From small {Mo2O4}2+ aggregates to infinite solids

Journal of Cluster Science

Volumn 13, Issue 3, 2002, Pages 279-302

  Modec, Barbara ^a   Brenčič, Jurij V ^a  

^a UNIVERSITY OF LJUBLJANA   (Slovenia)

Author keywords

Crystal structure; Oxomolybdenum(V) clusters; Polymeric oxomolybdenum(V) compounds; Mo2O4 2+ unit

Indexed keywords

ALCOHOL DERIVATIVE; HALIDE; MOLYBDENUM; MOLYBDIC ACID; OXYGEN; PYRIDINE DERIVATIVE;

ATOM; BINDING AFFINITY; CHEMICAL BOND; CHEMICAL STRUCTURE; CONFERENCE PAPER; DIMERIZATION; SOLID;

EID: 0142105924     PISSN: 10407278     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1020590630189     Document Type: Conference Paper

References (89)

1. (a) M. I. Khan and J. Zubieta (1995). Prog. Inorg. Chem. 43, 1.
2. (b) H. K. Chae, W. G. Klemperer, and T. A. Marquart (1993). Coord. Chem. Rev. 128, 209.
3. (c) E. I. Stiefel (1977). Prog. Inorg. Chem. 22, 1.
4. (d) B. Spivack and Z. Dori (1975). Coord. Chem. Rev. 17, 99.
5. F. A. Cotton and S. M. Morehouse (1965). Inorg. Chem. 4, 1377.
6. J. A. Beaver and M. G. B. Drew (1973). J. C. S. Dalton 1376.
7. M. H. Chisholm, J. C. Huffman, C. C. Kirkpatrick, J. Leonelli, and K. Folting (1981). J. Am. Chem. Soc. 103, 6093.
8. M. F. Belicchi, G. G. Fava, and C. Pelizzi (1983). J. Chem. Soc. Dalton Trans. 65.
9. D. J. Darensbourg, R. L. Gray, and T. Delord (1985). Inorg. Chim. Acta 98, L39.
10. C. du Peloux, A. Dolbecq, P. Mialane, J. Marrot, E. Riviere, and F. Secheresse (2001). Angew. Chem. Int. Ed. 40, 2455.
11. A. Müller, C. Kuhlmann, H. Bögge, M. Schmidtmann, M. Baumann, and E. Krickemeyer (2001). Eur. J. Inorg. Chem. 2271.
12. For the review, see, R. C. Haushalter and L. A. Mundi (1992). Chem. Mater. 4, 31.
13. (a) M. I. Khan and J. Zubieta (1992). J. Am. Chem. Soc. 114, 10058.
14. (b) M. I. Khan, Q. Chen, J. Salta, C. J. O'Connor, and J. Zubieta (1996). Inorg. Chem. 35, 1880.
15. (a) C. Hill (Guest editor) (1998). Chem. Rev. 98, 1.
16. (b) M. T. Pope and A. Müller (eds), Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Kluwer Academic, Dordrecht, 1994).
17. M. H. Chisholm, K. Folting, J. C. Huffman, and C. C. Kirkpatrick (1984). Inorg. Chem. 23, 1021.
18. S. Liu, X. Sun, and J. Zubieta (1989). J. Am. Chem. Soc. 111, 5944.
19. M. K. Ehlert, S. J. Rettig, A. Storr, R. C. Thompson, and J. Trotter (1993). Inorg. Chem. 32, 5176.
20. A. Müller, J. Meyer, E. Krickemeyer, C. Beugholt, H. Bögge, F. Peters, M. Schmidtmann, P. Kögerler, and M. J. Koop (1998). Chem. Eur. J. 4, 1000.
21. (a) B. Modec, J. V. Brenčič, and I. Leban (1998). Inorg. Chem. Commun. 1, 161.
22. (b) B. Modec, J. V. Brenčič, R. Rotar, L. Golič, and K. Prout (1998). Acta Crystallorg. C 54, 1573.
23. (c) B. Modec, J. V. Brenčič, and L. Golič (2000). Polyhedron 19, 1219.
24. (d) B. Modec, J. V. Brenčič, L. Golič, and L. M. Daniels (2000). Polyhedron 19, 1407.
25. (e) B. Modec, J. V. Brenčič, L. Golič, and G. Giester (2000). Inorg. Chim. Acta 307, 32.
