Octahedral perfluoroalkyl complexes of Ir(III) formed by oxidative addition of perfluoroalkyl iodides to Ir(acac)(CO)2

Canadian Journal of Chemistry

Volumn 87, Issue 1 SPEC. ISS., 2009, Pages 151-160

  Huang, Hui ^a   Hurubeanu, N Raluca ^a   Bourgeois, Cheryl J ^a   Cheah, Sue Mei ^a   Yuan, Jian ^a   Rheingold, Arnold L ^b   Hughes, Russell P ^a  

^a Lamont Doherty Earth Observatory   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Carbonyl; DFT; Fluoroalkyl; Iridium; Oxidation

Indexed keywords

ACCEPTOR PROPERTIES; BACK-BONDING; BENZYLIC; CARBONYL; CO LIGANDS; CO STRETCHING FREQUENCIES; CRYSTALLOGRAPHIC STUDIES; DFT; FLUOROALKYL; KINETIC PRODUCT; NATURAL BOND ORBITAL ANALYSIS; OXIDATIVE ADDITIONS; PHOSPHINE-FREE; QUANTITATIVE ESTIMATION; SOLUTION SPECTROSCOPY; THERMODYNAMIC CONTROL; TRIFLATE;

CARBON MONOXIDE; CARBONYLATION; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; LIGANDS; OXIDATION; PHOSPHORUS COMPOUNDS; PROBABILITY DENSITY FUNCTION; STEREOCHEMISTRY; SUGAR (SUCROSE);

IRIDIUM;

EID: 64749115617     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/V08-114     Document Type: Article

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