For other examples of early-late heterobimetallic complexes which can act as catalysts for hydroformylation, see: (a) Choukroun, R, Gervais, D, Kalck, P, Senocq, F. J. Organomet. Chem. 1987, 335, C9
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For other examples of early-late heterobimetallic complexes which can act as catalysts for hydroformylation, see: (a) Choukroun, R.; Gervais, D.; Kalck, P.; Senocq, F. J. Organomet. Chem. 1987, 335, C9.
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3543012739
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(b) Choukroun, R.; Gervais, D.; Rifai, C. Polyhedron 1989, 8, 1760.
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(c) Trzeciak, A. M.; Ziólkowski, J. J.; Choukroun, R. J. Organomet. Chem. 1991, 420, 353.
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0000582390
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(e) Choukroun, R.; Dahan, F.; Gervais, D.; Rifai, C. Organometallics 1990, 9, 1982.
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4644281746
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(g) Priva, S.; Balakrishna, M. S.; Mague, J. T. J. Organomet. Chem. 2004, 689, 3335.
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30
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65349133835
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Complexes of type C including early and late transition elements have been investigated in the chemistry of early-late heterobimetallic (ELHB) complexes. There are several ELHB complexes with a dative bond, in which the M1-M2 interaction is discussed from the point of view of crystallography and theoretical calculations.9 However, only a few papers have been reported on the reactivities
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9 However, only a few papers have been reported on the reactivities.
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36
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33646354387
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(a) Nagashima, H.; Sue, T.; Oda, T.; Kanemitsu, A.; Matsumoto, T.; Motoyama, Y.; Sunada, Y. Organometallics 2006, 25, 1987.
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37
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33745131741
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(b) Sunada, Y.; Sue, T.; Matsumoto, T.; Nagashima, H. J. Organomet. Chem. 2006, 691, 3176.
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(c) Sue, T.; Sunada, Y.; Nagashima, H. Eur. J. lnorg. Chem. 2007, 18, 2897.
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39
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43749110500
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Cordero, B.; Gómez, V.; Platero-Prats, A. E.; Revés, M.; Echeverría, J.; Cremades, E.; Barragán, F.; Alvarez, S. Dalton Trans. 2008, 2832.
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Cordero, B.1
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Revés, M.4
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Cremades, E.6
Barragán, F.7
Alvarez, S.8
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40
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65349147961
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2 center of 2a-c were reduced compared with those of 3a-c.
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2 center of 2a-c were reduced compared with those of 3a-c.
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41
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65349187329
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One of the reviewers suggested that NBO analysis may be a better tool for understanding the bonding situation. According to this suggestion, we carried out the NBO calculations of complexes 2a-c at various levels of theory. However, the Ti-M interaction is too weak to describe the bonding situation in 2a-c for NBO calculations
-
One of the reviewers suggested that NBO analysis may be a better tool for understanding the bonding situation. According to this suggestion, we carried out the NBO calculations of complexes 2a-c at various levels of theory. However, the Ti-M interaction is too weak to describe the bonding situation in 2a-c for NBO calculations.
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42
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65349144934
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31P NMR spectra of the latter are complicated, suggesting decomposition of 2a-c under these conditions.
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31P NMR spectra of the latter are complicated, suggesting decomposition of 2a-c under these conditions.
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43
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65349135030
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Catalytic allylation with nucleophiles is generally performed by using allyl carboxylates or allyl carbonates.16 Since the complexes 2a-c are generally sensitive toward compounds containing oxygen atoms, exposure of 2a-c to allyl carboxylates or allyl carbonates instantly results in decomposition of the complexes. Interestingly, 2a-c are stable toward the compounds containing halogen atoms, and the reactions with allyl chloride proceed smoothly as described in the text
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16 Since the complexes 2a-c are generally sensitive toward compounds containing oxygen atoms, exposure of 2a-c to allyl carboxylates or allyl carbonates instantly results in decomposition of the complexes. Interestingly, 2a-c are stable toward the compounds containing halogen atoms, and the reactions with allyl chloride proceed smoothly as described in the text.
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45
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0003321649
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Transition Metal Allyl Complexes: Pd, W, Mo-assisted Nucleophilic Attack
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Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon Press: New York, Chapter 8.2
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(b) Harrington, P. J. Transition Metal Allyl Complexes: Pd, W, Mo-assisted Nucleophilic Attack. In Comprehensive Organometallic Chemistty II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: New York, 1995; Vol. 12, Chapter 8.2.
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Frost, C.G.1
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