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Volumn 27, Issue 10, 2008, Pages 2321-2327

Synthesis and reactions of diphosphinidenecyclobutene ruthenium complexes relevant to catalytic hydrosilylation of terminal alkynes

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; CHEMICAL REACTIONS; COBALT COMPOUNDS; COMPLEXATION; HYDROCARBONS; HYDROSILYLATION; RUTHENIUM;

EID: 44649120296     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800119f     Document Type: Article
Times cited : (25)

References (56)
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    • Ruthenium catalysts giving 2-silyl-1-alkenes have also been reported: (a) Trost, B. M.; Ball, Z. T J. Am. Chem. Soc. 2001, 123, 12726.
    • Ruthenium catalysts giving 2-silyl-1-alkenes have also been reported: (a) Trost, B. M.; Ball, Z. T J. Am. Chem. Soc. 2001, 123, 12726.
  • 24
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    • DPCB-OMe: 1,2-bis(4-methoxyphenyl)-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]cyclobutene. See for review: Ozawa, F.; Yoshifuji, M. Dalton Trans. 2006, 4987.
    • DPCB-OMe: 1,2-bis(4-methoxyphenyl)-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]cyclobutene. See for review: Ozawa, F.; Yoshifuji, M. Dalton Trans. 2006, 4987.
  • 30
    • 44649096253 scopus 로고    scopus 로고
    • For the mechanism of trans-insertion, see: a
    • (a) For the mechanism of trans-insertion, see: (a) Ref 3a.
    • , vol.3 a
    • Ref1
  • 33
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    • 4c
    • 4c
  • 40
    • 44649103204 scopus 로고    scopus 로고
    • 2 containing ca. 25 mM of water as confirmed by the Karl-Fischer analysis.
    • 2 containing ca. 25 mM of water as confirmed by the Karl-Fischer analysis.
  • 49
    • 44649124154 scopus 로고    scopus 로고
    • 2Ph) catalyzed by HCl, which is generated from 8a in the formation of 9a.
    • 2Ph) catalyzed by HCl, which is generated from 8a in the formation of 9a.
  • 50
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    • 8a
    • 8a
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    • It has been confirmed that the amounts of styrene and PhMe 2SiOSiMe2Ph are nearly twice the amount of residual water in the system, showing the following stoichiometry: 2PhC≡CH, H 2O, 2HSiMe2Ph 2a(catalyst) 2PhCH=CH2, 2PhMe2SiOSiMe2Ph
    • 2Ph
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    • Frisch, M. J, Tracks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Zakrzewski, V. G, Montgomery Jr, J. A, Stratmann, R. E, Burant, J. C, Dapprich, S, Millam, J. M, Daniels, A. D, Kudin, K. N, Strain, M. C, Farkas, O, Tomasi, J, Barone, V, Cossi, M, Cammi, R, Mennucci, B, Pomelli, C, Adamo, C, Clifford, S, Ochterski, J, Petersson, G. A, Ayala, P. Y, Cui, Q, Morokuma, K, Malick, D. K, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Cioslowski, J, Ortiz, J. V, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Gomperts, R, Martin, R. L, Fox, D. J, Keith, T, Al-Laham, M. A, Peng, C. Y, Nanayakkara, A, Gonzalez, C, Challacombe, M, Gill, P. M. W, Johnson, B, Chen, W, Wong, M. W, Andres, J. L, Gonzalez, C, Head-Gordon, M, Replogle, E. S, Pople, J. A. Gaussian 98, Revision A.9; Gaussian, Inc, Pittsburgh, PA, 1998
    • Frisch, M. J.; Tracks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery Jr.; J. A.; Stratmann, R. E. ; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Andres, J. L.; Gonzalez, C.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. Gaussian 98, Revision A.9; Gaussian, Inc.: Pittsburgh, PA, 1998.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.