En route to {Mo2O2(μ2-O)2}2+ species: Isolation and structural characterization of a novel methoxide-bridged Mo(V) complex

Inorganic Chemistry Communications

Volumn 12, Issue 4, 2009, Pages 328-331

  Modec, Barbara ^a  

^a UNIVERSITY OF LJUBLJANA   (Slovenia)

Author keywords

Acetate; Crystal structure; Methoxide; Molybdenum(V) complexes; Polyoxometalates

Indexed keywords

EID: 62649090070     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.02.010     Document Type: Article

References (42)

1. Hill C.L. In: Wedd A.G. (Ed). Polyoxometalate: Reactivity in Comprehensive Coordination Chemistry II (2004), Elsevier, Oxford 679-759
2. In: Pope M.T., and Müller A. (Eds). Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (1994), Kluwer Academic Publishers, Dordrecht, The Netherlands
3. Some of the more recent studies are:. Collange E., Metteau L., Richard P., and Poli R. Polyhedron 23 (2004) 2605
4. Chen B., Jiang H., Zhu Y., Cammers A., and Selegue J.P. J. Am. Chem. Soc. 127 (2005) 4166
5. Yanagie H., Ogata A., Mitsui S., Hisa T., Yamase T., and Eriguchi M. Biomed. Pharmacother. 60 (2006) 349
6. Eda K., Iriki Y., Kawamura K., Ikuki T., and Hayashi M. J. Solid State Chem. 180 (2007) 3588
7. Keita B., Zhang G., Dolbecq A., Mialane P., Secheresse F., Miserque F., and Nadjo L. J. Phys. Chem. C 111 (2007) 8145
8. Liu F.-X., Marchal-Roch C., Dambournet D., Acker A., Marrot J., and Secheresse F. Eur. J. Inorg. Chem. (2008) 2191
9. Roy S., Bossers L.C.A.M., Meeldijk H.J.D., Kuipers B.W.M., and Kegel W.K. Langmuir 24 (2008) 666
10. McCarron III E.M., and Harlow R.L. J. Am. Chem. Soc. 105 (1983) 6179
11. See for example. Dolbecq A., Lisnard L., Mialane P., Marrot J., Benard M., Rohmer M.M., and Secheresse F. Inorg. Chem. 45 (2006) 5898
12. Mialane P., Dolbecq A., Lisnard L., Mallard A., Marrot J., and Secheresse F. Angew. Chem. Int. Ed. 41 (2002) 2398
13. Manos M.J., Woollins J.D., Slawin A.M.Z., and Kabanos T.A. Angew. Chem. Int. Ed. 41 (2002) 2801
14. Müller A., Kuhlmann C., Bögge H., Schmidtmann M., Baumann M., and Krickemeyer E. Eur. J. Inorg. Chem. (2001) 2271
15. Müller A., Dillinger S., Krickemeyer E., Bögge H., Plass W., Stammler A., and Haushalter R.C. Z. Naturforsch. 52b (1997) 1301
16. Khan M.I., Müller A., Dillinger S., Bögge H., Chen Q., and Zubieta J. Angew. Chem. Int. Ed. 32 (1993) 1780
17. Chae H.K., Klemperer W.G., and Marquart T.A. Coord. Chem. Rev. 128 (1993) 209
18. Modec B., and Brenčič J.V. J. Cluster Sci. 13 (2002) 279
19. Modec B., and Brenčič J.V. Eur. J. Inorg. Chem. (2005) 1698
20. sym(OCO)], 1351m, 1336m, 1250m, 1204m, 1197m, 1165m, 1051w, 1018s, 961vs, 947vs, 755w, 743vs, 728w, 704s, 678vs, 638w, 622w, 606s, 527m, 496m, 468m, 398w, 381m, 336w, 314vs, 290vs, 240m, 229m, 196m, 172m, 148w, 136m, 126w.
21. 2 = 0.0583 [all data].
22. Otwinowski Z., and Minor W. Methods Enzymol. 276 (1997) 307
23. G.M. Sheldrick, SHELXS-97 and SHELXL-97, University of Göttingen, 1997.
24. Farrugia L.J. J. Appl. Crystallogr. 30 (1997) 565
25. SHELXTL version 5.03, Siemens Analytical X-ray Instrument Division, Madison, WI, 1994.
26. CrystalMaker for Windows version 2.0, CrystalMaker Software Ltd., Oxfordshire, UK, 2007.
27. 2+-containing compounds range in length from 2.5 Å to 2.7 Å [5]. For more data see also:. Spivack B., and Dori Z. Coord. Chem. Rev. 17 (1975) 99
28. Modec B., Brenčič J.V., and Koller J. Eur. J. Inorg. Chem. (2004) 1611
29. Modec B. Inorg. Chim. Acta 361 (2008) 2863
30. Modec B., Brenčič J.V., Burkholder E.M., and Zubieta J. Dalton Trans. (2003) 4618
31. 2+ moieties held together with bridging alkoxide ions are considered as dioxide-bridged species.
32. Kamenar B., Penavić M., and Marković B. Croat. Chem. Acta 57 (1984) 637
33. Limberg C., Parsons S., Downs A.J., and Watkin D.J. J. Chem. Soc., Dalton Trans. (1994) 1169
34. Hunger M., Limberg C., and Zsolnai L. Polyhedron 17 (1998) 3935
35. 2+ species, are scarce and feature a planar bridging moiety. See for example:. Wieghardt K., Hahn M., Swiridoff W., and Weiss J. Angew. Chem. 95 (1983) 499
36. Limberg C., Downs A.J., Blake A.J., and Parsons S. Inorg. Chem. 35 (1996) 4439
37. Limberg C., Parsons S., and Downs A.J. J. Chem. Soc. Chem. Commun. (1994) 497
38. Blake A.J., Downs A.J., Limberg C., and Parsons S. J. Chem. Soc., Dalton Trans. (1995) 3263
39. Kamenar B., Korpar-Čolig B., Penavić M., and Cindrić M. Acta Cryst. C 46 (1990) 195
40. 2,6 (Py)) ppm. The content of solvent molecules of crystallization was estimated from the integrals of selected signals.
41. 4] [28].
42. Modec B., Brenčič J.V., and Zubieta J. J. Chem. Soc., Dalton Trans. (2002) 1500