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62349094845
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2 as the mobile phase to afford the product as a colorless crystalline solid (431 mg, 80%).
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2 as the mobile phase to afford the product as a colorless crystalline solid (431 mg, 80%).
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49149146669
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Deprotection of TBS ethers by the related trityl tetrafluoroborate has been reported with the anion acting as a fluoride ion source. See: Metcalf, B. W, Burkhart, J. P, Jund, K. Tetrahedron Lett. 1980, 21, 35
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Deprotection of TBS ethers by the related trityl tetrafluoroborate has been reported with the anion acting as a fluoride ion source. See: Metcalf, B. W.; Burkhart, J. P.; Jund, K. Tetrahedron Lett. 1980, 21, 35.
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62349114790
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2 as the mobile phase to afford the product as a creamy white solid (430 mg, 76%).
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2 as the mobile phase to afford the product as a creamy white solid (430 mg, 76%).
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31
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62349109837
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Data for Selected Compounds 7-Acetoxy-3-p-acetoxyphenyl-2-cyano-2H-1-benzopyran (7b) White solid; mp 156-158°C. 1H NMR (500 MHz, CDCl3, δ, 7.49 (d, J, 8.7 Hz, 2 H, H-2′/6′, 7.23 (d, J, 8.0 Hz, 1 H, H-5, 7.18 (d, J, 8.6 Hz, 2 H, H-3′/5′, 6.97 (s, 1 H, H4, 6.85 (dd, J, 2.5, 8.1 Hz, 1 H, H-6, 6.84 (s, 1 H, H-8, 6.01 (s, 1 H, H-2, 2.32 (s, 3 H, CH3, 2.30 (s, 3 H, CH3, 13C NMR (75 MHz, CDCl3, δ, 169.1 (C=O, 168.9 (C=O, 151.9 (C7, 151.1 (C8a, 150.3 (C4′, 131.9 (C3, 128.3 (C5, 126.2 (C2′, 125.9 (C1′, 122.4 (C3′, 122.3 (C4, 119.1 (C4a, 117.0 (C6, 110.5 (C8, 64.3 (C2, 21.1 (CH3, MS (CI, m/z, 323 (100, MH, HCN, Anal. Calcd, ) for C 20H15NO5: C, 68.76; H, 4.33; N, 4.01. Found: C, 69.20;
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10: C, 69.28; H, 4.60. Found: C, 69.27; H, 4.62.
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