-
1
-
-
34250292708
-
-
a) G. A. Razuvaev, K. G. Shalnova, L. G. Abakumova, G. A. Abakumov, Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.) 1977, 26, 1512;
-
(1977)
Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
, vol.26
, pp. 1512
-
-
Razuvaev, G.A.1
Shalnova, K.G.2
Abakumova, L.G.3
Abakumov, G.A.4
-
2
-
-
0001148961
-
-
b) R. M. Buchanan, H. H. Downs, W. B. Shorthill, C. G. Pierpont, S. L. Kessel, D. N. Hendrickson, J. Am. Chem. Soc. 1978, 100, 4318.
-
(1978)
J. Am. Chem. Soc
, vol.100
, pp. 4318
-
-
Buchanan, R.M.1
Downs, H.H.2
Shorthill, W.B.3
Pierpont, C.G.4
Kessel, S.L.5
Hendrickson, D.N.6
-
3
-
-
0000047707
-
-
a) F. Röhrscheid, A. L. Balch, R. H. Holm, Inorg. Chem. 1966, 5, 1542;
-
(1966)
Inorg. Chem
, vol.5
, pp. 1542
-
-
Röhrscheid, F.1
Balch, A.L.2
Holm, R.H.3
-
6
-
-
38949172019
-
-
G . H. Spikes, E. Bill, T. Weyhermüller, K. Wieghardt, Chem. Commun. 2007, 4339.
-
(2007)
Chem. Commun
, pp. 4339
-
-
Spikes, G.H.1
Bill, E.2
Weyhermüller, T.3
Wieghardt, K.4
-
7
-
-
53549085878
-
-
Crystal data for [NiIL•(cod, at 100(2) K with MoKα radiation (λ, 0.71073 Å, M r=545.42, monoclinic, space group C2/c (no. 15, a, 16.2464(5, b, 12.3107(4, c, 15.9082(5) Å, β, 112.580(3)°, Z, 4, R1, 0.0370 for 5600 reflections (I > 2σ(I, wR2, 0.1046 (all data, Crystal data for [FeIIIL•3] at 100(2) K with Mo Kα radiation (λ, 0.71073 Å, Mr, 1191.45, monoclinic, space group C2/c (no. 15, a, 10.8391(2, b, 27.8037(4, c, 23.8385(4) Å, β, 92.419(3)°, Z, 4, R1, 0.0345 for 14176 reflections (I > 2σ(I, wR2, 0.0955 all data, CCDC 668632 and 668633 contain the supplementary crystallographic data for this paper. These data can be obtained
-
r = 1191.45, monoclinic, space group C2/c (no. 15), a = 10.8391(2), b = 27.8037(4), c = 23.8385(4) Å, β = 92.419(3)°, Z = 4, R1 = 0.0345 for 14176 reflections (I > 2σ(I)), wR2 = 0.0955 (all data). CCDC 668632 and 668633 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac. uk/data_request/cif.
-
-
-
-
8
-
-
0032564853
-
-
P . Macchi, D. M. Proserpio, A Sironi, J. Am. Chem. Soc. 1998, 120, 1447.
-
P . Macchi, D. M. Proserpio, A Sironi, J. Am. Chem. Soc. 1998, 120, 1447.
-
-
-
-
10
-
-
53549127987
-
-
2).
-
2).
-
-
-
-
11
-
-
34447344855
-
-
a) N. Muresan, K. Chlopek, T. Weyhermüller, F. Neese, K. Wieghardt, Inorg. Chem. 2007, 46, 5327;
-
(2007)
Inorg. Chem
, vol.46
, pp. 5327
-
-
Muresan, N.1
Chlopek, K.2
Weyhermüller, T.3
Neese, F.4
Wieghardt, K.5
-
13
-
-
0001619627
-
-
A. S. Attia, B. J. Conklin, C. W. Lange, C. G. Pierpont, Inorg. Chem. 1996, 35, 1033.
-
(1996)
Inorg. Chem
, vol.35
, pp. 1033
-
-
Attia, A.S.1
Conklin, B.J.2
Lange, C.W.3
Pierpont, C.G.4
-
15
-
-
53549135365
-
-
This equation is derived from spin projection for a coupled system of an iron(III) ion (S, 5/2) and three aligned radicals S′, 3/2
-
This equation is derived from spin projection for a coupled system of an iron(III) ion (S = 5/2) and three aligned radicals (S′ = 3/2).
-
-
-
-
16
-
-
0032821544
-
-
M. D. Snodin, L. Ould-Moussa, U. Wallmann, S. Lecomte, V. Bachler, E. Bill, H. Hummel, T. Weyhermüller, P. Hildebrandt, K. Wieghardt, Chem. Eur. J. 1999, 5, 2554.
-
(1999)
Chem. Eur. J
, vol.5
, pp. 2554
-
-
Snodin, M.D.1
Ould-Moussa, L.2
Wallmann, U.3
Lecomte, S.4
Bachler, V.5
Bill, E.6
Hummel, H.7
Weyhermüller, T.8
Hildebrandt, P.9
Wieghardt, K.10
-
17
-
-
0000042525
-
-
M. J. Cohn, C. L. Xie, J. P. M. Tuchagues, C. G. Pierpont, D. N. Hendrickson, Inorg. Chem. 1992, 31, 5028.
-
(1992)
