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The intramolecular arene displacement has been extensively used to prepare a variety of tethered Ru (η6-arene) complexes since the following two papers8a, 8b were reported, but there had been no report that employs the protic amine group as an anchor when we initiated this research.8c Independently, a similar reaction was recently reported by Melchart et al.8d a) B. Therrien, T. R. Ward, M. Pilkington, C. Hoffmann, F. Gilardoni, J. Weber, Organometallics 1998, 17, 330
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Crystallographic data reported in this paper have been deposited with Cambridge Crystallographic Data Centre as supplementary publication Nos. CCDC-704734 (2d, 704735 (2g, 704736 (anti-5e, 704737 (syn-6e, 704738 (5c, and -704739 5f, Copies of the data can be obtained free of charge via
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Crystallographic data reported in this paper have been deposited with Cambridge Crystallographic Data Centre as supplementary publication Nos. CCDC-704734 (2d), -704735 (2g), -704736 (anti-5e), -704737 (syn-6e), -704738 (5c), and -704739 (5f). Copies of the data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html.
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Our method is complementary to that for the preparation of similar cationic complexes reported by Miyaki et al, 10a in which the introduction of the η6-arene ligand with protected 1-aminoalkyl-1, 4-cyclohexadienes precedes coordination of amine moiety, a Y. Miyaki, T. Onishi, H. Kurosawa, Inorg. Chim. Acta 2000, 300-302, 369. See also
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6-arene ligand with protected 1-aminoalkyl-1, 4-cyclohexadienes precedes coordination of amine moiety, a) Y. Miyaki, T. Onishi, H. Kurosawa, Inorg. Chim. Acta 2000, 300-302, 369. See also:
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