26. (f) B. Modec, J. V. Brenčič, and G. Giester (2001). Acta Crystallogr. C 57, 246.
27. (g) B. Modec, J. V. Brenčič, J. Zubieta, and P. J. Hagrman (2001). Inorg. Chem. Commun. 4, 537.
28. (h) B. Modec, J. V. Brenčič, R. C. Finn, R. S. Rarig and J. Zubieta (2001). Inorg. Chim. Acta 322, 113.
29. (i) B. Modec, J. V. Brenčič, and J. Zubieta (2002). J. Chem. Soc., Dalton Trans. 1500.
30. B. Modec, J. V. Brenčič, and J. Zubieta. Unpublished results.
31. J. Mizutani, H. Imoto, and T. Saito (1997). Acta Crystallogr. C53, 47.
32. J. Beck, W. Hiller, E. Schweda, and J. Strähle (1984). Z. Naturforsch. 39b, 1110.
33. 2+ containing oligomers.
34. 2+ containing oligomers.
35. 2+ containing oligomers.
36. 4] where a cyclopentadienyl ring is coordinated to each molybdenum atom [C. Couldwell and K. Prout (1978). Acta Crystallogr. B34, 933].
37. 2] (NP=2-pyridyl(diisopropylphosphino)methane) [H.-F. Lang, P. E. Fanwick, and R. A. Walton (2002). Inorg. Chim. Acta 328, 232].
38. 2] (NP=2-pyridyl(diisopropylphosphino)methane) [H.-F. Lang, P. E. Fanwick, and R. A. Walton (2002). Inorg. Chim. Acta 328, 232].
39. 2] (NP=2-pyridyl(diisopropylphosphino)methane) [H.-F. Lang, P. E. Fanwick, and R. A. Walton (2002). Inorg. Chim. Acta 328, 232].
40. 2] (NP=2-pyridyl(diisopropylphosphino)methane) [H.-F. Lang, P. E. Fanwick, and R. A. Walton (2002). Inorg. Chim. Acta 328, 232].
41. 2] (NP=2-pyridyl(diisopropylphosphino)methane) [H.-F. Lang, P. E. Fanwick, and R. A. Walton (2002). Inorg. Chim. Acta 328, 232].
42. 2] (NP=2-pyridyl(diisopropylphosphino)methane) [H.-F. Lang, P. E. Fanwick, and R. A. Walton (2002). Inorg. Chim. Acta 328, 232].
43. H. Kang, S. Liu, S. N. Shaikh, T. Nicholson, and J. Zubieta (1989). Inorg. Chem. 28, 920.
44. M. H. Chisholm (1983). Polyhedron 2, 681.
45. (a) S. A. Koch and S. Lincoln (1982). Inorg. Chem. 21, 2904.
46. (b) S. Lincoln and S. A. Koch (1986). Inorg. Chem. 25, 1594.
47. 2] [Q. Chen, S. Liu, and J. Zubieta (1989). Inorg. Chim. Acta 164, 115] which possess the same basic core to whose periphery molybdate(VI) or squarate anions are attached in monodentate and bidentate binding modes, respectively.
48. 2] [Q. Chen, S. Liu, and J. Zubieta (1989). Inorg. Chim. Acta 164, 115] which possess the same basic core to whose periphery molybdate(VI) or squarate anions are attached in monodentate and bidentate binding modes, respectively.
49. 2] [Q. He and E. Wang (2000). Inorg. Chim. Acta 298, 235].
50. 2] [Q. He and E. Wang (2000). Inorg. Chim. Acta 298, 235].
51. 2] [Q. He and E. Wang (2000). Inorg. Chim. Acta 298, 235].
52. 4] [C. Limberg, M Büchner, K. Heinze, and O. Walter (1997). Inorg Chem. 36, 872].
53. 4] [C. Limberg, M Büchner, K. Heinze, and O. Walter (1997). Inorg Chem. 36, 872].
54. M. Cano, J. A. Campo, J. V. Heras, E. Pinilla, and A. Monge (1996). Polyhedron 15, 1705
55. C.-L. Lee, P.-Y. Yang, C.-W. Su, J.-D. Chen, L.-S. Liou, and J. C. Wang (2001). Inorg. Chim. Acta 314, 147.
