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It is known in the organic literature that N-methylpyridinium salts result from a nucleophilic attack of pyridine on methyl halide formed from methanol and hydrogen halide. The halogenation of alcohols takes place only in a strongly acidic medium. It also proceeds more readily with tertiary and secondary alcohols, but not with methanol. The reaction medium in our case is not acidic, as it contains mostly pyridine. Further efforts to elucidate mechanisms governing the formation of N-alkylpyridinium cations are in progress.
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