Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal-organic frameworks

Journal of Materials Chemistry

Volumn 17, Issue 30, 2007, Pages 3197-3204

  Furukawa, Hiroyasu ^a   Miller, Michael A ^b,c   Yaghi, Omar M ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b SOUTHWEST RESEARCH INSTITUTE   (United States)

^c UNIVERSITY OF TEXAS AT SAN ANTONIO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION ISOTHERMS; BENCHMARKING; ERROR ANALYSIS; MOLECULAR STRUCTURE; SAMPLING;

HYDROGEN ISOTHERMS; METAL-ORGANIC FRAMEWORKS (MOF); STORAGE CAPACITIES;

HYDROGEN STORAGE;

EID: 34547516632     PISSN: 09599428     EISSN: 13645501     Source Type: Journal    
DOI: 10.1039/b703608f     Document Type: Article

References (47)

1. N. L. Rosi J. Eckert M. Eddaoudi D. T. Vodak J. Kim M. O'Keeffe O. M. Yaghi Science 2003 300 1127
2. J. L. C. Rowsell J. Eckert O. M. Yaghi J. Am. Chem. Soc. 2005 127 14904
3. J. L. C. Rowsell A. R. Millward K. S. Park O. M. Yaghi J. Am. Chem. Soc. 2004 126 5666
4. J. L. C. Rowsell O. M. Yaghi J. Am. Chem. Soc. 2006 128 1304
5. A. G. Wong-Foy A. J. Matzger O. M. Yaghi J. Am. Chem. Soc. 2006 128 3494
6. M. Dinc A. Dailly Y. Liu C. M. Brown D. A. Neumann J. R. Long J. Am. Chem. Soc. 2006 128 16876
7. D. N. Dybtsev H. Chun S. H. Yoon D. Kim K. Kim J. Am. Chem. Soc. 2004 126 32
8. S. S. Kaye J. R. Long J. Am. Chem. Soc. 2005 127 6506
9. X. Lin J. Jia X. Zhao K. M. Thomas A. J. Blake G. S. Walker N. R. Champness P. Hubberstey M. Schröder Angew. Chem., Int. Ed. 2006 45 7358
10. L. Pan M. B. Sander X. Huang J. Li M. Smith E. Bittner B. Bockrath J. K. Johnson J. Am. Chem. Soc. 2004 126 1308
11. B. Kesanli Y. Cui M. R. Smith E. W. Bittner B. C. Bockrath W. Lin Angew. Chem., Int. Ed. 2005 44 72
12. B. Chen N. W. Ockwig A. R. Millward D. S. Contreras O. M. Yaghi Angew. Chem., Int. Ed. 2005 44 4745
13. H. Kabbour T. F. Baumann J. H. Satcher, Jr. A. Saulnier C. C. Ahn Chem. Mater. 2006 18 6085
14. P. M. Forster J. Eckert B. D. Heiken J. B. Parise J. W. Yoon S. H. Jhung J.-S. Chang A. K. Cheetham J. Am. Chem. Soc. 2006 128 16846
15. D. Sun S. Ma Y. Ke D. J. Collins H.-C. Zhou J. Am. Chem. Soc. 2006 128 3896
16. S. Ma D. Sun M. Ambrogio J. A. Fillinger S. Parkin H.-C. Zhou J. Am. Chem. Soc. 2007 129 1858
17. M. Latroche S. Surblé C. Serre C. Mellot-Draznieks P. L. Llewellyn J.-H. Lee J.-S. Chang S. H. Jhung G. Férey Angew. Chem., Int. Ed. 2006 45 8227
18. A. Dailly J. J. Vajo C. C. Ahn J. Phys. Chem. B 2006 110 1099
19. J. Jia X. Lin C. Wilson A. J. Blake N. R. Champness P. Hubberstey G. Walker E. J. Cussena M. Schröder Chem. Commun. 2007 840
20. H. Li M. Eddaoudi M. O'Keeffe O. M. Yaghi Nature 1999 402 276
21. O. M. Yaghi M. O'Keeffe N. W. Ockwig H. K. Chae M. Eddaoudi J. Kim Nature 2003 423 705
22. J. L. C. Rowsell O. M. Yaghi Angew. Chem., Int. Ed. 2005 44 4670
23. Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technologies Program http://www1.eere.energy.gov/ hydrogenandfuelcells/
24. H. K. Chae D. Y. Siberio-Pérez J. Kim Y.-B. Go M. Eddaoudi A. J. Matzger M. O'Keeffe O. M. Yaghi Nature 2004 427 523