Inorg. Chem
, vol.31
, pp. 5028
-
-
Cohn, M.J.1
Xie, C.L.2
Tuchagues, J.P.M.3
Pierpont, C.G.4
Hendrickson, D.N.5
-
18
-
-
0034630837
-
-
C. Hauser, T. Glaser, E. Bill, T. Weyhermüller, K. Wieghardt, J. Am. Chem. Soc. 2000, 122, 4352.
-
(2000)
J. Am. Chem. Soc
, vol.122
, pp. 4352
-
-
Hauser, C.1
Glaser, T.2
Bill, E.3
Weyhermüller, T.4
Wieghardt, K.5
-
20
-
-
0035904991
-
-
A. J. Simaan, F. Banse, J. J. Girerd, K. Wieghardt, E. Bill, Inorg. Chem. 2001, 40, 6538.
-
(2001)
Inorg. Chem
, vol.40
, pp. 6538
-
-
Simaan, A.J.1
Banse, F.2
Girerd, J.J.3
Wieghardt, K.4
Bill, E.5
-
22
-
-
35348934861
-
-
K. Chlopek, N. Muresan, F. Neese, K. Wieghardt, Chem. Eur. J. 2007, 13, 8390.
-
(2007)
Chem. Eur. J
, vol.13
, pp. 8390
-
-
Chlopek, K.1
Muresan, N.2
Neese, F.3
Wieghardt, K.4
-
23
-
-
53549117357
-
-
The highest energy ligand orbital is predicted to have a very low, but non-zero, spatial overlap with the corresponding metal orbital (S = 0.01), although spin-pairing with the remaining two orbitals would force it into an antiferromagnetic alignment with respect to the Fe center. We propose, because of symmetry considerations, that this is one of three degenerate solutions.
-
The highest energy ligand orbital is predicted to have a very low, but non-zero, spatial overlap with the corresponding metal orbital (S = 0.01), although spin-pairing with the remaining two orbitals would force it into an antiferromagnetic alignment with respect to the Fe center. We propose, because of symmetry considerations, that this is one of three degenerate solutions.
-
-
-
-
24
-
-
16244368048
-
-
S. Sinnecker, L. D. Slep, E. Bill, F. Neese, Inorg. Chem. 2005, 44, 2245.
-
(2005)
Inorg. Chem
, vol.44
, pp. 2245
-
-
Sinnecker, S.1
Slep, L.D.2
Bill, E.3
Neese, F.4
-
25
-
-
0038666647
-
-
a) P. Hofmann, M. Frede, P. Stauffert, W. Lasser, U. Thewalt, Angew. Chem. 1985, 97, 693;
-
(1985)
Angew. Chem
, vol.97
, pp. 693
-
-
Hofmann, P.1
Frede, M.2
Stauffert, P.3
Lasser, W.4
Thewalt, U.5
-
27
-
-
0242324278
-
-
b) G. Erker, P. Czisch, R. Schlund, K. Angermund, C. Krüger, Angew. Chem. 1986, 98, 356;
-
(1986)
Angew. Chem
, vol.98
, pp. 356
-
-
Erker, G.1
Czisch, P.2
Schlund, R.3
Angermund, K.4
Krüger, C.5
-
29
-
-
0036533375
-
-
c) L.-C. Song, P.-C. Liu, C. Han, Q.-M. Hu, J. Organomet. Chem. 2002, 648, 119;
-
(2002)
J. Organomet. Chem
, vol.648
, pp. 119
-
-
Song, L.-C.1
Liu, P.-C.2
Han, C.3
Hu, Q.-M.4
-
30
-
-
4243825380
-
-
d) M. H. Chisholm, J. C. Huffman, A. L. Ratermann, Inorg. Chem. 1983, 22, 4100;
-
(1983)
Inorg. Chem
, vol.22
, pp. 4100
-
-
Chisholm, M.H.1
Huffman, J.C.2
Ratermann, A.L.3
-
32
-
-
34250637981
-
-
f) C. S. Weinert, A. E. Fenwick, P. E. Fanwick, I. P. Rothwell, Dalton Trans. 2003, 532;
-
(2003)
Dalton Trans
, pp. 532
-
-
Weinert, C.S.1
Fenwick, A.E.2
Fanwick, P.E.3
Rothwell, I.P.4
-
33
-
-
0012720383
-
-
g) A. Asadi, C. Eaborn, M. S. Hill, P. B. Hitchcock, M. M. Meehan, J. D. Smith, Organometallics 2002, 21, 2430.
-
(2002)
Organometallics
, vol.21
, pp. 2430
-
-
Asadi, A.1
Eaborn, C.2
Hill, M.S.3
Hitchcock, P.B.4
Meehan, M.M.5
Smith, J.D.6
-
35
-
-
0035982511
-
-
b) A. Knödler, M. Wanner, J. Fiedler, W. Kaim, J. Chem. Soc. Dalton Trans. 2002, 3079;
-
(2002)
J. Chem. Soc. Dalton Trans
, pp. 3079
-
-
Knödler, A.1
Wanner, M.2
Fiedler, J.3
Kaim, W.4
-
36
-
-
34547231234
-
-
c) E. Bulak, M. Leboschka, B. Schwederski, O. Sarper, T. Varnali, J. Fiedler, F. Lissner, T. Schleid, W. Kaim, Inorg. Chem. 2007, 46, 5562.
-
(2007)
Inorg. Chem
, vol.46
, pp. 5562
-
-
Bulak, E.1
Leboschka, M.2
Schwederski, B.3
Sarper, O.4
Varnali, T.5
Fiedler, J.6
Lissner, F.7
Schleid, T.8
Kaim, W.9
-
39
-
-
0006274589
-
-
M. Hanaya, S. Tero-kubota, M. Iwaizumi, Organometallics 1988, 7, 1500.
-
(1988)
Organometallics
, vol.7
, pp. 1500
-
-
Hanaya, M.1
Tero-kubota, S.2
Iwaizumi, M.3
|