56. 2+ chains [A. Johansson, M. Roman, G. A. Seisenbaeva, L. Kloo, Z. Szabo, and V. G. Kessler (2000). J. Chem. Soc., Dalton Trans. 387].
57. R. Mattes and K. Mühlsiepen (1980). Z. Naturforsch. 35b, 265.
58. W. Schirmer, U. Flörke, and H.-J. Haupt (1989). Z. Anorg. Allg. Chem. 574, 239.
59. G. S. Kim, D. A. Keszler, and C. W. DeKock (1991). Inorg. Chem. 30, 574.
60. B. Kamenar, B. Korpar-Čolig, and M. Penavič (1981). J. Chem. Soc., Dalton Trans. 311.
61. L. A. Mundi, K. G. Strohmaier, D. P. Goshorn, and R. C. Haushalter (1990). J. Am. Chem. Soc. 112, 8182.
62. C. Limberg, S. Parsons, and A. J. Downs (1994). J. Chem. Soc., Chem. Commun. 497.
63. M. Cindrič, G. Pavlovič, V. Vrdoljak, and B. Kamenar (2000). Polyhedron 19, 1471.
64. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
65. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
66. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
67. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
68. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
69. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
70. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
71. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
72. 2+ cations, respectively. In all cases the "dimers" are polymerized via additional metal cations into infinite chains, sheets or three-dimensional frameworks.
73. M. J. Manos, A. D. Keramidas, J. D. Woollins, A. M. Z. Slawin, and T. A. Kabanos (2001). J. Chem. Soc., Dalton Trans. 3419.
74. A. J. Blake, A. J. Downs, C. Limberg, and S. Parsons (1995). J. Chem. Soc., Dalton Trans. 3263.
75. (a) Q. Chen, S. Liu, and J. Zubieta (1988). Angew. Chem. Int. Ed. Engl. 27, 1724.
76. (b) Q. Chen, S. Liu, and J. Zubieta (1989). Inorg. Chem. 28, 4433.
77. 2n] have trapped into their central cavities anions such as oxalate (n=4) [A. Dolbecq, B. Salignac, E. Cadot, and F. Secheresse (1998). Bull. Pol. Acad. Sci. 46, 237], molybdate(VI) (n=4) [A. Dolbecq, E. Cadot, and F. Secheresse (1998). Chem. Commun. 2293], phosphate (n = 5 or 6) [E. Cadot, B. Salignac, T. Loiseau, A. Dolbecq, and F. Secheresse (1999). Chem. Eur. J. 5, 3390], glutarate (n=5) [B. Salignac, S. Riedel, A. Dolbecq, F. Secheresse, and E. Cadot (2000). J. Am. Chem. Soc. 122, 10381] and 1,3,5-benzenetri-carboxylate (n=6) [A. Dolbecq, E. Cadot, and F. Secheresse (2000). C. R. Acad. Sci. Ser. IIc 3, 193].
78. 2n] have trapped into their central cavities anions such as oxalate (n=4) [A. Dolbecq, B. Salignac, E. Cadot, and F. Secheresse (1998). Bull. Pol. Acad. Sci. 46, 237], molybdate(VI) (n=4) [A. Dolbecq, E. Cadot, and F. Secheresse (1998). Chem. Commun. 2293], phosphate (n = 5 or 6) [E. Cadot, B. Salignac, T. Loiseau, A. Dolbecq, and F. Secheresse (1999). Chem. Eur. J. 5, 3390], glutarate (n=5) [B. Salignac, S. Riedel, A. Dolbecq, F. Secheresse, and E. Cadot (2000). J. Am. Chem. Soc. 122, 10381] and 1,3,5-benzenetri-carboxylate (n=6) [A. Dolbecq, E. Cadot, and F. Secheresse (2000). C. R. Acad. Sci. Ser. IIc 3, 193].
