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Volumn , Issue 27, 2008, Pages 3546-3552

C-H activation on a diphosphine and hydrido-bridged diiridium complex: Generation and detection of an active IrII-IrII species [(Cp*Ir)2(μ-dmpm)(μ-H)]+

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; ORGANOMETALLICS;

EID: 46249083490     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b803626h     Document Type: Article
Times cited : (9)

References (55)
  • 41
    • 0034801447 scopus 로고    scopus 로고
    • 2, while the coordinated one is observed downfield by 1-2 ppm. Since the triflate ion in 8 was evidently uncoordinated, it is highly probable that the triflate ion in 7 would also be uncoordinated:
    • Z. Hou T. Koizumi A. Fujita H. Yamazaki Y. Wakatsuki J. Am. Chem. Soc. 2001 123 5812
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 5812
    • Hou, Z.1    Koizumi, T.2    Fujita, A.3    Yamazaki, H.4    Wakatsuki, Y.5
  • 46
    • 0001565235 scopus 로고
    • C-H activation of pyridine and cyclopentene selectively occurred at the 2-position of pyridine and the 1-position of cyclopentene. These results strongly suggest that the nitrogen atom and carbon-carbon double bond would pre-coordinate to the iridium center of the active species 7 at the first step of the activation
    • P. Diversi S. Iacoponi G. Ingrosso F. Laschi A. Lucherini C. Pinzino G. Uccello-Barretta P. Zanello Organometallics 1995 14 3275
    • (1995) Organometallics , vol.14 , pp. 3275
    • Diversi, P.1    Iacoponi, S.2    Ingrosso, G.3    Laschi, F.4    Lucherini, A.5    Pinzino, C.6    Uccello-Barretta, G.7    Zanello, P.8
  • 54
    • 0346669314 scopus 로고
    • A. J. C. Wilson, Kluwer Academic Publishers, Boston, pp. 200-206, Table 4.2.4.3 CrystalStructure3.8, crystal structure analysis package, Rigaku and Rigaku/Molecular Structure Corp., TX, USA, (2000-2006)
    • D. C. Creagh and J. H. Hubbell, in International Tables for X-Ray Crystallography, ed., A. J. C. Wilson, Kluwer Academic Publishers, Boston, 1992, vol. C, pp. 200-206, Table 4.2.4.3
    • (1992) International Tables for X-Ray Crystallography, Ed.
    • Creagh, D.C.1    Hubbell In, J.H.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.