25. For instance, (1) non-ideality of H2 gas is emphasized under low temperature and high-pressure conditions, and (2) temperature gradient effect between a sample cell and a pressure transducer could bring a huge experimental error since the deviation increases with an increase in the inverse of measurement temperature. In other words, even if the experimental value at room temperature looks reasonable, there is no guarantee that the sorption system will also work properly at cryogenic conditions
26. R. Chahine T. K. Bose Int. J. Hydrogen Energy 1994 19 161
27. H. W. Langmi A. Walton M. M. Al-Mamouri S. R. Johnson D. Book J. D. Speight P. P. Edwards I. Gameson P. A. Anderson I. R. Harris J. Alloys Compd. 2003 356-357 710
28. X. Li F. Cheng S. Zhang J. Chen J. Power Sources 2006 160 542
29. S. Lowell, J. E. Shields, M. A. Thomas and M. Thommes, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Kluwer Academic Publishers, Dordrecht, 2004
30. J. Keller and R. Staudt, Gas Adsorption Equilibria: Experimental Methods and Adsorption Isotherms, Springer Science + Business Media, New York, 2005
31. R. D. McCarty, J. Hord and H. M. Roder, Selected Properties of Hydrogen (Engineering Design Data), National Bureau of Standards, 1981, Monograph 168
32. K. Murata K. Kaneko F. Kokai K. Takahashi M. Yudasaka S. Iijima Chem. Phys. Lett. 2000 331 14
33. NIST chemistry webbook (thermophysical properties of fluid systems); http://webbook.nist.gov/chemistry/fluid/
34. S. Sircar Ind. Eng. Chem. Res. 1999 38 3670
35. A. L. Myers J. A. Calles G. Calleja Adsorption 1997 3 107
36. F. Rouquerol, J. Rouquerol and K. Sing, Adsorption by Powders and Porous Solids, Academic Press, London, 1999
37. H. Frost T. Düren R. Snurr J. Phys. Chem. B 2006 110 9565
38. K. Murata M. El-Merraoui K. Kaneko J. Chem. Phys. 2001 114 4196
39. A. V. Neimark P. I. Ravikovitch Langmuir 1997 13 5148
40. Actual pore volume after H2 adsorption may be smaller than the accessible pore volume, Vpore. However, in the Gibbs definition of dividing surface, the adsorbed phase is a surface therefore it does not have a volume. Considering this, in terms of H2 storage, the important factor is not the thickness of the adsorbed layer but the number of H 2 molecules in the pores (which includes the bulk region), we believe that rough estimation of absolute adsorbed amounts is an important issue. However, this is beyond the scope of this paper
41. The BET method is still widely used for determining the surface area of micro-mesoporous materials. It is also recognized that the BET area should not be accepted as the true internal area of microporous solids having pores of molecular dimensions, such as in MOF materials. In this case, the value obtained should be regarded as an apparent or equivalent surface area
42. A. Malek S. Farooq AIChE J. 1996 42 3191
43. L. Czepirski J. Jagiełło Chem. Eng. Sci. 1989 44 797
44. J. Jagiello T. J. Bandosz K. Putyera J. A. Schwarz J. Chem. Eng. Data 1995 40 1288
45. M. M. K. Salem P. Braeuer M. v. Szombathely M. Heuchel P. Harting K. Quitzsch M. Jaroniec Langmuir 1998 14 3376
46. S. K. Bhatia A. L. Myers Langmuir 2006 22 1688
47. This does not mean that volumetric measurements are better than gravimetric ones. Even in volumetric measurements either estimation of dead volume or unidealistic behavior of gas molecules under supercritical conditions can contain uncertainties