79. 2n] have trapped into their central cavities anions such as oxalate (n=4) [A. Dolbecq, B. Salignac, E. Cadot, and F. Secheresse (1998). Bull. Pol. Acad. Sci. 46, 237], molybdate(VI) (n=4) [A. Dolbecq, E. Cadot, and F. Secheresse (1998). Chem. Commun. 2293], phosphate (n = 5 or 6) [E. Cadot, B. Salignac, T. Loiseau, A. Dolbecq, and F. Secheresse (1999). Chem. Eur. J. 5, 3390], glutarate (n=5) [B. Salignac, S. Riedel, A. Dolbecq, F. Secheresse, and E. Cadot (2000). J. Am. Chem. Soc. 122, 10381] and 1,3,5-benzenetri-carboxylate (n=6) [A. Dolbecq, E. Cadot, and F. Secheresse (2000). C. R. Acad. Sci. Ser. IIc 3, 193].
80. 2n] have trapped into their central cavities anions such as oxalate (n=4) [A. Dolbecq, B. Salignac, E. Cadot, and F. Secheresse (1998). Bull. Pol. Acad. Sci. 46, 237], molybdate(VI) (n=4) [A. Dolbecq, E. Cadot, and F. Secheresse (1998). Chem. Commun. 2293], phosphate (n = 5 or 6) [E. Cadot, B. Salignac, T. Loiseau, A. Dolbecq, and F. Secheresse (1999). Chem. Eur. J. 5, 3390], glutarate (n=5) [B. Salignac, S. Riedel, A. Dolbecq, F. Secheresse, and E. Cadot (2000). J. Am. Chem. Soc. 122, 10381] and 1,3,5-benzenetri-carboxylate (n=6) [A. Dolbecq, E. Cadot, and F. Secheresse (2000). C. R. Acad. Sci. Ser. IIc 3, 193].
81. 2n] have trapped into their central cavities anions such as oxalate (n=4) [A. Dolbecq, B. Salignac, E. Cadot, and F. Secheresse (1998). Bull. Pol. Acad. Sci. 46, 237], molybdate(VI) (n=4) [A. Dolbecq, E. Cadot, and F. Secheresse (1998). Chem. Commun. 2293], phosphate (n = 5 or 6) [E. Cadot, B. Salignac, T. Loiseau, A. Dolbecq, and F. Secheresse (1999). Chem. Eur. J. 5, 3390], glutarate (n=5) [B. Salignac, S. Riedel, A. Dolbecq, F. Secheresse, and E. Cadot (2000). J. Am. Chem. Soc. 122, 10381] and 1,3,5-benzenetri-carboxylate (n=6) [A. Dolbecq, E. Cadot, and F. Secheresse (2000). C. R. Acad. Sci. Ser. IIc 3, 193].
82. H. K. Chae, W. G. Klemperer, D. E. Paez Loyo, V. W. Day, and T. A. Eberspacher (1999). Inorg. Chem. 31, 3187.
83. M. I. Khan, A. Müller, S. Dillinger, H. Bögge, Q. Chen, and J. Zubieta (1993). Angew. Chem. Int. Ed. Engl. 32, 1780.
84. J.-H. Chou, J. A. Hanko, and M. G. Kanatzidis (1997). Inorg. Chem 36, 4.
85. 2+ units. The dinuclear units are connected with the phosphates in such a way to form a layered structure [L. A. Mundi and R. C. Haushalter (1990). Inorg. Chem. 29, 2879].
86. 2O [R. C. Haushalter, K. G. Strohmaier, and F. W. Lai (1989). Science 246, 1289] results in a microporous material with sorption properties.
87. 2O [R. C. Haushalter, K. G. Strohmaier, and F. W. Lai (1989). Science 246, 1289] results in a microporous material with sorption properties.
88. 2O [R. C. Haushalter, K. G. Strohmaier, and F. W. Lai (1989). Science 246, 1289] results in a microporous material with sorption properties.
89. 2O [R. C. Haushalter, K. G. Strohmaier, and F. W. Lai (1989). Science 246, 1289] results in a microporous material with sorption properties.