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(d) For references to synthetic approaches to discodermolide, see ref. 6b.
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more..
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42
-
-
62249147102
-
-
+.
-
+.
-
-
-
-
43
-
-
62249212935
-
-
Spectroscopic Data for Compound 10 [α]D 25 +5.5 (c 1.05, CHCl3, 1H NMR (300 MHz, CDCl3, δ, 6.23 (d, J, 9.8 Hz, 1 H, 4.28 (dd, J, 6.8, 4.1 Hz, 1 H, 2.52-2.67 (m, 2 H, 1.47 (s, 9 H, 1.13 (d, J, 7.2 Hz, 3 H, 1.10 (s, 18 H, 1.04-1.13 (s, 3 H, 1.07 (d, J, 7.0 Hz, 3 H, 13C NMR (75 MHz, CDCl3, δ, 172.7, 140.8, 88.8, 80.7, 75.1, 46.9, 42.0, 28.2, 18.2, 15.5, 13.1, 9.4. IR (film, 1733, 1460, 1255, 882 cm-1. MS DCI/NH3, m/z, 529 [M, H, Anal. Calcd for C21H40Br 2O3Si: C, 47.73; H, 7.63. Found: C, 47.81; H, 7.51
-
3Si: C, 47.73; H, 7.63. Found: C, 47.81; H, 7.51.
-
-
-
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44
-
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30344479171
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49
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62249143737
-
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+.
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+.
-
-
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|