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Volumn 113, Issue 11, 2009, Pages 3477-3490

Energetic and entropic analysis of mirror symmetry breaking processes in a recycled microreversible chemical system

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL SYSTEMS; DYNAMICAL BEHAVIORS; ENTROPIC ANALYSIS; HOMOCHIRALITY; IN LINES; MIRROR SYMMETRY BREAKING; NON EQUILIBRIUMS; ORIGIN OF LIVES; SOURCE OF ENERGIES; STEADY STATE; THERMODYNAMIC STUDIES;

EID: 65249093780     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp803807p     Document Type: Article
Times cited : (28)

References (82)
  • 2
    • 0004161153 scopus 로고
    • Oxford University Press: New York, Oxford
    • (b) Kauffman, S. The Origin of Order; Oxford University Press: New York, Oxford, 1993.
    • (1993) The Origin of Order
    • Kauffman, S.1
  • 15
    • 65249133259 scopus 로고    scopus 로고
    • Fundamentals of Life; Pa'lyi, G
    • Zucchi, C, Caglioli, L, Eds, Paris
    • (e) Fundamentals of Life; Pa'lyi, G., Zucchi, C., Caglioli, L., Eds.; Elsevier Life Sci.: Paris, 2002.
    • (2002) Elsevier Life Sci
  • 16
    • 84902220478 scopus 로고    scopus 로고
    • Pa'lyi, G, Zucchi, C, Caglioli, L, Eds, Elsevier: Oxford
    • (f) Progress in Biological Chirality; Pa'lyi, G., Zucchi, C., Caglioli, L., Eds.; Elsevier: Oxford, 2004.
    • (2004) Progress in Biological Chirality
  • 40
  • 41
    • 84888574776 scopus 로고    scopus 로고
    • 15b and in order to avoid confusion with the different quantities, the notion of chemical fluxes15c will be used for the reactions (noted φ), while the notion of rate of appearance15d will be used for the compounds (noted V)
    • Following the IUPAC definitions
    • (a) Following the IUPAC definitions,15b and in order to avoid confusion with the different quantities, the notion of chemical fluxes15c will be used for the reactions (noted φ), while the notion of rate of appearance15d will be used for the compounds (noted V). A superscript "e" indicates a parameter relative to exchanges, and a superscript "i" a parameter relative to internal transformations.
    • A superscript e
  • 42
    • 84888522769 scopus 로고    scopus 로고
    • McNaught, A, Wilkinson, A. IUPAC. Compendium of Chemical Terminology Gold Book, 2nd ed, Blackwell Scientific Publications: Oxford, 1997. XML on-line corrected version created by M. Nic, J. Jirat, B Kosata; updates compiled by A. Jenkins. Last update: 2008-09-12; version 2.0.1
    • (b) McNaught, A.; Wilkinson, A. IUPAC. Compendium of Chemical Terminology ("Gold Book"), 2nd ed.; Blackwell Scientific Publications: Oxford, 1997. XML on-line corrected version created by M. Nic, J. Jirat, B Kosata; updates compiled by A. Jenkins. Last update: 2008-09-12; version 2.0.1.
  • 43
    • 84888523035 scopus 로고    scopus 로고
    • Chemical Flux φ. http://goldbook.iupac.org/C01024.html, DOI: 10.1351/ goldbook.C01024.
    • (c) Chemical Flux φ. http://goldbook.iupac.org/C01024.html, DOI: 10.1351/ goldbook.C01024.
  • 44
    • 84888559959 scopus 로고    scopus 로고
    • Rate of Appearance. http://goldbook.iupac.org/ R05143.html, DOI: 10.1351/goldbook.R05143.
    • (d) Rate of Appearance. http://goldbook.iupac.org/ R05143.html, DOI: 10.1351/goldbook.R05143.
  • 45
    • 84888493475 scopus 로고    scopus 로고
    • Microscopic Reversibility at Equilibrium. http://goldbook.iupac.org/ M03916.html, DOI: 10.1351/goldbook.M03916.
    • (e) Microscopic Reversibility at Equilibrium. http://goldbook.iupac.org/ M03916.html, DOI: 10.1351/goldbook.M03916.
  • 46
    • 84888566137 scopus 로고    scopus 로고
    • Detailed Balancing (Principle Of). http:// goldbook.iupac.org/D01626. html, DOI: 10.1351/goldbook.D01626.
    • (f) Detailed Balancing (Principle Of). http:// goldbook.iupac.org/D01626. html, DOI: 10.1351/goldbook.D01626.
  • 52
    • 33847087926 scopus 로고
    • Boyd, R. K. Chem. Rev. 1977, 77, 93-119.
    • (1977) Chem. Rev , vol.77 , pp. 93-119
    • Boyd, R.K.1
  • 53
    • 0009668714 scopus 로고
    • Klein, M. J. Phys. Rev. 1955, 97, 1446-1447.
    • (1955) Phys. Rev , vol.97 , pp. 1446-1447
    • Klein, M.J.1
  • 59
    • 84888494120 scopus 로고    scopus 로고
    • XPP-Aut v5.85. http://www.math.pitt.edu/∼bard/xpp/xpp.html. The .ode files used for the simulations are available in the Supporting Information.
    • XPP-Aut v5.85. http://www.math.pitt.edu/∼bard/xpp/xpp.html. The .ode files used for the simulations are available in the Supporting Information.
  • 67
    • 84888478576 scopus 로고    scopus 로고
    • It must be noted that the real activation and deactivation reactions are actually more complex than the simple reactions described in the model. The real reactions can easily be reduced to the simplified one. Typically, the implicit chemical compounds are such as water molecules, compounds resulting from acido-basic exchanges, or additional waste molecules having neglectable influence on the kinetics
    • It must be noted that the real activation and deactivation reactions are actually more complex than the simple reactions described in the model. The real reactions can easily be reduced to the simplified one. Typically, the implicit chemical compounds are such as water molecules, compounds resulting from acido-basic exchanges, or additional waste molecules having neglectable influence on the kinetics.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.