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Volumn 48, Issue 2, 2009, Pages 417-419

Targeted synthesis of a prototype MOF based on Zn4(O)(O 2C)6 units and a nonlinear dicarboxylate ligand

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EID: 61849134436     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801906e     Document Type: Article
Times cited : (66)

References (35)
  • 1
    • 61849137382 scopus 로고    scopus 로고
    • A survey using SciFinder shows that 782 articles have been published by journals or reviews in English with the keyword coordination polymer somewhere in the title or abstract in 2007. Such articles published in 1997 are just 52.
    • A survey using SciFinder shows that 782 articles have been published by journals or reviews in English with the keyword "coordination polymer" somewhere in the title or abstract in 2007. Such articles published in 1997 are just 52.
  • 18
    • 61849111875 scopus 로고    scopus 로고
    • Synthesis of [Zn4(O)(mip)3(DMF)2]-3(DMF, H2O, To a DMF (15.0 mL) solution containing Zn(NO 3)2 6H2O (0.423 g, 1.42 mmol) and H 2mip (0.191 g, 1.06 mmol) was added NEt3 (0.148 mL, 1.03 mmol, The initially formed white precipitate was dissolved after stirring for 1 h at room temperature. The solution was then heated to 100 °C for 2 days to produce large, polyhedral crystals (0.304 g, 72, The yields vary between 60 and 80% depending on the reaction scale. The elemental analysis was carried out for an evacuated sample. Anal. Calcd for [Zn4(O)(C9H 6O4)3] 2H2O: C, 38.24; H, 2.61; N, 0.00. Found:C, 38.17; H, 2.97; N, 0.00
    • 2O: C, 38.24; H, 2.61; N, 0.00. Found:C, 38.17; H, 2.97; N, 0.00.
  • 19
    • 61849185972 scopus 로고    scopus 로고
    • Crystal data for [Zn4(O)(mip)3(DMF) 2]-3DMF-H2O: formula C42H55N 5O19Zn4, M, 1195.39, orthorhombic, space group P2l2l2l (No. 19, α, 16.215(3) Å, b, 17.174(3) Å, c, 18.104(4) Å, V, 5042 (2) Å3, Z, 4, T, 173 K, pcalcd, 1.575 g/cm3, F(000, 2456, μ(Mo Kα, 1.958 mm-1, 10 253 independent reflections, 9713 observed [I > 2σ(I, Rl, 0.0596, wR2, 0.1642 all data
    • -1, 10 253 independent reflections, 9713 observed [I > 2σ(I)]; Rl = 0.0596, wR2 = 0.1642 (all data).
  • 21
    • 61849176114 scopus 로고    scopus 로고
    • 2 are the two best known topologies for uninodal six-connected nets.
    • 2 are the two best known topologies for uninodal six-connected nets.
  • 25
    • 61849149519 scopus 로고    scopus 로고
    • Connolly, M. L. J. Appl. Crystallogr. 1983, 16, 548-558. The calculation was carried out using Materials Studio v4.3 (Accelrys Software, Inc., 2008)
    • Connolly, M. L. J. Appl. Crystallogr. 1983, 16, 548-558. The calculation was carried out using Materials Studio v4.3 (Accelrys Software, Inc., 2008)
  • 34
    • 53249136449 scopus 로고    scopus 로고
    • 2 uptake known to date is 3.05 wt % at 77 K and 1 bar. For details, see: Wang, X.-S.; Ma, S.; Forster, P. M.; Yuan, D.; Eckert, J.; López, J. J.; Murphy, B. J.; Parise, J. B.; Zhou, H.-C. Angew. Chem., Int. Ed. 2008, 47, 7263-7266.
    • 2 uptake known to date is 3.05 wt % at 77 K and 1 bar. For details, see: Wang, X.-S.; Ma, S.; Forster, P. M.; Yuan, D.; Eckert, J.; López, J. J.; Murphy, B. J.; Parise, J. B.; Zhou, H.-C. Angew. Chem., Int. Ed. 2008, 47, 7263-7266.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.