Novel methanol-containing oxomolybdate(v) complexes: Synthesis and structural characterisation of intermediates in the formation of {Mo 2O4}2+ clusters from [MoOCl4(H 2O)]- and [MoOBr4]- precursors

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2005, Pages 1698-1709

  Modec, Barbara ^a   Brenčič, Jurij V ^a  

^a UNIVERSITY OF LJUBLJANA   (Slovenia)

Author keywords

Cluster compounds; Molybdenum; Polyoxometallates

Indexed keywords

INFRARED SPECTROSCOPY; MOLYBDENUM; SYNTHESIS (CHEMICAL); TEMPERATURE;

CLUSTER COMPOUNDS; COORDINATED WATER; DIMERIZATIONS; DINUCLEAR; POLYOXOMETALLATES; PYRIDINIUM CATIONS; PYRIDINIUM SALTS; STRUCTURAL CHARACTERIZATION; TRIFLUOROACETATES; WEAK BASIS;

METHANOL;

EID: 18844456070     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400829     Document Type: Article

References (69)

1. a) C. L. Hill (Guest editor), Chem. Rev. 1998, 98, 1-390;
2. b) Polyoxometallates: From Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer Academic Publishers, Dordrecht, 1994 and references cited therein.
3. H. K. Chae, W. G. Klemperer, T. A. Marquart, Coord. Chem. Rev. 1993, 128, 209-224.
4. E. I. Stiefel, Prog. Inorg. Chem. 1977, 22, 1-223.
5. H. K. Chae, J. Y. Kim, C. Hwang, B. W. Lee, Chem. Lett. 2002, 650-651.
6. A. Johansson, M. Roman, G. A. Seisenbaeva, L. Kloo, Z. Szabo, V. G. Kessler, J. Chem. Soc., Dalton Trans. 2000, 387-394.
7. M. J. Manos, J. D. Woollins, A. M. Z. Slawin, T. A. Kabanos, Angew. Chem. Int. Ed. 2002, 41, 2801-2805.
8. C. du Peloux, P. Mialane, A. Dolbecq, J. Marrot, F. Secheresse, Angew. Chem. ht. Ed. 2002, 41, 2808-2810.
9. E. Dumas, C. Sassoye, K. D. Smith, S. C. Sevov, Inorg. Chem. 2002, 41, 4029-4032.
10. C. du Peloux, A. Dolbecq, P. Mialane, J. Marrot, F. Secheresse, Dalton Trans. 2004, 1259-1263.
11. A. Müller, C. Kuhlmann, H. Bögge, M. Schmidtmann, M. Baumann, E. Krickemeyer, Eur. J. Inorg. Chem. 2001, 2271-2277.
12. M.-M. Rohmer, M. Benard, Dalton Trans. 2003, 3587-3590.
13. For a more detailed account see: a) B. Modec, J. V. Brenčič, J. Zubieta, J. Chem. Soc., Dalton Trans. 2002, 1500-1507;
14. b) B. Modec, J. V. Brenčič, J. Cluster Sci. 2002, 13, 279-302;
15. c) B. Modec, J.V. Brenčič, R. C. Finn, R. S. Rarig, J. Zubieta, Inorg. Chim. Acta 2001, 322, 113-119;
16. d) B. Modec, J. V. Brenčič, L. Golič, Polyhedron 2000, 19, 1219-1225;
17. e) B. Modec, J. V. Brenčič, L. Golič, L. M. Daniels, Polyhedron 2000, 19, 1407-1414;
18. f) B. Modec, J. V. Brenčič, L. Golič, G. Giester, Inorg. Chim. Acta 2000, 307, 32-40;
19. g) B. Modec, J. V. Brenčič, I. Leban, Inorg. Chem. Commun. 1998, I, 161-163.
20. E. A. Allen, B. J. Brisdon, D. A. Edwards, G. W. A. Fowles, R. G. Williams, J. Chem. Soc. 1963, 4649-4657.
21. 2- = squarate anion) [B. Modec, J. V. Brenčič, E. M. Burkholder, J. Zubieta, Dalton Trans. 2003, 4618-4625];
22. 6- [B. Modec, J. V. Brenčič, J. Koller, Eur. J. Inorg. Chem. 2004, 1611-1620];
23. 2] [NP = 2-pyridyl(diisopropylphosphanyl)-methane] [H.-F. Lang, P. E. Fanwick, R. A. Walton, Inorg. Chim. Acta 2002, 328, 232-236];
24. 2- [tpen = N,N,N′, N′-tetrakis(2-pyridylmethyl)ethylenediamine] [R. Hazama, K. Umakoshi, A. Ichimura, S. Ikari, Y. Sasaki, T. Ito, Bull. Chem. Soc. Jpn. 1995, 68, 456-468].
25. G. S. Kim, D. A. Keszler, C. W. DeKock, Inorg. Chem. 1991, 30, 574-577.
26. A. Bino, F. A. Cotton, Inorg. Chem. 1979, 18, 2710-2713.
27. a) A. Bino, F. A. Cotton, J. Am. Chem. Soc. 1979, 101, 4150-4154;
28. b) C. J. Kepert, M. Kurmoo, M. R. Truter, P. Day, J. Chem. Soc., Dalton Trans. 1997, 607-613;
29. c) C. D. Garner, L. H. Hill, F. E. Mabbs, D. L. McFadden, A. T. McPhail, J. Chem. Soc., Dalton Trans. 1977, 1202-1207;
