Does α-Fluorination Affect the Structural trans-Influence and Kinetic trans-Effect of an Alkyl Ligand? Molecular Structures of Pd(TMEDA)(CH3)(RF) and a Kinetic Study of the trans to cis Isomerization of Pt(TMEDA)(CH3)2I(RF) [RF = CF2CF3, CFHCF3, CH 2CF3]

Inorganic Chemistry

Volumn 43, Issue 2, 2004, Pages 747-756

  Hughes, Russell P ^a   Meyer, Monique A ^a   Tawa, Mark D ^a   Ward, Antony J ^a   Williamson, Alex ^a   Rheingold, Arnold L ^b   Zakharov, Lev N ^b  

^a Dartmouth College   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; ETHYLENEDIAMINE DERIVATIVE; FLUORINE DERIVATIVE; IODINE DERIVATIVE; N,N,N',N' TETRAMETHYLETHYLENEDIAMINE; PALLADIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; FLUORINATION; ISOMERIZATION; KINETICS; OXIDATION; REACTION ANALYSIS; X RAY DIFFRACTION;

EID: 1642477546     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic030251j     Document Type: Article

References (50)

1. Pidcock, A.; Richards, R. E.; Venanzi, L. M. J. Chem. Soc. A 1966, 1707-1710.
2. Appleton, T. G.; Clark, H. C.; Manzer, L. E. Coord. Chem. Rev. 1973, 10, 335-422.
3. Atwood, J. D. Inorganic and organometallic reaction mechanisms, 2nd ed.; VCH Publishers: New York, 1997.
4. Inorganic chemistry, 3rd ed.; Shriver, D. F., Atkins, P. W., Eds.; W. H. Freeman and Co.: New York, 1999.
5. Blanchard, M. D.; Hughes, R. P.; Concolino, T. E.; Rheingold, A. L. Chem. Mater. 2000, 12, 1604-1610.
6. Richardson, D. E.; Lang, L.; Eyler, J. R.; Kircus, S. R.; Zheng, X.; Morse, C. A.; Hughes, R. P. Organometallics 1997, 16, 149-150.
7. Lichtenberger, D. L.; Elkadi, Y.; Gruhn, N. E.; Hughes, R. P.; Curnow, O. J.; Zheng, X. Organometallics 1997, 16, 5209-5217.
8. Hughes, R. P.; Overby, J. S.; Williamson, A.; Lam, K.-C.; Concolino, T. E.; Rheingold, A. L. Organometallics 2000, 19, 5190-5201.
9. Hughes, R. P.; Smith, J. M.; Liable-Sands, L. M.; Concolino, T. E.; Lam, K.-C.; Incarvito, C.; Rheingold, A. L. J. Chem. Soc., Dalton Trans. 2000, 873-879.
10. Bowden, A. A.; Hughes, R. P.; Lindner, D. C.; Incarvito, C. D.; Liable-Sands, L. M.; Rheingold, A. L. J. Chem. Soc., Dalton Trans. 2002, 3245-3252.
11. Johnston, B. F.; Rankin, D. W. H.; Robertson, H. E.; Hughes, R. P.; Lomprey, J. R. Organometallics 2002, 21, 4840-4846.
12. Hughes, R. P. Adv. Organomet. Chem. 1990, 31, 183-267.
13. Bennett, M. A.; Chee, H.-K.; Robertson, G. B. Inorg. Chem. 1979, 18, 1061-1070.
14. Bennett, M. A.; Chee, H.-K.; Jeffery, J. C.; Robertson, G. B. Inorg. Chem. 1979, 18. 1071-1076.
15. Hall, M. B.; Fenske, R. F. Inorg. Chem. 1972, 11, 768-775.
16. Landis, C. R.; Firman, T. K.; Root, D. M.; Cleveland, T. J. Am. Chem. Soc. 1998, 120, 1842-1854.
17. Appleton, T. G.; Hall, J. R.; Kennard, C. H. L.; Mathieson, M. T.; Neale, D. W.; Smith, G.; Mak, T. C. W. J. Organomet. Chem. 1993, 453, 299-306.
18. Coe, B. J.; Glenwright, S. J. Coord. Chem. Rev. 2000, 203, 5-80.
