Tuning the oxidation level, the spin state, and the degree of electron delocalization in homo- And heteroleptic bis(α-diimine)iron complexes

Journal of the American Chemical Society

Volumn 131, Issue 3, 2009, Pages 1208-1221

  Khusniyarov, Marat M ^a   Weyhermüller, Thomas ^a   Bill, Eckhard ^a   Wieghardt, Karl ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CLOSED SHELLS; COORDINATION POLYHEDRA; CRYSTALLOGRAPHIC STUDIES; DENSITY FUNCTIONAL THEORY CALCULATIONS; DFT CALCULATION; DIANION; DIIMINE; ELECTRON DELOCALIZATION; ELECTRONIC SPECTROSCOPY; HETEROLEPTIC; HETEROLEPTIC COMPLEXES; HOMOLEPTIC; INTERMEDIATE SPINS; IRON COMPLEX; MAGNETIC SUSCEPTIBILITY MEASUREMENTS; MIXED-VALENT; MONOANION; MONOANIONS; MOSSBAUER; ORBITAL CHARGES; OXIDATION LEVEL; PENTAFLUOROPHENYL; RADICAL ANIONS; REDOX POTENTIALS; SPIN DENSITIES; SPIN STATE; TETRAHEDRAL GEOMETRY;

DENSITY FUNCTIONAL THEORY; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; IONS; IRON COMPOUNDS; LIGANDS; MAGNETIC SUSCEPTIBILITY; PROBABILITY DENSITY FUNCTION; SULFUR COMPOUNDS;

SPIN DYNAMICS;

AMIDE; ANION; IRON COMPLEX; N,N' BIS(PENAFLUOROPHENYL) 2 PHENYLENEDIAMIDE; UNCLASSIFIED DRUG; IMINE; IRON; LIGAND;

ARTICLE; ELECTRON; GEOMETRY; OXIDATION; SPECTROSCOPY; X RAY CRYSTALLOGRAPHY; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION; STEREOISOMERISM; TEMPERATURE;

CRYSTALLOGRAPHY, X-RAY; ELECTRONS; IMINES; IRON; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; STEREOISOMERISM; TEMPERATURE;

EID: 61749104121     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja808149k     Document Type: Article

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