30. d) S. J. Hibble, S. G. Eversfield, A. M. Chippindale, Acta Crystallogr., Sect. E 2002, 55, m366-m368 and references cited therein.
31. L. Lisnard, P. Mialane, A. Dolbecq, J. Marrot, F. Secheresse, Inorg. Chem. Commun. 2003, 6, 503-505.
32. Their preparations require strictly anhydrous conditions. See for example: a) S. Chitsaz, E. Iravani, J. Pauls, B. Neumuller, Z. Naturforsch., Teil B 2001, 56, 759-764;
33. b) M. G. B. Drew, J. D. Wilkins, J. Chem. Soc., Dalton Trans. 1975, 1984-1989;
34. c) D. Fenske, K. Jansen, K. Dehnicke, Z. Naturforsch., Teil B 1986, 41, 523-526;
35. d) J. Beck, M. Hengstmann, Z. Anorg. Allg. Chem. 1998, 624, 1943-1950.
36. O. Piovesana, C. Furlani, Inorg. Nucl. Chem. Lett. 1967, 3, 535-538.
37. T. Glowiak, M. Sabat, J. Cryst. Mol. Struct. 1975, 5, 247-256.
38. M. I. Khan, Q. Chen, J. Zubieta, Inorg. Chim. Acta 1995, 235, 135-145.
39. K. J. Moynihan, P. M. Boorman, J. M. Ball, V. D. Patel, K. A. Kerr, Acta Crystallogr., Sect. B 1982, 38, 2258-2261.
40. C. Limberg, A. J. Downs, A. J. Blake, S. Parsons, Inorg. Chem. 1982, 35, 4439-4448.
41. C. Limberg, R. Boese, B. Schiemenz, J. Chem. Soc., Dalton Trans. 1997, 1633-1637.
42. M. Cindrić, V. Vrdoljak, N. Strukan, A. Brbot-Šaranovič, P. Novak, B. Kamenar, Inorg. Chim. Acta 2004, 357, 931-938.
43. S. Lincoln, S. A. Koch, Inorg. Chem. 1986, 25, 1594-1602.
44. C. Limberg, S. Parsons, A. J. Downs, D. J. Watkin, J. Chem. Soc, Dalton Trans. 1994, 1169-1174.
45. A. J. Blake, A. J. Downs, C. Limberg, S. Parsons, J. Chem. Soc., Dalton Trans. 1995, 3263-3268.
46. F. H. Allen, O. Kennard, R. Taylor, Acc. Chem. Res. 1983, 16, 146-153.
47. C. G. Barraclough, J. Lewis, R. S. Nyholm, J. Chem. Soc. 1959, 3552-3555.
48. N. B. Colthup, L. H. Daly, S. E. Wiberley, Introduction to Infrared and Roman Spectroscopy, Academic Press, 1964, pp. 273-274 and 189-190.
49. a) R. G. James, W. Wardlaw, J. Chem. Soc. 1927, 2145-2156;
50. b) C. D. Garner, J. M. Charnock, in Comprehensive Coordination Chemistry (Eds.: G. Wilkinson, R. D. Gillard, I A. McCleverty), 1987, chapter 36.4., pp. 1329-1374.
51. P. M. Boorman, C. D. Garner, F. E. Mabbs, J. Chem. Soc., Dalton Trans. 1975, 1299-1306.
52. A. J. Blake, S. Parsons, A. J. Downs, C. Limberg, Acta Crystallogr., Sect. C1995, 51, 571-573.
53. P. Klinzing, A. El-Kholi, U. Müller, K. Dehnicke, K. Findeisen, Z. Anorg. Allg. Chem. 1989, 569, 83-90.
54. R. Herbst-Inner, E. Egert, Acta Crystallogr., Sect. C1992, 48, 1843-1844.
55. J. Beck, M. A. Pell, J. Richter, J. A. Ibers, Z. Anorg, Allg. Chem. 1996, 622, 413-478.
56. S. Rabe, U. Müller, Z. Anorg. Allg. Chem. 1999, 625, 842-844.
57. J. G. Scane, Acta Crystallogr. 1967, 23, 85-89.
58. 4]: a = b = 8.40 Å, c = 4.00 Å, α = β= γ = 90°, tetragonal (J. V. Brenčič, I. Leban, unpublished results).
59. 2n- chains and no pyridinium cations.
60. a) H. Funk, F. Schmeil, H. Scholz, Z. Anorg. Allg. Chem. 1961, 310, 86-89;
61. b) H. Funk, M. Hesselbarth, F. Schmeil, Z. Anorg. Allg. Chem. 1962, 318, 318-322.
62. N. T. Denisov, N. I. Shuvalova, V. F. Shuvalov, Zh. Fiz. Khim. 1971, 45, 2796-2799.
63. R. G. Cavell, J. W. Quail, Inorg. Chem. 1983, 22, 2597-2599.
64. a) G. R. Hanson, A. A. Brunette, A. C. McDonell, K. S. Murray, A. G. Wedd, J. Am. Chem. Soc. 1981, 103, 1953-1959;
65. b) H. K. Saha, M. C. Halder, J. Inorg. Nucl. Chem. 1971, 33, 705-711.
66. Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307-326.
67. G. M. Sheldrick, SHELXS-97 and SHELXL-97, University of Gottingen, 1997.
68. SHELXTL Version 5.03. Software Package for Crystal Structure Determination, Siemens Analytical X-ray Instrument Division, Madison, WI, 1994.
69. A. L. Spek, J. Appl. Crystallogr. 2003, 36, 7-13.