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Recently, Hanson et al. used ligand 3 as a linker to build extended cationic zinc phosphate cluster frameworks. See ref 6b
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Recently, Hanson et al. used ligand 3 as a linker to build extended cationic zinc phosphate cluster frameworks. See ref 6b.
-
-
-
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40
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61549094541
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-
Crystal data for 4: C44H40Cd 2N8O8, M, 1033.64, colorless needle, triclinic, space group P1̄ (No. 2, a, 10.104(3) Å, b, 10.676(4) Å, c, 11.869(4) Å, α, 111.14(3)°, β, 98.22(3)°, γ, 110.32(2)°, V, 1065.9(6) Å3, Z, 1, T, 293(2) K, Dc, 1.610 g/cm3, F(000, 520, reflections collected, 3964, independent reflections, 3913 Rint, 0.0111, Å, 0.0492, wR2, 0.1139, GOF, 0.986
-
2 = 0.1139, GOF = 0.986.
-
-
-
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41
-
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61549107435
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-
The purities of bulk samples of crystals 4 and 6 were determined through comparison of experimental and simulated PXRD patterns. Their experimental patterns favorably correlate with the corresponding simulated ones generated from single-crystal X-ray diffraction data. Unfortunately, crystal 5 immediately collapsed after being removed from the mother liquor, and reliable powder X-ray as well as elemental analysis data could not be obtained thereby. See Figures S1 and S2 in the Supporting Information, 11) The exact number of guest molecules (solvents) in the crystallographic asymmetry unit can not be determined according to the Fourier electron-densities because of disorder. However, the host framework can be located exactly. Crystal data for 5: Colorless plates, triclinic, space group P1̄ (No. 2, a, 5.6528(11) Å, b, 9.887(3) Å, c, 12.924(3) Å, Å, 75.29(2)°, β, 80.906(19)°, γ, 77.244(19)°, V, 677.43
-
2 = 0.1658, GOF = 0.993.
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-
-
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43
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61549103331
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Crystal data for 6: C22H22CdN 4O5, M, 534.84, colorless needle, triclinic, space group P1̄ (No. 2, a, 9.260(3) Å, b, 10.595(3) Å, c, 11.532(3) Å, α, 90.07(2)°, β, 102.86(2)°, γ, 103.33(2)°, V, 1071.7(5) Å3, Z, 2, T, 293(2) K, Dc, 1.657 g/cm3, F(000, 540, reflections collected, 3968, independent reflections, 3827 Rint, 0.0043, R1, 0.0487, wR2, 0.1166, GOF, 1.034
-
2 = 0.1166, GOF = 1.034.
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44
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33749652262
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