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Volumn 48, Issue 5, 2009, Pages 2260-2268

Concerted dismutation of chlorite ion: Water-soluble iron-porphyrins as first generation model complexes for chlorite dismutase

Author keywords

[No Author keywords available]

Indexed keywords

BIOMIMETIC MATERIAL; CHLORATE; CHLORIDE; CHLORITE; CHLORITE DISMUTASE; IRON; METALLOPORPHYRIN; OXIDIZING AGENT; OXIDOREDUCTASE; OXYGEN; WATER;

EID: 64649104265     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801681n     Document Type: Article
Times cited : (37)

References (85)
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    • For examples of iron-mediated chorite redox chemistry, see (a) Fábián, I. Prog. Nucl. Energy 2000, 37, 47
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    • For examples of iron-catalyzed decomposition of chlorite, see (a) Launer, H. F.; Wilson, W. K.; Flynn, J. H. J. Res. Nat. Bur. Stand. 1953 51, 237.
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    • For examples of metal-free decomposition of chlorite, see (a) Leitner, N. K.V, Delaat, J, Dore, M. Water Res. 1992. 26, 1655
    • For examples of metal-free decomposition of chlorite, see (a) Leitner, N. K.V.; Delaat, J.; Dore, M. Water Res. 1992. 26, 1655.
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    • For examples of hypochlorite decomposition studies, see (a) Lister, M. W. Can. J. Chem. 1956, 34, 479
    • For examples of hypochlorite decomposition studies, see (a) Lister, M. W. Can. J. Chem. 1956, 34, 479.
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    • 4TMAP) was assumed constant for each plot under steady-state conditions, i.e., catalyst degradation was negligible over the course of reaction.
    • 4TMAP) was assumed constant for each plot under steady-state conditions, i.e., catalyst degradation was negligible over the course of reaction.
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    • A detailed derivation of the rate law is given in the Supporting Information. While our 1st order approximation used in the treatment of kinetic data is not strictly mathematically correct (since dependences are really mixed-order), the treatment is sufficient to invalidate the possibility that the dependences are 1st order and to demonstrate the existence of a more complex kinetic profile.
    • A detailed derivation of the rate law is given in the Supporting Information. While our 1st order approximation used in the treatment of kinetic data is not strictly mathematically correct (since dependences are really mixed-order), the treatment is sufficient to invalidate the possibility that the dependences are 1st order and to demonstrate the existence of a more complex kinetic profile.
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    • Comparison of the thermodynamics of oxo transfer for the employed catalysts and/or the enzyme is not possible because the potentials for Compounds I and II are not available
    • Comparison of the thermodynamics of oxo transfer for the employed catalysts and/or the enzyme is not possible because the potentials for Compounds I and II are not available.


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