STM images of a large organic molecule adsorbed on a bare metal substrate or on a thin insulating layer: Visualization of HOMO and LUMO

Surface Science

Volumn 603, Issue 10-12, 2009, Pages 1526-1532

  Villagomez, Carlos Javier ^a   Zambelli, Tomaso ^a   Gauthier, Sébastien ^a   Gourdon, André ^a   Stojkovic, Sladjana ^a   Joachim, Christian ^a  

^a CEMES CNRS   (France)

Author keywords

Hyperconjugation; Insulating thin layer; LT STM; Molecular orbitals

Indexed keywords

BI LAYERS; CU(111); FRONTIER ORBITALS; HIGHEST OCCUPIED MOLECULAR ORBITALS; HYPERCONJUGATION; HYPERCONJUGATIVE INTERACTIONS; INSULATING THIN LAYER; LOW TEMPERATURES; LOWEST UN-OCCUPIED MOLECULAR ORBITALS; LT STM; METAL SUBSTRATES; METAL SURFACES; METHYL GROUPS; ORGANIC MOLECULES; PROBABILITY DENSITIES; QUANTUM CHEMISTRY CALCULATIONS; SALT LAYERS; SPATIAL DISTRIBUTIONS; STM IMAGES; TERRYLENE; THIN INSULATING LAYERS; ULTRA-HIGH VACUUMS;

CHEMICAL BONDS; HYDROCARBONS; MOLECULAR MODELING; MOLECULES; PROBABILITY DENSITY FUNCTION; SCANNING TUNNELING MICROSCOPY; SIZE DISTRIBUTION; SODIUM CHLORIDE;

MOLECULAR ORBITALS;

EID: 65149094744     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.susc.2008.10.057     Document Type: Article

References (36)

1. Mulliken R.S. Physical Review 41 (1932) 49
2. Schwarz W.H.E. Angewandte Chemie-International Edition 45 (2006) 1508
3. Melmed A.J., and Muller E.W. Journal of Chemical Physics 29 (1958) 1037
4. Itatani J., Levesque J., Zeidler D., Niikura H., Pepin H., Kieffer J.C., Corkum P.B., and Villeneuve D.M. Nature 432 (2004) 867
5. Uyeda N., Kobayashi T., Suito E., Harada Y., and Watanabe M. Journal of Applied Physics 43 (1972) 5181
6. Ohtani H., Wilson R.J., Chiang S., and Mate C.M. Physical Review Letters 60 (1988) 2398
7. Smith D.P.E., Horber J.K.H., Binnig G., and Nejoh H. Nature 344 (1990) 641
8. Lee H.S., Iyengar S., and Musselman I.H. Langmuir 14 (1998) 7475
9. Lippel P.H., Wilson R.J., Miller M.D., Woll C., and Chiang S. Physical Review Letters 62 (1989) 171
10. Sautet P. Chemical Reviews 97 (1997) 1097
11. Chiang S. Chemical Reviews 97 (1997) 1083
12. Sautet P., and Joachim C. Surface Science 271 (1992) 387
13. Chavy C., Joachim C., and Altibelli A. Chemical Physics Letters 214 (1993) 569
14. Pascual J.I., Gomez-Herrero J., Rogero C., Baro A.M., Sanchez-Portal D., Artacho E., Ordejon P., and Soler J.M. Chemical Physics Letters 321 (2000) 78
15. Folsch S., Barjenbruch U., and Henzler M. Thin Solid Films 172 (1989) 123
16. Bennewitz R., Bammerlin M., Guggisberg M., Loppacher C., Baratoff A., Meyer E., and Guntherodt H.J. Surface and Interface Analysis 27 (1999) 462
17. Folsch S., Helms A., and Rieder K.H. Applied Surface Science 162 (2000) 270
18. Baumer M., and Freund H.J. Progress in Surface Science 61 (1999) 127
19. Qiu X.H., Nazin G.V., and Ho W. Physical Review Letters 92 (2004) 206102
20. Kresse G., Schmid M., Napetschnig E., Shishkin M., Kohler L., and Varga P. Science 308 (2005) 1440
21. Repp J., Meyer G., Stojkovic S.M., Gourdon A., and Joachim C. Physical Review Letters 94 (2005) 026083
22. Repp J., Meyer G., Paavilainen S., Olsson F.E., and Persson M. Science 312 (2006) 1196
23. Liljeroth P., Repp J., and Meyer G. Science 317 (2007) 1203
24. OmicronNanoTechnology GmbH Limburger Str. 75 65232 Taunusstein (Germany).
25. Villagomez C.J., Zambelli T., Gauthier S., Gourdon A., Barthes C., Stojkovic S., and Joachim C. Chemical Physics Letters 450 (2007) 107
26. .
27. Sautet P., and Joachim C. Chemical Physics Letters 185 (1991) 23
28. Halasinski T.M., Weisman J.L., Ruiterkamp R., Lee T.J., Salama F., and Head-Gordon M. Journal of Physical Chemistry A 107 (2003) 3660
29. Clar E., and Schmidt W. Tetrahedron 34 (1978) 3219
30. Malloci G., Mulas G., Cappellini G., Fiorentini V., and Porceddu I. Astronomy and Astrophysics 432 (2005) 585
31. Repp J., Meyer G., Paavilainen S., Olsson F.E., and Persson M. Physical Review Letters 95 (2005) 225503
32. Eigler D.M., Weiss P.S., Schweizer E.K., and Lang N.D. Physical Review Letters 66 (1991) 1189
33. Libit L., and Hoffmann R. Journal of the American Chemical Society 96 (1974) 1370
34. Mikaelian G., Ogawa N., Tu X.W., and Ho W. Journal of Chemical Physics 124 (2006) 1131101
35. Guirado G., Coudret C., Hliwa M., and Launay J.P. Journal of Physical Chemistry B 109 (2005) 17445
36. Launay J.P. Chemical Society Reviews 30 (2001) 386