19. Flood, T. C.; Lim, J. K., Deming, M. A. Organometallics 2000, 19, 2310-2317.
20. Flood, T. C.; Lim, J. K.; Deming, M. A.; Keung, W. Organometallics 2000, 19, 1166-1174.
21. Wovkulich, M. J.; Atwood, J. D. Organometallics 1982, 1, 1316-1321.
22. Hughes, R. P.; Sweetser, J. T.; Tawa, M. D.; Williamson, A.; Incarvito, C. D.; Rhatigan, B.; Rheingold, A. L.; Rossi, G. Organometallics 2001, 20, 3800-3810.
23. Schorn, C.; Naumann, D.; Scherer, H.; Hahn, J. J. Fluorine Chem. 2001, 107, 159-169.
24. Baar, C. R.; Jenkins, H. A.; Vittal, J. J.; Yap, G. P. A.; Puddephatt, R. J. Organometallics 1998, 17, 2805-2818.
25. Levy, C. J.; Puddephatt, R. J. J. Am. Chem. Soc. 1997, 119, 10127-10136.
26. Monaghan, P. K.; Puddephatt, R. J. J. Chem. Soc., Dalton Trans. 1988, 595-599.
27. Crespo, M.; Puddephatt, R. J. Organometallics 1987, 6, 2548-2550.
28. Jawad, J. K.; Puddephatt, R. J. J. Chem. Soc., Dalton Trans. 1977, 1466-1469.
29. Jawad, J. K.; Puddephatt, R. J. J. Organomet. Chem. 1976, 117, 297-302.
30. Levy, C. J.; Puddephatt, R. J.; Vittal, J. J. Organometallics 1994, 13, 1559-1560.
31. Janzen, M. C.; Jennings, M. C.; Puddephatt, R. J. Inorg. Chem. 2003, 42, 4553-4558.
32. Springer, C. S., Jr. J. Am. Chem. Soc. 1973, 95, 1459-1467.
33. Ugi, I.; Marquarding, D.; Klusacek, H.; Gillespie, P.; Ramirez, F. Acc. Chem. Res. 1971, 4, 288-296.
34. Goldberg, K. I.; Yan, J.; Breitung, E. M. J. Am. Chem. Soc. 1995, 117, 6889-6896.
35. Reichardt, C. Solvents and Solvent Effects in Organic Chemistry, 3rd ed. ; Wiley-VCH: Weinheim, 2003.
36. Byers, P. K.; Canty, A. J.; Crespo, M.; Puddephatt, R. J.; Scott, J. D. Organometallics 1988, 7, 1363-1367.
37. Hill, G. S.; Puddephatt, R. J. Organometallics 1997, 16, 4522-4524.
38. Brown, M. P.; Puddephatt, R. J.; Upton, C. E. E. J. Chem. Soc., Dalton Trans. 1974, 2457-2465.
39. Brown, M. P.; Puddephatt, R. J.; Upton, C. E. E. Proc. Int. Conf. Coord. Chem. 16th 1974, 3.22, 23 pp.
40. Lowry, T. H.; Richardson, K. S. Mechanism and theory in organic chemistry, 3rd ed.; Harper & Row: New York, 1987.
41. Fainberg, A. H.; Winstein, S. J. Am. Chem. Soc. 1956, 78, 2763-2767.
42. Winstein, S.; Klinedinst, P. E., Jr.; Robinson, G. C. J. Am. Chem. Soc. 1961, 83, 885-895.
43. Winstein, S.; Robinson, G. C. J. Am. Chem. Soc. 1958, 80, 169-181.
44. Atwood, J. D.; Wovkulich, M. J.; Sonnenberger, D. C. Acc. Chem. Res. 1983, 16, 350-355.
45. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518-1520.
46. Monaghan, P. K.; Puddephatt, R. J. Organometallics 1984, 3, 444-449.
47. Yang, D. S.; Bancroft, G. M.; Dignard-Bailey, L.; Puddephatt, R. J.; Tse, J. S. Inorg. Chem. 1990, 29, 2487-2495.
48. de Graaf, W.; Boersma, J.; Smeets, W. J. J.; Spek, A. L.; van Koten, G. Organometallics 1989, 8, 2907-2917.
49. Walker, N.; Stuart, D. Acta Crystallogr., Sect. A. 1983, 39, 158-166.
50. Sheldrick, G. M. SADABS (2.01) Bruker/Siemens Area Detector Absorption Correction Program; Bruker AXS: Madison, WI, 1998